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Three-dimensional diesel engine combustion simulations with single-step chemistry have been compared with two-step and three-step chemistry by means of the Laminar and Turbulent Characteristic Time Combustion model using the Star-CD program. The second reaction describes the oxidation of CO and the third reaction describes the combustion of H2. The comparisons have been performed for two heavy-duty diesel engines. The two-step chemistry was investigated for a purely kinetically controlled, for a mixing limited and for a combination of kinetically and mixing limited oxidation. For the latter case, two different descriptions of the laminar reaction rates were also tested. The best agreement with the experimental cylinder pressure has been achieved with the three-step mechanism but the differences with respect to the two-step and single-step reactions were small.

A modified version of the Laminar and Turbulent Characteristic Time combustion model and the Hiroyasu-Magnussen soot model have been implemented in the flow solver Star-CD. Combustion simulations of three DI diesel engines, utilizing the standard k-ε turbulence model and a modified version of the RNG k-ε turbulence model, have been performed and evaluated with respect to combustion performance and emissions. Adjustments of the turbulent characteristic combustion time coefficient, which were necessary to match the experimental cylinder peak pressures of the different engines, have been justified in terms of non-equilibrium turbulence considerations. The results confirm the existence of a correlation between the integral length scale and the turbulent time scale. This correlation can be used to predict the combustion time scale in different engines.

The one-equation subgrid scale model for the Large Eddy Simulation (LES) turbulence model has been compared to the popular k-ε RNG turbulence model in very different sized direct injection diesel engines. The cylinder diameters of these engines range between 111 and 200 mm. This has been an initial attempt to study the effect of LES in diesel engines without any modification to the combustion model being used in its Reynolds-averaged Navier-Stokes (RANS) form. Despite some deficiencies in the current LES model being used, it already gave much more structured flow field with approximately the same kind of accuracy in the cylinder pressure predictions than the k-ε RNG turbulence model.