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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Video

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO2 oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Technical Paper

External Corrosion Resistance of CuproBraze® Radiators

2001-05-14
2001-01-1718
New technology for the manufacturing of copper/brass heat exchangers has been developed and the first automotive radiators are already in operation in vehicles. This new technology is called CuproBraze®. One of the essential questions raised is the external corrosion resistance with reference to the present soldered copper/brass radiators and to the brazed aluminium radiators. Based on the results from electrochemical measurements and from four different types of accelerated corrosion tests, the external corrosion resistance of the CuproBraze® radiators is clearly better than that of the soldered copper/brass radiators and competitive with the brazed aluminum radiators, especially as regards marine atmosphere. Due to the relatively high strength of the CuproBraze® heat exchangers, down gauging of fins and tubes in some applications is attractive. High performance coatings can ensure long lifetime from corrosion point of view, even for thin gauge heat exchangers.
Technical Paper

The Effects of Natural Aging on Fleet and Durability Vehicle Engine Mounts from a Dynamic Characterization Perspective

2001-04-30
2001-01-1449
Elastomers are traditionally designed for use in applications that require specific mechanical properties. Unfortunately, these properties change with respect to many different variables including heat, light, fatigue, oxygen, ozone, and the catalytic effects of trace elements. When elastomeric mounts are designed for NVH use in vehicles, they are designed to isolate specific unwanted frequencies. As the elastomers age however, the desired elastomeric properties may have changed with time. This study looks at the variability seen in new vehicle engine mounts and how the dynamic properties change with respect to miles accumulated on fleet and durability test vehicles.
Technical Paper

Drawbeads in Sheet Metal Stamping - A Review

1997-02-24
970986
The paper reviews the role of drawbeads in sheet metal stamping. The design of drawbeads is discussed in depth, with treatment of different bead cross sections, bead end shapes, and bead materials. International standards and practices are included. This is followed by the historical development of the modeling of the drawbead restraining force, starting with basic equilibrium approaches, and leading to the use of the finite element method which permits the study of drawbead effects on sheet metal flow in three dimensions. Finally, the potential of active drawbeads is described based upon ongoing research which is directed toward closed-loop computer control of the stamping process through adjustment of the drawbead penetration.
Technical Paper

A 2-D Computational Model Describing the Flow and Filtration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980545
A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.
Technical Paper

A 2-D Computational Model Describing the Heat Transfer, Reaction Kinetics and Regeneration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980546
A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.
Technical Paper

The Effect of Oil and Coolant Temperatures on Diesel Engine Wear

1977-02-01
770086
A study has been made of piston ring wear and total engine wear using literature data and new experimental results. The main purpose of the study was to establish the effects of oil and coolant temperatures on engine wear. Wear trends that were found in the early 1960's may not be valid any longer because of the development of higher BMEP turbocharged diesel engines, better metallurgical wear surfaces and improved lube oil properties. New data are presented for the purpose of describing present wear trends. A direct-injection, 4-cycle, turbocharged diesel engine was used for the wear tests. The radioactive tracer technique was used to measure the top piston ring chrome face wear. Atomic emission spectroscopy was employed to determine the concentration of wear metals in the oil to determine total engine wear based on iron and lead. The data were analyzed and compared to the results found in the literature from previous investigators.
Technical Paper

The Effects of a Porous Ceramic Particulate Trap on the Physical, Chemical and Biological Character of Diesel Particulate Emissions

1983-02-01
830457
Physical, chemical, and biological characterization data for the particulate emissions from a Caterpillar 3208 diesel engine with and without Corning porous ceramic particulate traps are presented. Measurements made at EPA modes 3,4,5,9,lO and 11 include total hydrocarbon, oxides of nitrogen and total particulate matter emissions including the solid fraction (SOL), soluble organic fraction (SOF) and sulfate fraction (SO4), Chemical character was defined by fractionation of the SOF while biological character was defined by analysis of Ames Salmonella/ microsome bioassay data. The trap produced a wide range of total particulate reduction efficiencies (0-97%) depending on the character of the particulate. The chemical character of the SOF was significantly changed through the trap as was the biological character. The mutagenic specific activity of the SOF was generally increased through the trap but this was offset by a decrease in SOF mass emissions.
Technical Paper

Effects of Fretting Corrosion on Lift Glass

2011-04-12
2011-01-1434
The electrical architecture design of a rear back glass defrost grid system encompasses many critical criteria that must be integrated into the design. For example, the defrost clip location and interface to the glass must meet all vehicle performance requirements. If the defrost clip to the glass interface is not resistant to vibration and relative movement, detachment and loss of function can occur. This paper describes a back glass defrost clip with a solder joint that is robust to manufacturing variations and customer usage conditions. A designed experiment using Design for Six Sigma methodologies was performed to understand the effects of the attachment interface to the electrical wiring pigtail, and parameters that affect performance. The working constraints, testing set up, validation, and root cause investigation of the clip detachment phenomenon is covered in this paper.
Technical Paper

The Effect of Pt-Pd Ratio on Oxidation Catalysts Under Simulated Diesel Exhaust

2011-04-12
2011-01-1134
With a tighter regulatory environment, reduction of hydrocarbon emissions has emerged as a major concern for advanced low-temperature combustion engines. Currently precious metal-based diesel oxidation catalysts (DOC) containing platinum (Pt) and palladium (Pd) are most commonly used for diesel exhaust hydrocarbon oxidation. The efficiency of hydrocarbon oxidation is greatly enhanced by employing both Pt and Pd together compared to the case with Pt or Pd alone. However, there have been few systematic studies to investigate the effects of the ratio of platinum to palladium on catalytic oxidation over the DOC. The present study illustrates the relationship between the Pt-Pd ratio and catalyst activity and stability by evaluating a series of catalysts with various Pt to Pd ratios (1:0, 7:1, 2:1, 1:2, 1:5, 0:1). These catalysts were tested for their CO and hydrocarbon light-off temperatures under simulated conditions where both unburned and partially burned hydrocarbons were present.
Technical Paper

Effects of Fuel Ethanol Quality on Vehicle System Components

2011-04-12
2011-01-1200
Corn ethanol has been used for fuel blending as both an oxygenate and octane booster and in most U.S. states conform to the ASTM D5798 fuel ethanol quality standard. Today the fuel ethanol market is expanding the types of feedstocks used to make ethanol and changing the processing techniques. These non-corn alternative feedstocks used to produce fuel ethanol bring new chemical components into the product that are not monitored under the D5798 standard, and it is unclear if they will result in material compatibility challenges for vehicle fuel systems that could affect performance and emissions. The vehicle contains a variety of plastic, metallic, and polymeric materials in the fuel tank, fuel pump, engine, and exhaust system that are sensitive to water, ions, acids, and high molecular weight compounds.
Technical Paper

Comparisons of Current Concepts for Press Hardened Steel Tailor Welded Blanks and Tailor Rolled Blanks on Center Pillar Reinforcements

2011-04-12
2011-01-1059
Press hardened steels (PHS) are commonly used in automotive structural applications because of their combination of extremely high strength, load carrying capacity and the ability to form complex shapes in the press hardening process. Recent adoption of increased roof crush standards, side impact requirements and the increased focus on CO2 emissions and mass reduction have led autmotive manufacturers to significantly increase the amount of PHS being designed into future vehicle designs. As a way to further optimize the use of these steels, multi-gauge welded blanks of PHS and multi-material blanks of PHS to microalloyed steels of various thickness have been developed to help achieve these requirements. More recently, tailor rolled PHS, whereby the steel is rolled such that the thickness changes across the width of the sheet, have been developed.
Technical Paper

Investigation of Stamping Tooling Durability for Dual Phase Steels

2011-04-12
2011-01-1060
Advanced High-Strength Steels (AHSS) have become an essential part of the lightweighting strategy for automotive body structures. The ability to fully realize the benefits of AHSS depends upon the ability to aggressively form, trim, and pierce these steels into challenging parts. Tooling wear has been a roadblock to stamping these materials. Traditional die materials and designs have shown significant problems with accelerated wear, galling and die pickup, and premature wear and breakage of pierce punches. [1] This paper identifies and discusses the tribological factors that contribute to the successful stamping of AHSS. This includes minimizing tool wear and galling/die pick-up; identifying the most effective pierce clearance (wear vs. burr height) when piercing AHSS; and determining optimal die material and coating performance for tooling stamping AHSS.
Technical Paper

Application of Failure Plastic Strain to Quasi-Static Finite Element Analysis for Projection Weld and Strain-based Spot Weld Evaluation

2011-04-12
2011-01-1074
One of the most critical and important fracture mechanisms in a FMVSS207/210/225[1] test is the pull-thru of bolts from the body structure or spot weld separation. There are no analytically proven methods of making a judgment of pull-thru occurring except through evaluation of the plastic strain or through the thickness strain value around projection welds on Weld nut/stud bolt or spot welds. Therefore it is essential to have accurate criteria to evaluate the pull-thru. During elastic deformation, the sheet steel deforms while the quasi-static force is being applied and then returns to its original shape when the force is released. But when the force causes a stress that exceeds the yield strength, the sheet steel will permanently elongate with each additional unit of force applied, and it will not return to its original shape and size.
Technical Paper

Seal Testing in Aerated Lubricants

2011-04-12
2011-01-1209
Typical seal immersion testing in lubricants does not aerate the lubricant as typically seen during normal operation of a transmission or axle. This paper will discuss a new test apparatus that introduces air into transmission fluids and gear oils during seal immersion testing. The seal materials selected for the testing are from current vehicle applications from several different material families. The test results compare the standard properties: change in tensile strength, elongation, hardness, and volume swell. Several tests were completed to investigate and refine the new testing method for seal compatibility testing with transmission fluids and gear oils. Initial results from the first data sets indicate that lubricant aeration helps improve test repeatability. In addition to aeration, the test results explore appropriate fluid immersion temperature for repeatability and appropriate test duration.
Technical Paper

An Experimental Study of Particulate Thermal Oxidation in a Catalyzed Filter During Active Regeneration

2009-04-20
2009-01-1474
Active regeneration experiments were performed on a Cummins 2007 aftertreatment system by hydrocarbon dosing with injection of diesel fuel downstream of the turbocharger. The main objective was to characterize the thermal oxidation rate as a function of temperature and particulate matter (PM) loading of the catalyzed particulate filter (CPF). Partial regeneration tests were carried out to ensure measureable masses are retained in the CPF in order to model the oxidation kinetics. The CPF was subsequently re-loaded to determine the effects of partial regeneration during post-loading. A methodology for gathering particulate data for analysis and determination of thermal oxidation in a CPF system operating in the engine exhaust was developed. Durations of the active regeneration experiments were estimated using previous active regeneration work by Singh et al. 2006 [1] and were adjusted as the experiments progressed using a lumped oxidation model [2, 3].
Technical Paper

An Experimental Investigation into Particulate Matter Oxidation in a Catalyzed Particulate Filter with Biodiesel Blends on an Engine during Active Regeneration

2013-04-08
2013-01-0521
Active regeneration experiments were carried out on a production 2007 Cummins 8.9L ISL engine and associated diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF) aftertreatment system. The effects of SME biodiesel blends were investigated to determine the particulate matter (PM) oxidation reaction rates for active regeneration. The experimental data from this study will also be used to calibrate the MTU-1D CPF model [1]. The experiments covered a range of CPF inlet temperatures using ULSD, B10, and B20 blends of biodiesel. The majority of the tests were performed at a CPF PM loading of 2.2 g/L with in-cylinder dosing, although 4.1 g/L and a post-turbo dosing injector were also investigated. The PM reaction rate was shown to increase with increasing percent biodiesel in the test fuel as well as increasing CPF temperature.
Technical Paper

Temperature Effects on the Deformation and Fracture of a Quenched-and-Partitioned Steel

2013-04-08
2013-01-0610
Temperature effects on the deformation and fracture of a commercially produced transformation-induced plasticity (TRIP) steel subject to a two-step quenching and partitioning (Q&P) heat treatment are investigated. Strain field evolution at room temperature is quantified in this 980 MPa grade Q&P steel with a stereo digital image correlation (DIC) technique from quasi-static tensile tests of specimens with 0°, 45°, and 90° orientations. Baseline tensile properties along with the variation of the instantaneous hardening index with strain were computed. Variations of the bake-hardening index were explored under simulated paint bake conditions. Tensile properties were measured at selected temperatures between -100°C and 200°C and the TRIP effect was found to be temperature-dependent due to stress-induced martensitic transformation at lower temperatures versus strain-induced transformation at higher temperatures.
Technical Paper

An Experimental and Numerical Study of the Microstructural and Mechanical Properties of an Extruded Magnesium Alloy at 450 °C and Varied Strain Rates

2013-04-08
2013-01-0976
An extruded Mg-Al-Mn (AM30) magnesium alloy was subjected to uniaxial compression along the extrusion direction (ED) and the extrusion radial direction (RaD) at 450 °C and different strain rates. The microstructure and texture of the AM30 alloy under different deformation conditions were examined. Texture evolution was characterized by electron backscatter diffraction (EBSD). The activity of different deformation modes including twinning were simulated using the visco-plastic self-consistent (VPSC) and the simplistic Sachs polycrystal plasticity models. The results show that the microstructure and the mechanical property of the Mg alloy strongly depend on the strain rate, with twinning activated at strain rates >0.5 s−1. Dynamic recrystallization and twinning interacted with each other and affected the final microstructure and mechanical property of the magnesium alloy.
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