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A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO3 (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn4+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/?-Al2O3 (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO2).
Technical Paper

Management System for Continuously Variable Valve Lift Gasoline Engine

2007-04-16
2007-01-1200
A continuously variable valve lift gasoline engine can improve fuel consumption by reducing pumping loss and increase maximum torque by optimizing valve lift and cam phase according to engine speed. In this research, a new control system to simultaneously ensure good driveability and low emissions was developed for this low fuel consumption, high power engine. New suction air management through a master-slave control made it possible to achieve low fuel consumption and good driveability. To regulate the idle speed, a new controller featuring a two-degree-of-freedom sliding-mode algorithm with cooperative control was designed. This controller can improve the stability of idle speed and achieve the idle operation with a lower engine speed. To reduce emissions during cold start condition, an ignition timing control was developed that combine I-P control with a sliding mode control algorithm.
Technical Paper

Study on Emission Reducing Method with New Lean NOX Catalyst for Diesel Engines

2007-07-23
2007-01-1933
In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For diesel engines, reducing NOX emissions is a difficult technical challenge.[1],[2],[3],[4]. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows the effective reduction of NOX. However, in order to realize cleaner emission gases, precise engine control in response to the state of the exhaust aftertreatment system is essential.
Technical Paper

Summary report of Japan Clean Air Program diesel and diesel fuel activities

2007-07-23
2007-01-1952
Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.
Technical Paper

Development of Thinnest Wall Catalyst Substrate

2002-03-04
2002-01-0358
The thinnest wall thickness of automotive catalyst substrates has previously been 30 μm for metal substrates and 50 μm for ceramic substrates. This paper describes a newly developed catalyst substrate that is the world's first to achieve 20-μm-thick cell walls. This catalyst substrate features low thermal capacity and low pressure loss. Generally, a thinner cell wall decreases substrate strength and heat shock resistance. However, the development of a “diffused junction method”, replacing the previous “wax bonding method”, and a small waved foil has overcome these problems. This diffused junction method made it possible to strengthen the contact points between the inner waved foil and the rolled foil compared with previous substrates. It was also found that heat shock resistance at high temperature can be much improved by applying a slight wave to the foil instead of using a plane foil.
Technical Paper

Development of Diesel Engine System with DPF for the European Market

2007-04-16
2007-01-1061
Nissan Motor has put on the European SUV market a 2.2-L direct-injection diesel engine with a diesel particulate filter (DPF) system that complies with the EURO IV emission regulations. This paper describes the DPF system, cooperative control of a variable geometry turbo (VGT) and exhaust gas recirculation (EGR), and a high-accuracy lambda control adopted for this engine. In order to achieve a compact DPF, the high-accuracy lambda control was developed to reduce variation in engine-out particulate matter (PM) emissions. Moreover, the accuracy of the technique for predicting the quantity of PM accumulation was improved for reliable detection of the DPF regeneration. Prediction error for PM accumulation increases during transient operation. Control logic was adopted to correct the PM prediction according to lambda fluctuation detected by an observer for lambda at cylinder under transient operating conditions. The observer is corrected lambda sensor output.
Technical Paper

Expansion of Premixed Compression Ignition Combustion Region by Supercharging Operation and Lower Compression Ratio Piston

2007-08-05
2007-01-3614
Various premixed diesel combustion concepts are suggested as the way of simultaneous reduction of NOx and PM emission from diesel engines. However, every combustion concept has common problems, such as difficulty of ignition timing control, a great deal of HC and CO emissions and limiting the operation region to low load operation. The purpose of this study is to expand the operation region of Premixed Compression Ignition (PCI) combustion, which is a premixed diesel combustion concept that realizes the fuel injection around the top dead center. As a result of examining it with EGR, supercharging operation and low compression ratio piston, PCI combustion region was expanded to cover higher load operation. And the high load region was limited by not only stoichiometric air fuel ratio but also permissible maximum in-cylinder pressure.
Technical Paper

Study on HCCI-SI Combustion Using Fuels Ethanol Containing

2007-10-29
2007-01-4051
Bio-ethanol is one of the candidates for automotive alternative fuels. For reduction of carbon dioxide emissions, it is important to investigate its optimum combustion procedure. This study has explored effect of ethanol fuels on HCCI-SI hybrid combustion using dual fuel injection (DFI). Steady and transient characteristics of the HCCI-SI hybrid combustion were evaluated using a single cylinder engine and a four-cylinder engine equipped with two port injectors and a direct injector. The experimental results indicated that DFI has the potential for optimizing ignition timing of HCCI combustion and for suppressing knock in SI combustion under fixed compression ratio. The HCCI-SI hybrid combustion using DFI achieved increasing efficiency compared to conventional SI combustion.
Technical Paper

Nano Particle Emission Evaluation of State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI) and Fuel Qualities Effects (EtOH, ETBE, FAME, Aromatics and Distillation)

2007-10-29
2007-01-4083
Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.
Technical Paper

Unregulated Emissions Evaluation of Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI), State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), and Fuel Qualities Effects (EtOH, ETBE, Aromatics and FAME)

2007-10-29
2007-01-4082
In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.
Technical Paper

The Effect of a Longer Stroke on Improving Fuel Economy of a Multiple-Link VCR Engine

2007-10-29
2007-01-4004
Some automakers have been studying variable compression ratio (VCR) technology as one possible way of improving fuel economy. In previous studies, we have developed a VCR mechanism of a unique multiple-link configuration that achieves a piston stroke characterized by semi-sinusoidal oscillation and lower piston acceleration at top dead center than on conventional mechanisms. By controlling compression ratio with this multiple-link VCR mechanism so that it optimally matches any operating condition, the mechanism has demonstrated that both lower fuel consumption and higher output power are simultaneously possible. However, it has also been observed that fuel consumption does not reduce further once the compression ratio reached a certain level. This study focused on the fact that the piston-stroke characteristic obtained with the multiple-link mechanism is suitable to a longer stroke.
Technical Paper

Parametric Study and Clarification of Determination Factors of Diesel Exhaust Emission Using a Single Cylinder Engine and Model Fuels - JCAP Combustion Analysis Working Group Report Part I

2002-10-21
2002-01-2824
Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.
Technical Paper

Novel Analysis Approach for Better Understanding of Fuel and Engine Effects on Diesel Exhaust Emission - JCAP Combustion Analysis Working Group Report Part II

2002-10-21
2002-01-2825
1 A novel analysis approach called “Regression Density method” was developed for better understanding of fuel property effects on exhaust emission. The approach was applied to diesel emission data obtained in JCAP programs and emission models were conducted to analyze the effects of fuel properties and engine conditions on emissions. By introducing this analysis method, the relationship between density factor and aromatics factor (chemical composition factor) was identified, however, they have been reported previously as dominant factors in fuel properties. The effects of engine conditions and fuel properties on emissions were investigated quantitatively based on the statistically conducted emission models to clarify universal ways to emission reduction. The mechanism of emission formation of vehicles and engines with characteristic behavior was also examined.
Technical Paper

52 Development of a Four-stroke Engine with Turbo Charger for Personal Watercraft

2002-10-29
2002-32-1821
There is a movement to apply emission control in a marine engine as well due to high public awareness of environmental concern in the United States. We started at the development of 3-seater Personal Watercraft (PWC) equipped with 4-stroke engines in taking environment conformity and potential into account. The PWC employed series 4-cylinder 1100cc displacement engine that has been used for mass production motorcycles. The engine was modified to satisfy requirements for PWC, as a marine engine, such as performance function and corrosion. In order to achieve greater or equal power/weight ratio as against two-stroke PWCs, a four-stroke engine for PWC with an exhaust turbo charger was developed. As a result, we succeeded in developing an engine that attained top-level running performance and durability superior to competitors' 2-stroke engines.
Technical Paper

Study of an Integrated Diesel Engine-CVT Control Algorithm for Improving Drivability and Exhaust Emission Performance

2001-10-01
2001-01-3452
Diesel engines have attracted more attention in recent years as one means of reducing carbon dioxide (CO2) emissions from motor vehicles. One of the major issues for diesel engines is exhaust emissions performance. Diesel engines also face various difficulties in providing the driving force demanded by the driver because of their greater inertia than that of gasoline engines. Meanwhile, continuously variable transmissions (CVTs) have been popularized as gearboxes that execute ratio changes continuously without generating shift shock. The aim of this research is to achieve higher levels of drivability and exhaust emissions performance by mating a CVT to a diesel engine and making maximum use of the continuous ratio change capability. An integrated engine-CVT control algorithm that can freely set the driving force and also the engine operating conditions for generating that driving force has been developed through this study.
Technical Paper

JamaS Study on the Location of In-Vehicle Displays

2000-11-01
2000-01-C010
JAMA (Japan Automobile Manufactures Association, Inc.)'s guideline for car navigation systems is being decided on displayed the amount of information while driving. The position of a display and the estimated equation, which could be applied from a passenger car to a heavy truck, was studied. The evaluation index was the distance which drivers could become aware of a preceding vehicle by their peripheral vision, because car accidents while drivers glance at an in- vehicle display are almost the rear end collisions. As the results, the lower limit of a position of an in-vehicle display for a passenger car was 30 degrees, and a heavy truck was 46 degrees.
Technical Paper

Basic Understanding of Activated Radical Combustion and Its Two-Stroke Engine Application and Benefits

2000-06-19
2000-01-1836
For a better understanding of the auto-ignition phenomenon in internal combustion engines, consideration is given from the in-cylinder gas temperature aspect. Experimental results demonstrate that the in-cylinder gas temperature at the end of compression, namely, the “auto-ignition temperature” is deeply involved in the onset of auto-ignition. The relation between the gas exchange state and the auto-ignition temperature explains the mechanism of timing controlled auto-ignition, namely, Activated Radical (AR) Combustion. The auto-ignition temperature is maintained constant during the AR combustion state, thanks to the exhaust valve controlling the hot residual gas amount. Finally, the utilization of auto-ignition in gasoline engines is discussed from the methodology aspect.
Technical Paper

Intake and Exhaust Systems Equipped with a Variable Valve Control Device for Enhancing of Engine Power

2001-03-05
2001-01-0247
The variable intake and exhaust control valve system for the in-line four-cylinder motorcycle engine was developed for realization of high engine power in all the engine speed ranges. Both the variable intake and exhaust control valves are operated by one servomotor. For high engine speeds, the exhaust collector pipe design for merging of each exhaust gas flow at 180 degrees phase difference is used. For mid engine speeds, the design for merging of each exhaust gas flow at 360 degrees phase difference is used. Two modes are provided to the intake control, and three modes are provided to the exhaust control. Along with exhaust-gas treatment systems such as the catalyst and air-injection system, high engine performance with optimum driveability and reduced emission are realized.
Technical Paper

Engine Application of a Battery Voltage-Driven DI Fuel Injection System

2001-03-05
2001-01-0986
Every fuel injection system for DI gasoline engines has a DC-DC converter to provide high, stabile voltage for opening the injector valve more quickly. A current control circuit for holding the valve open is also needed, as well as a large-capacity capacitor for pilot injection. Since these components occupy considerable space, an injector drive unit separate from the ECU must be used. Thus, there has been a need for a fuel injection system that can inject a small volume of fuel without requiring high voltage. To meet that need, we have developed a dual coil injector and an opening coil current control system. An investigation was also made of all the factors related to the dynamic range of the injector, including static flow rate, fuel pressure, battery voltage and harness resistance. Both efforts have led to the adoption of a battery voltage-driven fuel injector.
Technical Paper

Technique for Analyzing Swirl Injectors of Direct-Injection Gasoline Engines

2001-03-05
2001-01-0964
This paper describes the numerical and experimental approaches that were applied to study swirl injectors that are widely used in direct-injection gasoline engines. As the numerical approach, the fuel and air flow inside an injector was first analyzed by using a two-phase flow analysis method [VOF (Volume of Fluid) model]. A time-series analysis was made of the flow though the injector and also of the air cavity that forms at the nozzle and influences fuel atomization. The calculated results made clear the process from initial spray formation to liquid film formation. Spray droplet formation was then analyzed with the synthesized spheroid particle (SSP) method. As the experimental approach, in order to measure the cavity factor that represents the liquid film thickness, nozzle exit flow velocities were measured by particle image velocimetry (PIV).
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