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This paper presents a new substrate for Lean NOx Traps (LNT) which enables high NOx conversion efficiency, even after long-term aging, when using alkali metals as the NOx adsorber. When a conventional metal honeycomb is used as the LNT substrate, the chromium in the metal substrate migrates into the washcoat and reacts with the alkali metals after thermal aging. In order to help prevent this migration, we have developed a new substrate where a fine -alumina barrier is precipitated to the surface of the metal substrate. The new substrate is highly capable of preventing migration of chromium into the washcoat and greatly enhances the NOx conversion. The durability of the new substrate and emission test using a test vehicle are also examined.

Recently, emission regulations have been strict in many countries, and it is very difficult technical issue to reduce emissions of diesel cars. In order to reduce the emissions, various combustion technologies such as Massive EGR, PCCI, Rich combustion, etc. have been researched. The combustion technologies require precise control of the states of in-cylinder gas (air mass flow, EGR rate etc.). However, a conventional controller such as PID controller could not provide sufficient control accuracy of the states of in-cylinder gas because the air-pass system controlled by an EGR valve, a throttle valve, a variable nozzle turbo, etc. is a multi-input, multi-output (MIMO) coupled system. Model predictive control (MPC) is well known as the advanced MIMO control method for industrial process. Generally, the sampling period of industrial process is rather long so there is enough time to carry out the optimization calculation for MPC.

The purpose of this research was to predict the amount of wear on exhaust valve seats in durability testing of gasoline engines. Through the rig wear test, a prediction formula was constructed with multiple factors as variables. In the rig test, the wear rate was measured in some cases where a number of factors of valve seat wear were within a certain range. Through these tests, sensitivity for each factor was determined from the measured wear data, and then a prediction formula for calculating the amount of wear was constructed with high sensitivity factors. Combining the wear amount calculation formula with the operation mode of the actual engine, the wear amount in that mode can be calculated. The calculated wear amount showed a high correlation with the wear amount measured in bench tests and the wear amount measured in vehicle tests.

The field of diesel combustion research is producing numerous reports on studies of premixed combustion, which promises simultaneous reduction of both NOx and soot, in order to meet increasingly stringent regulations on harmful emissions from automobiles. However, although premixed combustion can simultaneously reduce both NOx and soot, certain issues have been pointed out, including the fact that it emits greater quantities of unburned HC and CO gases and the fact that it limits the operating range. Furthermore, this combustion method sets the ignition delay longer with the aim of promoting the mixing of fuel and air. This raises issues with the product due to the combustion instability and sensitivity to the uneven fuel properties that are found on the market, the capability of the engine response under transient conditions, the deterioration in combustion noise, and so on.

A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For diesel engines, reducing NOX emissions is a difficult technical challenge.[1],[2],[3],[4]. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows the effective reduction of NOX. However, in order to realize cleaner emission gases, precise engine control in response to the state of the exhaust aftertreatment system is essential.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For lean-burn diesel engines, since it is not possible to use three-way catalytic converters, reducing NOX emissions is a difficult technical challenge. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows more efficient reduction of NOX than its conventional counterparts. However, an appropriate switching control between lean and rich mixture conditions along with compensation for catalyst deterioration was necessary.

A continuously variable valve lift gasoline engine can improve fuel consumption by reducing pumping loss and increase maximum torque by optimizing valve lift and cam phase according to engine speed. In this research, a new control system to simultaneously ensure good driveability and low emissions was developed for this low fuel consumption, high power engine. New suction air management through a master-slave control made it possible to achieve low fuel consumption and good driveability. To regulate the idle speed, a new controller featuring a two-degree-of-freedom sliding-mode algorithm with cooperative control was designed. This controller can improve the stability of idle speed and achieve the idle operation with a lower engine speed. To reduce emissions during cold start condition, an ignition timing control was developed that combine I-P control with a sliding mode control algorithm.

When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.

A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.

Variable-valve-actuation mechanism is considered to be one of the most suitable solutions to realize the compatibility between higher power output and performances in the practical speed range. A new variable-valve-actuation mechanism named “Shuttle Cam” was designed and studied. In this mechanism which was applied to a conventional motorcycle engine with rocker arms and gear-train-driven valve system, the cam gears move along the idler gear. And cam shafts simultaneously slide along the rocker-arm slipper surfaces which are concentric with the idler gear. Consequently valve lift varies continuously in accordance with the alteration in the rocker-arm lever ratio and the cam phasing changes simultaneously in accordance with the cam gear rotation. Result of the experiments has confirmed that the mechanism functions accurately even at high speeds up to 10,000 rpm and some improvements were achieved in power output, fuel consumption, idling quality, and exhaust-noise level.

The reduction of fuel consumption is of great importance to automobile manufacturers. As a prospective means to achieve fuel economy, lean burn is being investigated at various research organizations and automobile manufacturers and a number of studies on lean-burn technology have been reported to this date. This paper describes the development of a four-valve lean-burn engine; especially the improvement of the combustion, the development of an engine management system, and the achievement of vehicle test results. Major themes discussed in this paper are (1) the improvement of brake-specific fuel consumption under partial load conditions and the achievement of high output power by adopting an optimized swirl ratio and a variable-swirl system with a specially designed variable valve timing and lift mechanism, (2) the development of an air-fuel ratio control system, (3) the improvement of fuel economy as a vehicle and (4) an approach to satisfy the NOx emission standard.

For reduction of NOx and soot emission with conventional diesel diffusion combustion, the authors focused on enhancement of the rate of injection (hereafter referred to as RoI) to improve air availability, thus enhancing the fuel distribution and atomization. In order to increase opening ramp of the RoI (hereafter referred to as fast injection rate), a hydraulic circuit was improved and nozzle geometries were optimized to make the greatest use of the advantages of the hydraulic circuit. Two different common rail injectors were prepared for this research. One is a mass production-type injector with piezo actuator that achieved the EURO-V exhaust gas emission standards, and the other is a prototype injector equipped with the new hydraulic circuit. The nozzle needle of the prototype injector is directly actuated by high-pressure fuel from common rail to improve the RoI.

A measurement method for valve behavior during engine firing is established. In order to grasp valve behavior accurately, it has been required to develop a measurement method for valve behavior that takes in account for the condition during engine firing. However, behaviors of a valve train have generally been analyzed during engine motoring because it is difficult to measure them during engine firing. In this study, valve behavior during engine firing can be measured accurately by attaching a gap sensor to the valve guide. Furthermore, the simulation system for valve behavior that treated the valve train as three-dimensional flexible body is built. Under engine motoring condition, high correlation between measurement and simulation is confirmed for valve behavior and spring stress.

Compression ignition combustion with a lean mixture has high potential in terms of high theoretical thermal efficiency and low NOx emission characteristics due to low combustion temperatures. In particular, a Dual-Fuel concept is proposed to achieve high ignition timing controllability and an extended operation range. This concept controls ignition timing by adjusting the fraction of two fuels with different ignition characteristics. However, a rapid combustion process after initial ignition cannot be avoided due to the homogenous nature of the fuel mixture, because the combustion process depends entirely on the high reaction rate of thermal ignition. In this study, the effect of mixture stratification in the cylinder on the combustion process after ignition based on the Dual-Fuel concept was investigated. Port injection of one fuel creates the homogeneous mixture, while direct injection of the other fuel prepares a stratified mixture in the cylinder at the compression stroke.

The aim of this study is to clarify the mixture formation in the combustion chamber of our developed natural gas engine incorporating the sub-chamber injection system, in which natural gas is directly injected into a combustion sub-chamber in order to completely separate rich mixture in the sub-chamber, suitable for ignition, from ultra-lean mixture in the main chamber. Mixture distributions in chambers with and without sub-chamber were numerically simulated at a variety of operating conditions. The commercial software of Fluent 16.0 was used to conduct simulations based on Reynolds averaged Navier-Stokes equations in an axial 2 dimensional numerical domain considering movements of piston. Non-reactive flow in the combustion chamber was simulated before the ignition timing at an engine speed of 2000 rpm. The turbulence model employed here is standard k-ε model. Air-fuel ratio is set with a lean condition of 30.

Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.

In practical lean burn engines used to date, the use of a stratified air-fuel configuration, with a comparatively rich mixture in the vicinity of the spark plugs, has resulted in the stable combustion of an overall lean mixture. However, because a comparatively rich mixture is burned during the first half of combustion, NOx emissions are not reduced sufficiently. This research focused on a form of lean burn with homogeneous premixture that would be able to balance low NOx emissions with combustion controllability. It is widely known that homogeneous lean premixed gas has poor flame propagation characteristics. To determine the dominant cause of this, this study investigated the combustion properties of a single-cylinder engine while changing the compression ratio and intake temperature. As a result, the primary cause of combustion fluctuation, the abnormal cycle has a low TDC temperature compared to that of other cycles.

As technologies for simultaneously maintaining the current high thermal efficiency of diesel engines and reducing particulate matter (PM) and nitrogen oxide (NOX) emissions, many new combustion concepts have been proposed, including premixed charge compression ignition (PCCI) and low-temperature combustion[1]. However, it is well known that since such new combustion techniques precisely control combustion temperatures and local air-fuel ratios by varying the amount of air, the exhaust gas recirculation (EGR) ratio and the fuel injection timing, they have the issues of being less stable than conventional combustion techniques and of performance that is subject to variance in the fuel and driving conditions. This study concerns a system that addresses these issues by detecting the ignition timing with in-cylinder pressure sensors and by controlling the fuel injection timing and the amount of EGR for optimum combustion onboard.

Clarifying the impact of ETBE 8% blended fuel on current Japanese gasoline vehicles, under the Japan Clean Air Program II (JCAPII) we conducted exhaust emission tests, evaporative emission tests, durability tests on the exhaust after-treatment system, cold starting tests, and material immersion tests. ETBE 17% blended fuel was also investigated as a reference. The regulated exhaust emissions (CO, HC, and NOx) didn't increase with any increase of ETBE content in the fuel. In durability tests, no noticeable increase of exhaust emission after 40,000km was observed. In evaporative emissions tests, HSL (Hot Soak Loss) and DBL (Diurnal Breathing Loss) didn't increase. In cold starting tests, duration of cranking using ETBE 8% fuel was similar to that of ETBE 0%. In the material immersion tests, no influence of ETBE on these material properties was observed.