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A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO3 (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn4+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/?-Al2O3 (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO2).
Technical Paper

Corrosion Resistance of Gas Shielded Metal Arc Welds with E-coat

1997-02-24
971008
Gas shielded metal arc welding is generally applied to automobile chassis parts. However, the weld parts with the E-coat show poor corrosion resistance. Therefore, the corrosion mechanism of the weld parts was investigated. The results found two reasons why the weld parts corroded faster than the non weld parts:(1)inadequate phosphating (2)defects in the E-coat. After detailed investigation, it was clarified that the major cause of poor corrosion resistance was the defects in the E-coat caused by slags formed on the surface of the weld bead. Therefore the amount of slag has to be decreased to improve the corrosion resistance. The effect of shielding gas composition on the amount of slag was then investigated. In the case of Ar and oxidizing gas mixture, the corrosion resistance improved as the oxidizing gas content decreased. This was due to the reduction of slags.
Technical Paper

Open-Loop Chestbands for Dynamic Deformation Measurements

1998-02-23
980857
Originally designed for measuring closed-loop contours such as those around a human thorax, the External Peripheral Instrument for Deformation Measurement (EPIDM), or chestband, was developed to improve the measurement of dummy and cadaver thoracic response during impact. In the closed-loop configuration, the chestband wraps around on itself forming a closed contour. This study investigates the use of the chestband for dynamic deformation measurements in an open-loop configuration. In the open-loop configuration, the chestband does not generally form a closed contour. This work includes enhanced procedures and algorithms for the calculation of chestband deformation contours including the determination of static and dynamic chestband contours under several boundary conditions.
Technical Paper

The Effect of Thermal Cycling on the Mechanical Properties of the Macro-Interface in Squeeze Cast Composites

1994-03-01
940810
Selectively reinforced, squeeze cast automotive pistons contain a boundary between the reinforced and unreinforced regions. This boundary is known as the macro-interface. Due to the difference in CTE between the composite and unreinforced matrix, the macro-interface can be the site of residual stress formation during cooling from the casting or heat treatment temperature. Subsequent thermal exposure, particularly thermal cycling, may produce cyclic stress at this interface causing it to experience fatigue. It has been found that matrix precipitates at the macro-interface and the aging behavior of the matrix also may play a role in defining the strength of the macro-interface during thermal cycling conditions.
Technical Paper

Development of Aluminum Powder Metallurgy Composites for Cylinder Liners

1994-03-01
940847
There are several all-aluminum cylinder blocks. A typical example is a mono-block cylinder of alusil alloy produced by low pressure die casting. This material's resistance to abrasion and seizure, however, is not satisfactory for motorcycle; in addition, long processing time is another disadvantage. To cope with these problems, the authors developed a light and highly productive all-aluminum cylinder block with a cast-in liner through die casting. The liner is made from powder metallurgy composite (PMC) with 3 to 5 % alumina and 0.5 to 3 % of graphite additives. The PMC reconciles abrasion resistance and machinability. The hardness deterioration of the composite due to the heat at die casting is avoided by using heat-resistant rapidly-solidified powders, made from an aluminum-silecon-iron alloy, for the matrix.
Technical Paper

Application of Aluminum for Automobile Chassis Parts

1991-02-01
910554
Several processes, such as casting, forging, and pressing, were used in the manufacturing of the Honda NSX's aluminum chassis. For casting, a high grade method which utilizes program control of mold temperature was developed and put into practical use. For optimum forging, a selection of cold and hot processes were investigated and a process to save energy during processing was pursued. As a result, an overall weight reduction of approximately 50% was achieved.
Technical Paper

Non-Destructive Measurement of Residual Strain in Connecting Rods Using Neutrons

2018-04-03
2018-01-1063
Increasing the strength of materials is effective in reducing weight and boosting structural part performance, but there are cases in where the residual strain generated during the process of manufacturing of high-strength materials results in a decline of durability. It is therefore important to understand how the residual strain in a manufactured component changes due to processing conditions. In the case of a connecting rod, because the strain load on the connecting rod rib sections is high, it is necessary to clearly understand the distribution of strain in the ribs. However, because residual strain is generally measured by using X-ray diffractometers or strain gauges, measurements are limited to the surface layer of the parts. Neutron beams, however, have a higher penetration depth than X-rays, allowing for strain measurement in the bulk material.
Technical Paper

Development of Pd-Only Catalyst for LEV III and SULEV30

2015-04-14
2015-01-1003
This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.
Technical Paper

Development of Gasoline Combustion Reaction Model

2013-04-08
2013-01-0887
Gasoline includes various kinds of chemical species. Thus, the reaction model of gasoline components that includes the low-temperature oxidation and ignition reaction is necessary to investigate the method to control the combustion process of the gasoline engine. In this study, a gasoline combustion reaction model including n-paraffin, iso-paraffin, olefin, naphthene, alcohol, ether, and aromatic compound was developed. KUCRS (Knowledge-basing Utilities for Complex Reaction Systems) [1] was modified to produce paraffin, olefin, naphthene, alcohol automatically. Also, the toluene reactions of gasoline surrogate model developed by Sakai et al. [2] including toluene, PRF (Primary Reference Fuel), ethanol, and ETBE (Ethyl-tert-butyl-ether) were modified. The universal rule of the reaction mechanisms and rate constants were clarified by using quantum chemical calculation.
Technical Paper

Development of Compact Fuel Pump Module for Motorcycles

2008-09-09
2008-32-0039
A compact, low-cost fuel pump module has been developed for use in motorcycles with a small-displacement engine. Various considerations are given to make the module as compact as possible. The pump motor, which is one of the major component parts, is down-sized specifically for applications to small-displacement engines. The pressure regulator uses a simple construction consisting only of a ball and a spring without a diaphragm. Especially noteworthy is that with the volume reduced by approximately 40% from the conventional pressure regulator while using the construction that reduces self-excited vibrations caused by fuel pressure pulsations, the pressure regulator contributes significantly to the down-sizing and cost reduction of the module. Furthermore, the down-sized module remarkably reduces the size of fuel pump mount surface, allowing a modification from the flat-surface sealing to the radial sealing.
Technical Paper

Development of a Small-Sized Multilayer Fuel Tank for Motorcycles and ATVs Complying with EPA Gasoline Permeation Controls

2008-09-09
2008-32-0041
As a result of recent EPA (U.S. Environmental Protection Agency) gasoline permeation control regulations, the fuel tanks on motorcycles and ATVs (All-Terrain Vehicles) are required to change to lower gasoline permeation performance on 2008 models. Therefore, we determined to use a multilayer plastic fuel tank. There are some molding issues that are peculiar to motorcycle and ATV fuel tanks. First, when the insert is blow molded, there is a reduction in welding strength. Second, peeling of the adhesion occurs on impact in the inserted parts. Third, saddle shapes with large ductility deformation are easy to be punctured during molding. Finally, the appearance of the fuel tank is not acceptable. In order to address the first issue, the welding performance, the drawdown of parison and the melting damage of insert parts were balanced, focusing attention to the temperatures of the parison and the insert.
Technical Paper

Development of Compound Coating that Reduces Permeation of Chloride Ion in Salty Water for Hexavalent-Chromium-Free Metal Gasket for PWC Engines

2008-09-09
2008-32-0047
A hexavalent-chromium-free metal gasket for PWC engines was developed to correspond to the ELV (End of Life Vehicle) directive. In order to enhance the adhesive property, the ion capture to trap the chloride ion, an anti-rust pigment to reform the chemical coating, and an inorganic sealer to stop the passage of chloride ion were added to the adhesive and rubber raw material. A good adhesive property and rubber physical property was obtained through the addition of an anticorrosive pigment. The rubber vulcanization condition in the manufacturing process was reviewed. As a result, without modifying the current compound coating line for mass-production, a gasket with a blistering resistance more than hexavalent chromium conversion coating equivalence and coating adhesion was developed when using salt water for engine cooling.
Technical Paper

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-04-16
2012-01-0365
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).
Technical Paper

Development of Aluminum Powder Metal Composite Material Suitable for Extrusion Process used for Cylinder Sleeves of Internal Combustion Engines

2014-04-01
2014-01-1002
There are a couple of ways to manufacture aluminum cylinder blocks that have a good balance between productivity and abrasion resistance. One of them is the insert-molding of a sleeve made of PMC (Powder Metal Composite) by the HPDC (High Pressure Die Casting) method. However, in this method, cracks are apt to occur on the surface when the PMC sleeve is extruded and that has been a restriction factor against higher extrusion speed. The authors attempted to raise this extrusion temperature by eliminating the Cu additive process from the aluminum alloy powder in order to raise its melting point by approximately 50 °C. This enabled the wall of the extruded sleeve to be thinner and the extrusion speed to be higher compared to those of a conventional production method while avoiding the occurrence of surface cracks.
Technical Paper

Development of a Target Sensitivity Function based A/F F/B Controller by Sensor Response Characteristics

2015-04-14
2015-01-1631
Recently, automotive emission regulations are being further tightened, such as the Tier III/LEV III in the U.S. As a result, reducing cost of after-treatment systems to meet these strict regulations has become an urgent issue, and then the demand for high-precision air-fuel ratio (A/F) control which can achieve this cost reduction is high [1]. On the other hand, in order to meet rapidly changing market needs, it is becoming difficult to keep enough development periods that enable sufficient calibration by trial-and-error, such as feedback-gain calibration. This leads to an increase in three-way catalytic converter costs in some cases. For these reasons, it is necessary to construct control system that can make full use of hardware capabilities, can shorten development periods regardless of the skill level of engineers.
Technical Paper

Technology to Enhance Deep-Drawability by Strain Dispersion Using Stress Relaxation Phenomenon

2015-04-14
2015-01-0531
When the strain is temporarily stopped during tensile testing of a metal, a stress relaxation phenomenon is known to occur whereby the stress diminishes with the passage of time. This phenomenon has been explained as the change of elastic strain into plastic strain. A technique was devised for deliberately causing strain dispersion to occur by applying the stress relaxation phenomenon during stamping. A new step motion that pause the die during forming was devised; it succeeded in modifying the deep-draw forming limit by a maximum of 40%. This new technique was verified through tensile and actual stamping tests. It was confirmed that the use of step motion causes the strain to disperse, thereby modifying the deep draw forming limit. The degree to which the forming limit is modified is dependent on the stop time and the temperature. Step motion technology increases the stampability of high-strength, forming-resistant materials and allows for expanded application of these materials.
Technical Paper

Influence of Driver Input on the Touchdown Conditions and Risk of Rollover in Case of Steering Induced Soil-Trip Rollover Crashes

2016-04-05
2016-01-1514
Some rollover testing methodologies require specification of vehicle kinematic parameters including travel speed, vertical velocity, roll rate, and pitch angle, etc. at the initiation of vehicle to ground contact, which have been referred to as touchdown conditions. The complexity of the vehicle, as well as environmental and driving input characteristics make prediction of realistic touchdown conditions for rollover crashes, and moreover, identification of parameter sensitivities of these characteristics, is difficult and expensive without simulation tools. The goal of this study was to study the sensitivity of driver input on touchdown parameters and the risk of rollover in cases of steering-induced soil-tripped rollovers, which are the most prevalent type of rollover crashes. Knowing the range and variation of touchdown parameters and their sensitivities would help in picking realistic parameters for simulating controlled rollover tests.
Technical Paper

Transmission-Mounted Power Control Unit with High Power Density for Two-Motor Hybrid System

2016-04-05
2016-01-1223
A second-generation power control unit (PCU) for a two-motor hybrid system is proposed. An optimally designed power module, which is a key component of the PCU, is applied to increase heat-resistant temperature, while the basic structure of the first generation is retained and the power semiconductor chip is directly cooled from the single side. In addition to the optimum design, by decreasing the power loss as well as increasing the heat-resistant temperature of the power semiconductors (IGBT: Insulated Gate Bipolar Transistor and FWD: Free Wheeling Diode), the proposed PCU has attained 25% higher power density and 23% smaller size compared to first-generation units, maintaining PCU efficiency (fuel economy). To achieve a high yield rate in the power module assembly process, a new screening technology is adopted at the initial stage of power module manufacturing.
Technical Paper

Development of Aluminium Hollow Subframe Using High-Pressure Die Casting

2016-04-05
2016-01-0406
High-tensile steel plates and lightweight aluminum are being employed as materials in order to achieve weight savings in automotive subframe. Closed-section structures are also in general use today in order to efficiently increase parts stiffness in comparison to open sections. Aluminum hollow-cast subframe have also been brought into practical use. Hollow-cast subframe are manufactured using sand cores in gravity die casting (GDC) or low-pressure die casting (LPDC) processes. Using these manufacturing methods, it is difficult to reduce product thickness, and the limitations of the methods therefore make the achievement of weight reductions a challenge. The research discussed in this paper developed a lightweight, hollow subframe technology employing high-pressure die casting (HPDC), a method well-suited to reducing wall thickness, as the manufacturing method. Hollow-casting using HPDC was developed as a method of forming water jackets for water-cooled automotive engines.
Technical Paper

The Structure of an Advanced Independent Rear Toe-Control System

2015-04-14
2015-01-1499
Honda announced an independent right and left rear toe control system (first generation) in 2013 and presented it as the world's first. As stated in a previous paper, “Independent Left and Right Rear Toe Control System,” with this system Honda has achieved a balance between an enjoyable driving experience in which handling is performed at the driver's will (“INOMAMA” handling) and stable driving performance.(1) This first generation is optimally designed to the vehicle specifications such as suspension axial force and steering gear ratio of the vehicle to which the system is applied. For more widespread application of independent rear toe control technology, a next generation system (second generation) has been developed, which achieves both cost reduction and flexible system performance which can be adapted to a variety of vehicles. The system development began by setting the required target performance with consideration for adaptation to various car models.
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