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The reduction of NOx in exhaust gas has been a major challenge in diesel engine development. For the NOx reduction issues, a new Lean NOx Catalyst (LNC) aftertreatment system has been developed by Honda. A feature of the LNC system is the method that is used to reduce NOx through an NH₃-Selective Catalytic Reduction (NH₃-SCR). In an LNC system NOx is adsorbed at lean conditions, then converted to NH₃ at rich conditions and subsequently reduced in the next lean phase. In recent years, as the efficiency of the diesel engine has improved, the exhaust gas temperatures have been reduced gradually. Therefore, the aftertreatment system needs to be able to purify NOx at lower temperatures. The development of a new LNC which has a high activity at low temperature has been carried out. For the improvement of the LNC three material improvements were developed. The first of these was the development of a NOx adsorbent which is matching the targeted exhaust gas temperatures.

Recently, automotive emission regulations are being further tightened, such as the Tier III/LEV III in the U.S. As a result, reducing cost of after-treatment systems to meet these strict regulations has become an urgent issue, and then the demand for high-precision air-fuel ratio (A/F) control which can achieve this cost reduction is high [1]. On the other hand, in order to meet rapidly changing market needs, it is becoming difficult to keep enough development periods that enable sufficient calibration by trial-and-error, such as feedback-gain calibration. This leads to an increase in three-way catalytic converter costs in some cases. For these reasons, it is necessary to construct control system that can make full use of hardware capabilities, can shorten development periods regardless of the skill level of engineers.

This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.