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In a previous study by the authors, austenite (γ phase) formed on the topmost of pulleys after long term operation of continuously variable transmission (CVT) [1]. In general, martensite arising from heat treatment forms on the surface of pulleys and gears. Therefore, the sliding surface has a body-centered cubic (BCC) metal structure, and transformation into and existence of austenite (γ phase) is difficult unless there is a thermal history exceeding the eutectoid point. For the verification of that possibility, it was crucial to obtain temperature variation on the sliding surface. The major problem for such measurements was rotation of parts inside an operating CVT. In this study, uniquely developed measurement system enabled non-contact temperature measurement near the contact portion. Results were substituted to heat conduction equation to predict the temperature at the exact contact portion.