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Atomization of fuel sprays is a key factor in controlling the combustion quality in the direct-injection engines. In this present work, the effect of saturation ratio (Rs) on the near nozzle spray patterns of ethanol was investigated using an ultra-high speed imaging technique. The Rs range covered both flash-boiling and non-flash boiling regions. Ethanol was injected from a single-hole injector into an optically accessible constant volume chamber at a fixed injection pressure of 40 MPa with different fuel temperatures and back pressures. High-speed imaging was performed using an ultrahigh speed camera (1 million fps) coupled with a long-distance microscope. Under non-flash boiling conditions, the effect of Rs on fuel development was small but observable. Clear fuel collision can be observed at Rs=1.5 and 1.0. Under the flash boiling conditions, near-nozzle spray patterns were significant different from the non-flash boiling ones.