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In order to comply with the stringent future emission mandates of automotive diesel engines it is essential to deploy a suitable combination of after treatment devices like diesel oxidation catalyst (DOC), diesel particulate filter (DPF) and DeNox converter (Lean NOx Trap (LNT) or Selective Catalytic reduction (SCR) system). Since arriving at a suitable strategy through experiments will involve deploying a lot of resources, development of well-tuned simulation models that can reduce time and cost is important. In the first phase of this study experiments were conducted on a single cylinder light duty diesel engine fitted with a diesel oxidation catalyst (DOC) at thirteen steady state mode points identified in the NEDC (New European Driving cycle) cycle. Inlet and exit pressures and temperatures, exhaust emission concentrations and catalyst bed temperature were measured. A one dimensional simulation model was developed in the commercial software AVL BOOST.