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In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

Swirling flows are very dominant in applied technical problems, especially in IC engines, and their prediction requires rather sophisticated modeling. An adaptive low-pass filtering procedure for the modeled turbulent length and time scales is derived and applied to Menter' original k - ω SST turbulence model. The modeled length and time scales are compared to what can potentially be resolved by the computational grid and time step. If the modeled scales are larger than the resolvable scales, the resolvable scales will replace the modeled scales in the formulation of the eddy viscosity; therefore, the filtering technique helps the turbulence model to adapt in accordance with the mesh resolution and the scales to capture.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

The flow field resulting from injecting a gas jet into a crossflow confined in a narrow square duct has been studied under steady regime using schlieren imaging and laser Doppler velocimetry (LDV). This transparent duct is intended to simulate the intake port of an internal combustion engine fueled by gaseous mixture, and the jet is issued from a round nozzle. The schlieren images show that the relative small size of the duct would confine the development of the transverse jet, and the interaction among jet and sidewalls strongly influences the mixing process between jet and crossflow. The mean velocity and turbulence fields have been studied in detail through LDV measurements, at both center plane and several cross sections. The well-known flow feature formed by a counter rotating vortex pair (CVP) has been observed, which starts to appear at the jet exit section and persists far downstream contributing to enhancing mixing process.

An experimental campaign is presented aiming at the characterization of thermal dissipation of batteries to be used on board of small satellites. A suitably designed device allows to manage automatically the orbital cycling simulation between battery cell charge and discharge. The cell thermal performance is characterized in various combinations of temperature, discharge current and Depth of Discharge. The gathered data are used for providing guidelines in the design of a family of Italian Small Satellites.

In the last years, as a response to the more and more restrictive emission legislation, new devices (SRC, DOC, NOx-trap, DPF) have been progressively introduced as standard components of modern after-treatment system for Diesel engines. In addition, the adoption of electrical heating is nowadays regarded with interest as an effective solution to promote the light-off of the catalyst at low temperature, especially at the start-up of the engine and during the low load operation of the engine typical of the urban drive. In this work, a state-of-the-art 48 V electrical heated catalyst is considered, in order to investigate its effect in increasing the abatement efficiency of a standard DOC. The electrical heating device considered is based on a metallic support, arranged in a spiral layout, and it is heated by the Joule effect due to the passage of the electrical current.

The s.i. combustion process and its corresponding pollutant formation are investigated by means of a quasiD approach and a CFD model. This work has been motivated by the need to better understand the reliability of such models and to assess their accuracies with respect to the prediction of engine performances and emissions. An extended dissertation about the fundamental mechanisms governing the pollutant formation in the turbulent premixed combustion which characterizes the s.i. engines is given. The conclusion of such analysis is the definition of a new reduced chemical scheme, based on the application of partial-equilibrium and steady-state assumptions for the radicals and the solution of a transport equation for each specie which is kinetically controlled. For this purpose the CFD code OpenFOAM [1, 2, 3] and the thermo-fluid dynamic code GASDYN [4, 5] have been applied and enhanced.

The transient heat transfer behavior of an automotive catalytic converter has been simulated with OpenFOAM in 1D. The model takes into consideration the gas-solid convective heat transfer, axial wall conduction and heat capacity effects in the solid phase, but also the chemical reactions of CO oxidation, based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters are the results of data in literature tuned by experiments. Simplified cases of constant flow rates and gas temperatures in the catalyst inflow have been chosen for a comprehensive analysis of the heat and mass transfer phenomena. The impact of inlet flow temperatures and inlet flow rates on the heat up characteristics as well as in the CO emissions have been quantified. A dimensional analysis is proposed and dimensionless temperature difference and space-time coordinates are introduced.

In this paper, computation fluid dynamics (CFD) simulations are performed to describe the effect of in-cylinder flow structures on the formation and oxidation of soot in a swirl-supported light-duty diesel engine. The focus of the paper is on the effect of swirl motion and injection pressure on late cycle soot oxidation. The structure of the flow at different swirl numbers is studied to investigate the effect of varying swirl number on the coherent flow structures. These coherent flow structures are studied to understand the mechanism that leads to efficient soot oxidation in late cycle. Effect of varying injection pressure at different swirl numbers and the interaction between spray and swirl motions are discussed. The complexity of diesel combustion, especially when soot and other emissions are of interest, requires using a detailed chemical mechanism to have a correct estimation of temperature and species distribution.

In this work, the possibility to perform a cold-flow simulation as a way to improve the accuracy of the starting conditions for a combustion simulation is examined. Specifically, a dual-fuel marine engine running on methanol/diesel and natural gas/diesel fueling conditions is investigated. Dual-fuel engines can provide a short-term solution to cope with the more stringent emission legislations in the maritime sector. Both natural gas and methanol appear to be interesting alternative fuels that can be used as main fuel in these dual-fuel engines. Nevertheless, it is observed that combustion problems occur at part load using these alternative fuels. Therefore, different methods to increase the combustion efficiency at part load are investigated. Numerical simulations prove to be very suitable hereto, as they are an efficient way to study the effect of different parameters on the combustion characteristics.

The characterization of a turbulent diesel spray combustion process has been carried out in a divided chamber diesel system with optical accesses. Laser Doppler Anemometry, spectral extinction and flame intensity measurements have been performed from U.V., to visible from the start of injection to the end of combustion, at fixed air/fuel ratio and different engine speeds. Spatial distribution of fuel and vapor as well as the ignition location and soot distribution have been derived in order to study the mechanism of the air-fuel interaction and the combustion process. The analysis of results has shown that the high swirling motion transports the fuel towards the left part of the chamber and breaks up the jet into small droplets of different sizes and accelerates the fuel vaporization. Then, chemical and physical overlapped phases were observed during the ignition delay, contributing both to autoignition.

In future decarbonized scenarios, hydrogen is widely considered as one of the best alternative fuels for internal combustion engines, allowing to achieve zero CO2 emissions at the tailpipe. However, NOx emissions represent the predominant pollutants and their production has to be controlled. In this work different strategies for the control and abatement of pollutant emissions on a H2-fueled high-performance V8 twin turbo 3.9L IC engine are tested. The characterization of pollutant production on a single-cylinder configuration is carried out by means of the 1D code Gasdyn, considering lean and homogeneous conditions. The NOx are extremely low in lean conditions with respect to the emissions legislation limits, while the maximum mass flow rate remains below the turbocharger technical constraint limit at λ=1 only.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.

The reduction of the catalyst light-off time at the engine cold start represents a key factor for the pollutant emissions control from vehicles tested on homologation cycles and real drive conditions. The adoption of heating strategies to increase the temperature of the catalytic substrate in the early phase of the engine start is regarded as a promising solution. The present study focuses on the application of electrical heated catalyst (EHC) in an after-treatment line for a spark-ignition gasoline engine. The analysis is carried out by means of an advanced CFD framework, which includes the modeling of catalytic reactions in the substrates and accounts for the thermal evolution of all the components included in the after-treatment system.