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In recent years the use of alternative fuels for internal combustion engines has had a strong push coming from both technical and economic-environmental aspects. Among these, gaseous fuels such as liquefied petroleum gas and natural gas have occupied a segment no longer negligible in the automotive industry, thanks to their adaptability, anti-knock capacity, lower toxicity of pollutants, reduced CO2 emissions and cost effectiveness. On the other hand, diesel engines still represent the reference category among the internal combustion engines in terms of fuel consumptions. The possibility offered by the dual fuel systems, to combine the efficiency and performance of a diesel engine with the environmental advantages of gaseous fuels, has been long investigated. However the simple replacement of diesel fuel with natural gas does not allow to optimize the performance of the engine due to the high THC emissions particularly at lower loads.