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Bio-derived fuels are drawing more and more attention in the internal combustion engine (ICE) research field in recent years. Those interests in use of renewable biofuels in ICE applications derive from energy security issues and, more importantly, from environment pollutant emissions concerns. High fidelity numerical study of engine combustion requires advanced computational fluid dynamics (CFD) to be coupled with detailed chemical kinetic models. This task becomes extremely challenging if real fuels are taken into account, as they include a mixture of hundreds of different hydrocarbons, which prohibitively increases computational cost. Therefore, along with employing surrogate fuel models, reduction of detailed kinetic models for multidimensional engine applications is preferred. In the present work, a reduced mechanism was developed for primary reference fuel (PRF) using the directed relation graph (DRG) approach. The mechanism was generated from an existing detailed mechanism.

Gasoline direct injection (GDI) engines are characterized by complex phenomena involving spray dynamics and possible spray-wall interaction. Control of mixture formation is indeed fundamental to achieve the desired equivalence ratio of the mixture, especially at the spark plug location at the time of ignition. Droplet impact on the piston or liner surfaces has also to be considered, as this may lead to gasoline accumulation in the liquid form as wallfilm. Wallfilms more slowly evaporate than free droplets, thus leading to local enrichment of the charge, hence to a route to diffusive flames, increased unburned hydrocarbons formation and particulate matter emissions at the exhaust. Local heat transfer at the wall obviously changes if a wallfilm is present, and the subtraction of the latent heat of vaporization necessary for secondary phase change is also an issue deserving a special attention.