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Technical Paper

Influence of Catalyst Performance on Car Emissions in Urban Congested Traffic

A reason of the lack of agreement between measured pollutants concentration in the air of urban areas and vehicle pollutant emissions evaluated by available emission models is the fact that catalyst performance variability is not considered. In this paper, an experimental study on the effect of performance variability of catalyst on emissions is presented. Average emissions have been measured using driving cycles representative of different levels of urban traffic, determined by statistical methods on the basis of data detected on-road by an instrumented car. For each driving cycle, representative of a certain traffic level, different thermal starting conditions of catalyst have been tested. These conditions have been determined by the characterization of catalyst performance at steady state and are representative of real catalyst conditions experienced on the road.
Technical Paper

Experimental Characterization of an Ethanol DI - Gasoline PFI and Gasoline DI - Gasoline PFI Dual Fuel Small Displacement SI Engine

The aim of the paper is the comparison of the performance, gaseous and particle emissions from different injection configurations and fuels. The engine was operated in port fuel injection (PFI), direct injection (DI) and dual fuel (DF). For DF, ethanol DI-gasoline PFI and gasoline DI-gasoline PFI strategies were performed to discern the effect of injection strategy from the effect of the fuel. The experimental activity was carried out in a small displacement single cylinder engine, representative of 2-3 wheel vehicle engines or of 3-4 cylinder small displacement automotive engines. It was equipped with a prototype gasoline direct injection (GDI) head. The tests were carried out at 3000 rpm, 4000 rpm and 5000 rpm full load. The investigated engine operating conditions are representative of the homologation urban driving cycle. The gaseous and particle emissions were measured at the exhaust by means of a gas analyzer and a smoke meter.
Technical Paper

Fuel Injection Effect on In-cylinder Formation and Exhaust Emission of Particulate from a 4-Stroke Engine for 2-Wheel Vehicles

The small engine for two-wheel vehicles has generally high possibility to be optimized at low speeds and high loads. In these conditions fuel consumption and pollutants emission should be reduced maintaining the performance levels. This optimization can be realized only improving the basic knowledge of the thermo-fluid dynamic phenomena occurring during the combustion process. It is known that, during the fuel injection phase in PFI SI engines, thin films of liquid fuel can form on the valves surface and on the cylinder walls. Successively the fuel films interact with the intake manifold and the combustion chamber gas flow. During the normal combustion process, it is possible to achieve gas temperature and mixture strength conditions that lead to fuel film ignition. This phenomenon can create diffusion-controlled flames that can persist well after the normal combustion event. These flames induce the emission of soot and unburned hydrocarbons.
Technical Paper

Experimental and Modeling Study of a Diesel Oxidation Catalyst (DOC) under Transient and CPF Active Regeneration Conditions

In this study, a DOC catalyst was experimentally studied in an engine test cell with a2010 Cummins 6.7L ISB diesel and a production aftertreatment system. The test matrix consisted of steady state, active regeneration with in-cylinder fuel dosing and transient conditions. Conversion efficiencies of total hydrocarbon (THC), CO, and NO were quantified under each condition. A previously developed high-fidelity DOC model capable of predicting both steady state and transient active regeneration gaseous emissions was calibrated to the experimental data. The model consists of a single 1D channel where mass and energy balance equations were solved for both surface and bulk gas regions. The steady-state data were used to identify the activation energies and pre-exponential factors for CO, NO and HC oxidation, while the steady-state active regeneration data were used to identify the inhibition factors. The transient data were used to simulate the thermal response of the DOC.
Technical Paper

Optical Investigation of Post-injection Strategy Impact on the Fuel Vapor within the Exhaust Line of a Light Duty Diesel Engine Supplied with Biodiesel Blends

Multi-wavelength ultraviolet-visible extinction spectroscopy was applied to follow the evolution of fuel vapor injected by post-injection along the exhaust line of a common-rail turbocharged direct-injection diesel engine at moderate speed and load. The exhaust line was specifically designed and customized to allow the insertion of the optical access upstream of the Diesel Oxidation Catalyst. During the experimental campaign, the engine was fuelled with commercial B5 fuel and a B30 v/v blend of RME and ultra low sulfur diesel, monitoring emissions upstream of the catalyst and exhaust gas temperature across the catalyst. Tests were performed at different engine operating conditions with particular attention to moderate speed and load.
Technical Paper

Optimization of Control Parameters for a Heavy-Duty CNG Engine via Co-Simulation Analysis

Internal combustion engines for vehicle propulsion are more and more sophisticated due to increasingly restrictive environmental regulations. In case of heavy-duty engines, Compressed Natural Gas (CNG) fueling coupled with Three-Way Catalyst (TWC) and Exhaust Gas Recirculation (EGR) can help in meeting the imposed emission limits and preventing from thermal stress of engine components. To cope with the new issues associated with the more complex hardware and to improve powertrain performance and reliability and after-treatment efficiency, the engine control strategies must be reformulated. The paper focuses on the steady-state optimization of control parameters for a heavy-duty engine fueled by CNG and equipped with turbocharger and EGR. The optimization analysis is carried out to design EGR, spark timing and wastegate control, aimed at increasing fuel economy while reducing in-cylinder temperature to prevent from thermal stress of engine components.
Technical Paper

Adequacy of Reduced Order Models for Model-Based Control in a Urea-SCR Aftertreatment System

Model-based control strategies are important for meeting the dual objective of maximizing NOx reduction and minimizing NH3 slip in urea-SCR catalysts. To be implementable on the vehicle, the models should capture the essential behavior of the system, while not being computationally intensive. This paper discusses the adequacy of two different reduced order SCR catalyst models and compares their performance with a higher order model. The higher order model assumes that the catalyst has both diffusion and reaction kinetics, whereas the reduced order models contain only reaction kinetics. After describing each model, its parameter identification and model validation based on experiments on a Navistar I6 7.6L engine are presented. The adequacy of reduced order models is demonstrated by comparing the NO, NO2 and NH3 concentrations predicted by the models to their concentrations from the test data.
Technical Paper

A Calculation Procedure for the Evaluation of Cold Emissive Behavior of High-Performance Motorcycles

All the experimental investigations performed in the last years on newly sold motorcycles, equipped with a three-way catalyst and electronic mixture control, clearly indicate that CO and HC cold additional emissions, if compared with those exhausted in hot conditions, represent an important proportion of total emissions. Consequently, calculation programs for estimating emissions from road transports for air quality modeling in dedicated local areas should take into consideration this effect. From this motivation, an experimental activity on motorcycles cold emissive behavior is being jointly conducted by Istituto Motori of the National Research Council (IM-CNR) and the Department of Mechanic and Energetic (DiME) of the University of Naples.
Technical Paper

Effects of Ethanol and Gasoline Blending and Dual Fueling on Engine Performance and Emissions.

Ethanol is the most promising alternative fuel for spark ignition (SI) engines, that is blended with gasoline, typically. Moreover, in the last years great attention is paid to the dual fueling, ethanol and gasoline are injected simultaneously. This paper aims to analyze the better methods, blending or dual fueling in order to best exploit the potential of ethanol in improving engine performance and reducing pollutant emissions. The experimental activity was carried out in a small displacement single cylinder engine, representative of 2-3 wheel vehicle engines or of 3-4 cylinder small displacement automotive engines. It was equipped with a prototype gasoline direct injection (GDI) head. The tests were carried out at 3000, 4000, and 5000 rpm full load. The investigated engine operating conditions are representative of the European homologation urban driving cycle.
Technical Paper

Solutions to the Clean Snowmobile Challenge - What Works?

The Society of Automotive Engineers' (SAE) Clean Snowmobile Challenge 2004 (CSC 2004) was held at Michigan Technological University in Houghton, Michigan, from March 15 - 20, 2004. The Clean Snowmobile Challenge has been a competition in the SAE Collegiate Design Series since 2000, and began in Jackson Hole, Wyoming, as a response to rising concerns about snowmobiling in environmentally-sensitive areas. Teams from fifteen universities competed in CSC 2004. The winning snowmobile (sled) was developed by the University of Wisconsin, Madison, and featured a four-stroke engine with electronic fuel injection (EFI), a two-stage tuned muffler, and catalytic exhaust aftertreatment. A hybrid-electric design was used to increase the snowmobile's powertrain output and improve acceleration. [8] Teams should be competitive in all events to gain enough points to win the competition.
Technical Paper

The Effect of a Diesel Oxidation Catalyst and a Catalyzed Particulate Filter on Particle Size Distribution from a Heavy Duty Diesel Engine

The effect of a Johnson Matthey catalyzed continuously regenerating technology™ (CCRT®) filter on the particle size distribution in the raw exhaust from a 2002 Cummins ISM-2002 heavy duty diesel engine (HDDE) is reported at four loads. A CCRT® (henceforth called DOC-CPF) has a diesel oxidation catalyst (DOC) upstream (UP) of a catalyzed particulate filter (CPF). The particle size data were taken at three locations of UP DOC, downstream (DN) DOC and DN CPF in the raw exhaust in order to study the individual effect of the DOC and the CPF of the DOC-CPF on the particle size distribution. The four loads of 20, 40, 60 and 75% loads at rated speed were chosen for this study. Emissions measurements were made in the raw exhaust chosen to study the effect of nitrogen dioxide and temperature on particulate matter (PM) oxidation in the CPF at different engine conditions, exhaust and carbonaceous particulate matter (CPM) flow rates.
Technical Paper

The Effect of a Diesel Oxidation Catalyst and a Catalyzed Particulate Filter on the Emissions from a Heavy Duty Diesel Engine

The objective of this research was to study the effects of a CCRT®, henceforth called Diesel Oxidation Catalyst - Catalyzed Particulate Filter (DOC-CPF) system on particulate and gaseous emissions from a heavy-duty diesel engine (HDDE) operated at Modes 11 and 9 of the old Environmental Protection Agency (EPA) 13-mode test cycle Emissions characterized included: total particulate matter (TPM) and components of carbonaceous solids (SOL), soluble organic fraction (SOF) and sulfates (SO4); vapor phase organics (XOC); gaseous emissions of total hydrocarbons (HC), carbon monoxide (CO), oxides of nitrogen (NOx), nitric oxide (NO) and nitrogen dioxide (NO2), oxygen (O2) and carbon dioxide (CO2); and particle size distributions at normal dilution ratio (NDR) and higher dilution ratio (HDR). Significant reductions were observed for TPM and SOL (>90%), SOF (>80%) and XOC (>70%) across the DOC-CPF at both modes.
Technical Paper

A Study of the Filtration and Oxidation Characteristics of a Diesel Oxidation Catalyst and a Catalyzed Particulate Filter

An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.
Technical Paper

Experimental and Modeling Results Comparing Two Diesel Oxidation Catalyst - Catalyzed Particulate Filter Systems

Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.
Technical Paper

An Experimental and Numerical Study of the Performance Characteristics of the Diesel Oxidation Catalyst in a Continuously Regenerating Particulate Filter

A one-dimensional model simulating the oxidation of CO, HC, and NO was developed to predict the gaseous emissions downstream of a diesel oxidation catalyst (DOC). The model is based on the conservation of mass, species, and energy inside the DOC and draws on past research literature. Steady-state experiments covering a wide range of operating conditions (exhaust temperatures, flow rates and gaseous emissions) were performed, and the data were used to calibrate and validate the model. NO conversion efficiencies of 50% or higher were obtained at temperatures between 300°C and 350°C. CO conversion efficiencies of 85% or higher and HC conversion efficiencies of 75% or higher were found at every steady state condition above 200°C. The model agrees well with the experimental results at temperatures from 200°C to 500°C, and volumetric flow rates from 8 to 42 actual m3/min.
Technical Paper

The Effects of Two Catalyzed Particulate Filters on Exhaust Emissions from a Heavy Duty Diesel Engine: Filtration and Particulate Matter Oxidation Characteristics Studied Experimentally and Using a 1- D 2- Layer Model

A 1-D 2-layer model developed previously at MTU was used in this research to predict the pressure drop, filtration characteristics and various properties of the particulate filter and the particulate deposit layer. The model was used along with dilute emission data to characterize two catalyzed particulate filters (CPFs) having different catalyst loading and catalyst application processes. The model was calibrated and validated with data obtained from steady state experiments conducted using a 1995 Cummins M11-330E heavy-duty diesel engine with manual EGR with different fuels for the two different CPFs. The two different catalyzed particulate filters were CPF III (5 gms/ft3 Pt) and CPF V (50 gms/ft3 Pt). Both the CPFs had cordierite substrates with CPF III and CPF V had MEX and NEX catalyst type formulation respectively. The CPF III filter was catalyzed using a solution-impregnated process while the CPF V filter was catalyzed using a wash coat process.
Journal Article

Water Injection: a Technology to Improve Performance and Emissions of Downsized Turbocharged Spark Ignited Engines

Knock occurrence and fuel enrichment, which is required at high engine speed and load to limit the turbine inlet temperature, are the major obstacles to further increase performance and efficiency of down-sized turbocharged spark ignited engines. A technique that has the potential to overcome these restrictions is based on the injection of a precise amount of water within the mixture charge that can allow to achieve important benefits on knock mitigation, engine efficiency, gaseous and noise emissions. One of the main objectives of this investigation is to demonstrate that water injection (WI) could be a reliable solution to advance the spark timing and make the engine run at leaner mixture ratios with strong benefits on knock tendency and important improvement on fuel efficiency.
Journal Article

Model-Based Estimation and Control System Development in a Urea-SCR Aftertreatment System

In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.