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This study makes use of the detailed mechanisms of n-heptane combustion, from gas reactions to soot particle formation and oxidation, and a two-stage model based on the CHEMKIN reactor network is developed and used to investigate the trade-off between soot and NOx emissions. The effects of the equivalence ratio, EGR, ambient pressure and temperature, and initial particle diameter are observed for various residence times. The results show that high rates of NOx formation are unavoidable under conditions where high reduction rates of soot particles are obtained. This suggests that suppression of the amount of soot during the formation stage is essential for simultaneous reductions in engine-out soot and NOx emissions.

Further improvement in fuel consumption is needed for diesel engines to address regulatory requirement particularly for heavy duty diesel in Japan enforced in 2015, in addition to the compliance to the regulatory requirements for exhaust emission, which seems to be more stringent in future. The authors have participated in the project of “Comprehensive Technological Development of Innovative, Next-Generation, Low-Pollution Vehicles” organized by New Energy and Industrial Technology Development Organization (NEDO), and innovative devices such as multi stage boosting system, ultra high-pressure fuel injection system and variable valve actuation (camless) system had been developed in this project from a standpoint of simultaneous improvement of fuel consumption and exhaust emission. In camless system, intake and exhaust valves are driven by hydraulic pressure. So, fully flexible setting of opening and closure timings and lift of the intake and exhaust valves is possible.

Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.

The objective of this program was to improve the HCCI combustion process on a single-cylinder VCR engine by calibrating engine and HCCI operation specific factors such as EGR flow rates, intake air pressure, intake air temperature, compression ratio, etc. Due to the large number of factors to be investigated, a statistical design of experiments method (DoE) was utilized in order to reduce the number of test combinations in the calibration test matrix and, thus, the duration of the engine calibration task. Upon completion of the HCCI engine calibration, the engine was operated through a steady-state test matrix representing vehicle certification test cycles. Weighting factors for each of the test points were applied to estimate the engine performance and emissions in respect to certification requirements.

Water and diesel fuel emulsions containing 13% and 26% water by volume were investigated in a modern diesel engine with relatively early pilot injection, supercharging, and cooled EGR. The heat release from the pilot injection with water emulsions is retarded toward the top dead center due to the poor ignitability, which enables larger pilot and smaller main injection quantities. This characteristic results in improvements in the thermal efficiency due to the larger heat release near the top dead center and the smaller afterburning. With the 26% water emulsion, mild, smokeless, and very low NOx operation is possible at an optimum pilot injection quantity and 15% intake oxygen with EGR at or below 0.9 MPa IMEP, a condition where large smoke emissions are unavoidable with regular unblended diesel fuel. Heat transfer analysis with Woschni's equation did not show the decrease in cooling loss with the water emulsion fuels.

Combustion and exhaust gas emissions of alcohol and vegetable oil blends including a 20% ethanol + 40% 1-butanol + 40% vegetable oil blend and a 50% 1-butanol + 50% vegetable oil blend were examined in a single cylinder, four-stroke cycle, 0.83L direct injection diesel engine, with a supercharger and a common rail fuel injection system. A 50% diesel oil + 50% vegetable oil blend and regular unblended diesel fuel were used as reference fuels. The boost pressure was kept constant at 160 kPa (absolute pressure), and the cooled low pressure loop EGR was realized by mixing with a part of the exhaust gas. Pilot injection is effective to suppress rapid combustion due to the lower ignitability of the alcohol and vegetable oil blends. The effects of reductions in the intake oxygen concentration with cooled EGR and changes in the fuel injection pressure were investigated for the blended fuels.

Port injection of ethanol addition as an ignition inhibitor was implemented to control ignition timing and expand the operating range in DME fueled HCCI combustion. The ethanol reduced the rate of low-temperature oxidation and consequently delayed the onset of the high-temperature reaction with ultra-low NOx over a wide operating range. Along with the ethanol addition, changes in intake temperature, overall equivalence ratio, and engine speed are investigated and shown to be effective in HCCI combustion control and to enable an extension of operation range. A chemical reaction analysis was performed to elucidate details of the ignition inhibition on low-temperature oxidation of DME-HCCI combustion.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

Various premixed diesel combustion concepts are suggested as the way of simultaneous reduction of NOx and PM emission from diesel engines. However, every combustion concept has common problems, such as difficulty of ignition timing control, a great deal of HC and CO emissions and limiting the operation region to low load operation. The purpose of this study is to expand the operation region of Premixed Compression Ignition (PCI) combustion, which is a premixed diesel combustion concept that realizes the fuel injection around the top dead center. As a result of examining it with EGR, supercharging operation and low compression ratio piston, PCI combustion region was expanded to cover higher load operation. And the high load region was limited by not only stoichiometric air fuel ratio but also permissible maximum in-cylinder pressure.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Our research objective is to clarify the effect of the utilization of diesel fuels made from unconventional petroleum sources (GTL, Tar Sand, etc.) on the latest vehicle‛s emission and performance. The target properties studied are mainly cetane number and cyclic compounds. Two diesel vehicles and one engine were used in this study. Varieties of transient driving modes were selected for better understanding under real world driving in the emission test. Startability and operability are examined in the vehicle performance test. It was revealed that the tail-pipe emission from a J-2003 reg-compliant vehicle and the engine-out emission from a J-2005 reg-compliant engine used in this study were changed by cetane number and cyclic compound. For J-2003 reg-compliant vehicle, the decrease in cetane number led to the increase in emissions of THC, CO and NOx, while the increase in cyclic compounds led to increase in emissions of PM, THC, CO and NOx.

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

It has been found that over Rh/a specified support NOx is eliminated using rich/lean excursions in a different reaction mechanism from a Lean NOx Trap system, where NO is decomposed into nitrogen and oxygen. The contribution of the transient NOx direct decomposition to NOx elimination depends on both reaction conditions and supports. 0.1-0.5wt%Rh and 0.5wt%Pd/a specified support: X can mainly catalyze the transient NO decomposition. On the other hand, on another Rh-based catalyst NO reduction proceeds mainly in the Lean NOx trap system. As expected from the NO elimination mechanism, the newly developed catalyst has shown a high tolerance against SOx.

Time resolved changes in unburned hydrocarbon emissions and their components were investigated in a DI diesel engine with a specially developed gas sampling system and gas chromatography. The tested transient operations include starting and increasing loads. At start-up with high equivalence ratios the total hydrocarbon (THC) at first increased, and after a maximum gradually decreased to reach a steady state value. Reducing the equivalence ratio of the high fueling at start-up and shortening the high fueling duration are effective to reduce THC emissions as long as sufficient startability is maintained. Lower hydrocarbons, mainly C1-C8, were the dominant components of the THC and mainly determined the THC behavior in the transient operations while the proportion of hydrocarbon (HC) components did not significantly change. The unregulated toxic substances, 1,3 butadiene and benzene were detected in small quantities.

Increasing CO2 emissions from vehicles is becoming a major concern in automotive society, and variety of future types of cars are intensively investigated. However it is not clear which level of performance and cost must be achieved for the future cars to be available in a market and how much percentage of cars is necessary to be replaced by the future cars for the conservation of environment. The objective of this paper is to evaluate the possibility of market growth of future cars, as hybrid cars, electric vehicles and fuel cell cars, based on the performance and economic aspects. This paper investigates the emission reduction potential of these vehicles, and also compares the composition of vehicle types and emissions for a variety of scenarios of consumer characteristics, economic growth, fuel price, performance of cars, and carbon tax control measures. A model of user preference of cars was established from the statistic analysis of past data.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

1 A novel analysis approach called “Regression Density method” was developed for better understanding of fuel property effects on exhaust emission. The approach was applied to diesel emission data obtained in JCAP programs and emission models were conducted to analyze the effects of fuel properties and engine conditions on emissions. By introducing this analysis method, the relationship between density factor and aromatics factor (chemical composition factor) was identified, however, they have been reported previously as dominant factors in fuel properties. The effects of engine conditions and fuel properties on emissions were investigated quantitatively based on the statistically conducted emission models to clarify universal ways to emission reduction. The mechanism of emission formation of vehicles and engines with characteristic behavior was also examined.