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Exhaust gas from the diesel engine contains particulate matter (PM) of soot that affects human health and the environment. For the reduction of the emission of the PM, the diesel particulate filter (DPF) is placed in the exhaust system. The pressure drops increases with the PM deposit quantity in the DPF, which results in the burden of the engine. Therefore, the PM should be removed regularly by oxidation process called regeneration. Consumption of fuel is improved by optimizing the timing of regeneration. However, it is difficult to visualize the behavior of PM trapping and oxidation. We have proposed a series of models from PM deposition to the oxidation process in the DPF. In this study, the behavior of deposition and oxidation of PM in the DPF with a catalyst are calculated. The numerical calculations are performed to estimate PM deposition-oxidation process within the DPF. The results are obtained using the simplified model constructed in this study.

Further improvement in fuel consumption is needed for diesel engines to address regulatory requirement particularly for heavy duty diesel in Japan enforced in 2015, in addition to the compliance to the regulatory requirements for exhaust emission, which seems to be more stringent in future. The authors have participated in the project of “Comprehensive Technological Development of Innovative, Next-Generation, Low-Pollution Vehicles” organized by New Energy and Industrial Technology Development Organization (NEDO), and innovative devices such as multi stage boosting system, ultra high-pressure fuel injection system and variable valve actuation (camless) system had been developed in this project from a standpoint of simultaneous improvement of fuel consumption and exhaust emission. In camless system, intake and exhaust valves are driven by hydraulic pressure. So, fully flexible setting of opening and closure timings and lift of the intake and exhaust valves is possible.

Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.

Study of DME diesel engines was conducted to improve fuel consumption and emissions of its. Additionally, DME trucks were built for the promotion and the road tests of these trucks were executed on EFV21 project. In this paper, results of diesel engine tests and DME truck driving tests are presented. As for DME diesel engines, the performance of a DME turbocharged diesel engine with LPL-EGR was evaluated and the influence of the compression ratio was also explored. As for DME trucks, a 100,000km road test was conducted on a DME light duty truck. After the road test, the engine was disassembled for investigation. Furthermore, two DME medium duty trucks have been developed and are now the undergoing practical road testing in each area of two transportation companies in Japan.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Various premixed diesel combustion concepts are suggested as the way of simultaneous reduction of NOx and PM emission from diesel engines. However, every combustion concept has common problems, such as difficulty of ignition timing control, a great deal of HC and CO emissions and limiting the operation region to low load operation. The purpose of this study is to expand the operation region of Premixed Compression Ignition (PCI) combustion, which is a premixed diesel combustion concept that realizes the fuel injection around the top dead center. As a result of examining it with EGR, supercharging operation and low compression ratio piston, PCI combustion region was expanded to cover higher load operation. And the high load region was limited by not only stoichiometric air fuel ratio but also permissible maximum in-cylinder pressure.

Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.

NOx emitted from diesel is one of the main air pollutants for most countries. To reduce the emission of NOx could promote to diffuse diesel vehicles. A NOx storage/reduction (NSR) catalyst has been developed for the diesels. The catalyst for NSR is strongly poisoned by sulfur. We have found good reaction of CaCO3 with sulfur dioxide by using a thermogravimetry. We obtained desulfurization breakthrough characteristic for the sample of the CaCO3 which is washcoated on the monolith. As a result, this sample which has specific surface area, of 100 m2/g, absorbed SO2 about 0.43 ~ 0.45 g−SO2/g−CaCO3. In this experimental condition, The conversion of the sulfate does not depend on the amount of the supported CaCO3. The absorption efficiency of these samples were more than 99.4%. According to this result, it was found that the necessary amount of the absorbent was supposed to be 0.538 kg or 2.1 L for 100,000 km running.

It has been found that over Rh/a specified support NOx is eliminated using rich/lean excursions in a different reaction mechanism from a Lean NOx Trap system, where NO is decomposed into nitrogen and oxygen. The contribution of the transient NOx direct decomposition to NOx elimination depends on both reaction conditions and supports. 0.1-0.5wt%Rh and 0.5wt%Pd/a specified support: X can mainly catalyze the transient NO decomposition. On the other hand, on another Rh-based catalyst NO reduction proceeds mainly in the Lean NOx trap system. As expected from the NO elimination mechanism, the newly developed catalyst has shown a high tolerance against SOx.

1 A novel analysis approach called “Regression Density method” was developed for better understanding of fuel property effects on exhaust emission. The approach was applied to diesel emission data obtained in JCAP programs and emission models were conducted to analyze the effects of fuel properties and engine conditions on emissions. By introducing this analysis method, the relationship between density factor and aromatics factor (chemical composition factor) was identified, however, they have been reported previously as dominant factors in fuel properties. The effects of engine conditions and fuel properties on emissions were investigated quantitatively based on the statistically conducted emission models to clarify universal ways to emission reduction. The mechanism of emission formation of vehicles and engines with characteristic behavior was also examined.

Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.

Premixed diesel combustion was performed and various characteristics examined with fuel injection timing near top dead center (TDC). A lean and uniform fuel-air mixture was found to during 25° C.A. with a narrow injection angle (27.5° with respect to horizontal), shallow dish combustion chamber, and low cetane number fuel (CN=19). These conditions enabled low NOx combustion in no exhaust gas re-circulation (EGR), despite fuel injection timing around 25° BTDC. Furthermore, HC emissions were lower than with premixed diesel combustion of the early injection type. Because fuel injection timing was near TDC, the volume of the mixture dispersed to a squish area was decreased. This combustion mode was also achieved with a high-cetane fuel (conventional diesel fuel) and high EGR rate conditions. However, in this case, it was difficult to adjust the ignition timing near top dead center. This combustion system also showed good performance in conventional diesel combustion mode.

In order to reduce fine particle emission, a diesel particulate filter (DPF) has begun to be equipped to a diesel engine. During regeneration of DPF, nanoparticles are known to be formed downstream of DPF. VOCs emission during regeneration is of interest in view of toxicity and formation mechanism of nanoparticles. A heavy duty diesel engine equipped with DPF was investigated to measure particle and VOCs emissions using PTR-TOFMS (Proton Transfer Reaction - Time of Flight Mass Spectrometer). PTR-TOFMS is a new on-line mass spectrometer using chemical ionization and its application to engine exhaust measurements is new. During active regeneration of the DPF, fine particle emission was increased by nucleation. But VOCs as well as THC emissions increased prior to particle increase. After the regeneration the particle and VOCs emissions decreased immediately to the level of normal operation.

Urea/SCR systems have been proven effective at reducing NOx over a wide range of operating conditions on mid/heavy duty diesel vehicles. However, design changes due to reduction in the size of modern compact Urea/SCR systems and lower exhaust temperature have increased the possibility of urea deposit formation. Urea deposits are formed when urea in films and droplets undergoes undesirable secondary reactions and generate by-products such as ammelide, biuret and cyanuric Acid (CYA). Ammelide and CYA are difficult to decompose which lead to the formation of solid deposits on the surface. This phenomenon degrades the performance of the after treatment system by decreasing overall mixing efficiency, lowering de-NOx efficiency and increasing pressure drop. Therefore, mitigating urea deposits is a primary design goal of modern diesel after-treatment systems.

Supercharging as the method of increasing the output of diesel engines has a long history. Recently, because the potential for lower exhaust emissions for a given power output, supercharging has been considered as a method to reach increasingly strict emissions standards. Some research investigating the effects of supercharging has shown favorable results in terms of emissions(e.g.[1][2][3] *). Also some fundamental studies have examined the effect of ambient pressures on the characteristics of spray and ignition in constant volume combustion borb[4][5][6][7]. However, for further improvement of combustion when utilizing supercharging, more detailed information inside of the combustion chamber is needed about the effects of supercharging on fuel spray and combustion. In order to gather this information, it is necessary to observe the processes within the combustion chamber of a supercharged engine.

An experimental study aiming to investigate the effects of combustion chamber geometry on combustion process has been carried out in an optically accessible DI diesel engine. The combustion processes of three different chamber geometries, included the production type, were revealed and the flame movement behaviors such as the distribution of flame velocity vectors and the averaged flame velocity inside and outside the combustion chamber were measured by means of a cross-correlation method. Meanwhile, an endoscope system was used to acquire information about the distribution of flames inside and outside the chamber. BY comparing the flame movement and distribution between different chambers and nozzle protrusions, the results showed that; The chamber geometry has significant effect on the flame velocity, the flame velocities of the reentrant chamber were larger than that of the dish chamber during expansion period.

It is well known that a high-pressure fuel injection is effective for the reduction in particulates and smoke emissions. Exhaust gas recirculation (EGR) is effective for the reduction in NOX emission. In this study an experiment aiming to understand more comprehensive combustion under the condition of EGR and high-pressure fuel injection was carried out by using gas sampling method for the purpose of understanding what occurred inside the spray before and after combustion. The number of combustion cycles in this engine can be controlled in order to change EGR conditions by adjusting the residual gas concentration in the cylinder. Main results were: (1) Close to the nozzle tip, the sampling gas data showed little reaction which implies that combustion never occurs in this area during the injection period. (2) In the case of high-pressure fuel injection O2 concentration decreased faster and air dilution was more active and earlier.

This paper describes a method for effectively reducing a level of idling vibration in heavy-duty trucks, which has been the point at issue lately. In this method, the vibration level is significantly reduced by using a full vehicle model, which is made by finite elements, and varying parameters to study effects. In order to achieve high accuracy, engine excitation forces calculated from the measured fluctuation in the flywheel angular velocity are input to the model. An effective use of this method in an early development stage has enabled us to reduce development cost and the lead-time.

This paper introduced a very simple method to measure the liquid phase of spray in an optically accessible DI diesel engine. Particular attention was paid to easy usage and maintaining the compression ratio of the real engine. As a result, a less-expensive 4 W argon laser was used as the beam source and an E-10 high-speed camera was used for continuously observing the elastic-scatter liquid phase image. Meanwhile, the compression ratio can be kept as the real engines by this method. Through this method, the effects such as injection pressure, nozzle specification, intake air boost and temperature on liquid phase penetration before ignition were investigated. Reducing nozzle hole diameter decreased the length of the liquid phase. Increasing injection pressure hastened the evolution of liquid phase, while the liquid phase length varied complexly. Increasing intake air boost considerably shortened the liquid phase penetration and ignition delay.