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Polymers are one of the major constituents in electrical components. A study investigating pre-combustion off-gassing and particle release by polymeric materials over a range of temperatures can provide an understanding of thermal degradation prior to failure which may result in a fire hazard. In this work, we report simultaneous measurements of pre-combustion vapor and particle release by heated polymeric materials. The polymer materials considered for the current study are silicone and Kapton. The polymer samples were heated over the range 20 to 400°C. Response to vapor releases were recorded using the JPL Electronic Nose (ENose) and Industrial Scientific's ITX gas monitor configured to detect hydrogen chloride (HCl), carbon monoxide (CO) and hydrogen cyanide (HCN). Particle release was monitored using a TSI P-TRAK particle counter.

Solar proton events (SPEs) represent the single-most significant source of acute radiation exposure during space missions. Historically, an exponential in rigidity (particle momentum) fit has been used to express the SPE energy spectrum using GOES data up to 100 MeV. More recently, researchers have found that a Weibull fit better represents the energy spectrum up to 1000 MeV (1 GeV). In addition, the availability of SPE data extending up to several GeV has been incorporated in analyses to obtain a more complete and accurate energy spectrum representation. In this paper we discuss the major SPEs that have occurred over the past five solar cycles (~50+ years) in detail - in particular, Aug 1972 and Sept & Oct 1989 SPEs. Using a high-energy particle transport/dose code, radiation exposure estimates are presented for various thicknesses of aluminum. The effects on humans and spacecraft systems are also discussed in detail.

Carbon dioxide (CO2) removal technology development for portable life support systems (PLSS) has traditionally concentrated in the areas of solid and liquid chemical sorbents and semi-permeable membranes. Most of these systems are too heavy in gravity environments, require prohibitive amounts of consumables for operation on long term planetary missions, or are inoperable on the surface of Mars due to the presence of a CO2 atmosphere. This paper describes the effort performed to mature an innovative CO2 removal technology that meets NASA's planetary mission needs while adhering to the important guiding principles of simplicity, reliability, and operability. A breadboard cryogenic carbon dioxide scrubber for an ejector-based cryogenic PLSS was developed, designed, and tested. The scrubber freezes CO2 and other trace contaminants out of expired ventilation loop gas using cooling available from a liquid oxygen (LOX) based PLSS.

This project investigates methods to capture an astronaut's exhaled carbon dioxide (CO2) before it becomes diluted with the high volumetric oxygen flow present within a space suit. Typical expired breath contains CO2 partial pressures (pCO2) in the range of 20-35 mm Hg (.0226-.046 atm). This research investigates methods to capture the concentrated CO2 gas stream prior to its dilution with the low pCO2 ventilation flow. Specifically this research is looking at potential designs for a collection cup for use inside the space suit helmet. The collection cup concept is not the same as a breathing mask typical of that worn by firefighters and pilots. It is well known that most members of the astronaut corps view a mask as a serious deficiency in any space suit helmet design. Instead, the collection cup is a non-contact device that will be designed using a detailed Computational Fluid Dynamic (CFD) analysis of the ventilation flow environment within the helmet.

Development of new air revitalization system (ARS) technology can initially be performed in a subscale laboratory environment, but in order to advance the maturity level, the technology must be tested in an end-to-end integrated environment. The Air Revitalization Technology Evaluation Facility (ARTEF) at the NASA Johnson Space Center (JSC) serves as a ground test bed for evaluating emerging ARS technologies in an environment representative of spacecraft atmospheres. At the center of the ARTEF is a hypobaric chamber which serves as a sealed atmospheric chamber for closed loop testing. A Human Metabolic Simulator (HMS) was custom-built to simulate the consumption of oxygen, and production of carbon dioxide, moisture and heat by up to eight persons. A variety of gas analyzers and dew point sensors are used to monitor the chamber atmosphere and the process flow upstream and downstream of a test article. A robust vacuum system is needed to simulate the vacuum of space.

To meet the challenge of future deep space programs an accurate and efficient engineering code for analyzing the shielding requirements against high-energy galactic heavy radiations is needed. Such engineering design codes require establishing validation processes using laboratory ion beams and space flight measurements in realistic geometries. In consequence, a new version of the HZETRN code capable of simulating HZE ions with either laboratory or space boundary conditions is currently under development. The new code, GRNTRN, is based on a Green's function approach to the solution of Boltzmann's transport equation and like its predecessor is deterministic in nature. Code validation in the laboratory environment is addressed by showing that GRNTRN accurately predicts energy loss spectra as measured by solid-state detectors in ion beam experiments.

Protecting astronauts from space radiation exposure is an important challenge for mission design and operations for future exploration-class and long-duration missions. Crew members are exposed to sporadic solar particle events (SPEs) as well as to the continuous galactic cosmic radiation (GCR). If sufficient protection is not provided the radiation risk to crew members from SPEs could be significant. To improve exposure risk estimates and radiation protection from SPEs, detailed evaluations of radiation shielding properties are required. A model using a modern CAD tool ProE™, which is the leading engineering design platform at NASA, has been developed for this purpose. For the calculation of radiation exposure at a specific site, the cosine distribution was implemented to replicate the omnidirectional characteristic of the 4π particle flux on a surface.

The Internal Active Thermal Control System (IATCS) aboard the International Space Station (ISS) contains an aqueous, alkaline fluid (pH 9.5±0.5) that aids in maintaining a habitable environment for the crew. Because microbes have significant potential to cause disease, adverse effects on astronaut health, and microbe-induced corrosion, the presence of both bacteria and viruses within IATCS fluids is of concern. This study sought to detect and identify viral populations in IATCS samples obtained from the Kennedy Space Center as a first step towards characterizing and understanding potential risks associated with them. Samples were concentrated and viral nucleic acids (NA) extracted providing solutions containing 8.87-22.67 μg NA per mL of heat transfer fluid. After further amplification viral DNA and cDNA were then pooled, fluorescently labeled, and hybridized onto a Combimatrix panvira 12K microarray containing probes for ∼1,000 known human viruses.

A new life support approach is proposed for use on the International Space Station (ISS). This involves advanced technologies for water recovery and air revitalization, tested at the Johnson Space Center (JSC), including bioprocessing, reverse-osmosis and distillation, low power carbon dioxide removal, non-expendable trace contaminant control, and carbon dioxide reduction.

As part of NASA's initiative to develop an advanced portable life support system (PLSS), a baseline schematic has been chosen that includes gaseous oxygen in a closed circuit ventilation configuration. Supply oxygen enters the suit at the back of the helmet, passes over the astronaut's body, and is extracted at the astronaut's wrists and ankles through the liquid cooling and ventilation garment (LCVG). The extracted gases are then treated using a rapid cycling amine (RCA) system for carbon dioxide and water removal and activated carbon for trace gas removal before being mixed with makeup oxygen and reintroduced into the helmet. Thermal control is provided by a suit water membrane evaporator (SWME). As an extension of the original schematic development, NASA evaluated several Helmet Exhalation Capture System (HECS) configurations as alternatives to the baseline.

In a crewed spacecraft environment, atmospheric carbon dioxide (CO2) and moisture control are crucial. Hamilton Sundstrand has developed a stable and efficient amine-based CO2 and water vapor sorbent, SA9T, that is well suited for use in a spacecraft environment. The sorbent is efficiently packaged in pressure-swing regenerable beds that are thermally linked to improve removal efficiency and minimize vehicle thermal loads. Flows are controlled with a single spool valve. This technology has been baselined for the new Orion spacecraft, but additional data was needed on the operational characteristics of the package in a simulated spacecraft environment. One unit was tested with simulated metabolic loads in a closed chamber at Johnson Space Center during the latter part of 2006. Those test results were reported in a 2007 ICES paper.

A system of amine-based carbon dioxide (CO2) and water vapor sorbent in pressure-swing regenerable beds has been developed by Hamilton Sundstrand and is baselined for the Orion Atmosphere Revitalization System (ARS). In two previous years at this conference, reports were presented on extensive Johnson Space Center (JSC) testing of the technology, which was performed in a representative environment with simulated human metabolic loads. The next step in developmental testing at JSC was to use real human loads in the spring of 2008.

The Third Generation ENose is an air quality monitor designed to operate in the environment of the US Lab on the International Space Station (ISS). It detects a selected group of analytes at target concentrations in the ppm regime at an environmental temperature range of 18 – 30 °C, relative humidity from 25 – 75% and pressure from 530 to 760 torr. This device was installed and activated on ISS on Dec. 9, 2008 and has been operating continuously since activation. Data are downlinked and analyzed weekly. Results of analysis of ENose monitoring data show the short term presence of low concentration of alcohols, octafluoropropane and formaldehyde as well as frequent short term unknown events.

Simultaneous measurements were made for particle releases and off-gassing products produced by heating electrical wires. The wire samples in these experiments were heated to selected temperatures in a heating chamber and responses to vapor releases were recorded by the JPL Electronic Nose (ENose) and an Industrial Scientific ITX gas-monitor; particles released were detected by a TSI P-Trak particle counter. The temperature range considered for the experiment is room temperature (24−26°C) to 500 °C. The results were analyzed by overlapping responses from the ENose, ITX gas sensors and P-Trak, to understand the events (particle release/off-gassing) and sequence of events as a function of temperature and to determine qualitatively whether ENose may be used to detect pre-combustion event markers.

The 2001 Mars Odyssey spacecraft Martian Radiation Environment Experiment (MARIE) is a solid-state silicon telescope high-energy particle detector designed to measure galactic cosmic radiation (GCR) and solar particle events (SPEs) in the 20 – 500 MeV/nucleon energy range. In this paper we discuss the instrument design and focus on the observations and measurements of SPEs at Mars. These are the first-ever SPE measurements at Mars. The measurements are compared with the geostationary GOES satellite SPE measurements. We also discuss some of the current interplanetary particle propagation and diffusion theories and models. The MARIE SPE measurements are compared with these existing models.

As shielding materials are developed for protection against the hazards of galactic cosmic rays, it is desirable to develop a protocol for rapid assessment of shielding properties. Solid state energy loss detectors are often used to estimate the charge and energy of particles in ion beam experiments. The direct measurement is energy deposited in the detector. As a means of separating the charge components in typical shield transmission studies with observation, a stack of many such detectors is used. With high-energy beams and thin targets, surviving primaries and fragments emerging from the target have nearly-equal velocities and deposited energy scales with the square of the charge, simplifying the data analysis. The development of a transport model for the shield and detector arrangement and evaluation of prediction of the energy loss spectrum for direct comparison with the experimentally derived data allows a rapid assessment of the shield transmission characteristics.

A generalized computer program for analysis of pressure and composition in multiple volume systems has been under development by the National Aeronautics and Space Administration (NASA) since 1976. This paper describes the most recent developments in the program. These improvements include the expansion of the program to nine volumes, improvements to the model of the International Space Station (ISS) carbon dioxide removal system, and addition of a detailed Sabatier carbon dioxide reduction mode. An evaluation of the feasibility of adding of trace contaminant tracking was also performed. This paper will also present the results of an analysis that compares model predictions with ISS flight data for carbon dioxide (CO2) maintenance.

TDA Research, Inc. (TDA) is developing a compact, lightweight ExtraVehicular activity (EVA) emergency system that provides 30-minute life-support in the case of system or component failures in the Portable Life Support System (PLSS). The system uses a low ventilation rate to reduce the amount of stored oxygen, reducing the associated weight and volume penalty. Operation of the system requires an effective sorbent that would remove carbon dioxide and moisture from the suit. We are developing a regenerable sorbent that is suitable for the conceptual system. Recently, we tested the sorbent performance in an adiabatic reactor setup simulating representative EVA emergency conditions. This paper summarizes results of these adiabatic tests.

Space-faring crews must have safe breathing air throughout their missions to ensure adequate performance and good health. Toxicological assessment of air quality depends on the standards that define acceptable air quality, measurements of pollutant levels during the flight, and reports from the crew on their in-flight perceptions of air quality. Air samples returned from ISS on flights 8A, UF2, 9A, and 11A were analyzed for trace pollutants. On average, the air during this period of operations was safe for human respiration. However, about 3 hours into the regeneration of 2 Metox canisters in the U.S. airlock on 20 February 2002 the crew reported an intolerable odor that caused them to stop the regeneration, take refuge in the Russian segment, and scrub air in the U.S. segment for 30 hours. Analytical data from grab samples taken during the incident showed that the pollutants released were characteristic of nominal air pollutants, but were present in much higher concentrations.

Research into increased capacity solid amine sorbents has found a candidate (SA9T) that will provide enough increase in cyclic carbon dioxide removal capacity to produce a fully redundant Regenerative Carbon Dioxide Removal System (RCRS). This system will eliminate the need for large quantities of backup LiOH, thus gaining critical storage space on board the shuttle orbiter. This new sorbent has shown an ability to package two fully redundant (four) sorbent beds together with their respective valves, fans and plumbing to create two operationally independent systems. The increase in CO2 removal capacity of the new sorbent will allow these two systems to fit within the envelope presently used by the RCRS. This paper reports on the sub-scale amine testing performed in support of the development effort. In addition, this paper will provide a preliminary design schematic of a fully redundant RCRS.