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It has long been recognized that the key to achieving stringent emission standards such as ULEV is the control of cold-start hydrocarbons. This paper describes a new approach for achieving excellent cold-start hydrocarbon control. The most important component in the system is a catalyst that is highly active at ambient temperature for the exothermic CO oxidation reaction in an exhaust stream under net lean conditions. This catalyst has positive order kinetics with respect to CO for CO oxidation. Thus, as the concentration of CO in the exhaust is increased, the rate of this reaction is increased, resulting in a faster temperature rise over the catalyst.

The molecular filtration of sulfur components in ultra low sulfur diesel (ULSD) fuel is described. A comprehensive screening of potential sulfur removal chemistries has yielded a sorbent which has the capability to efficiently remove organo-sulfur components in ULSD fuel. This sorbent has been used to treat ULSD fuel on a heavy duty engine equipped with NOx adsorber after-treatment technology and has been shown to lengthen the time between desulfation steps for the NOx adsorber. The fuel properties, cetane number and aromatics content, etc., have not been changed by the removal of the sulfur in the fuel with the exception of the lubricity which is reduced.

The SNR-technique is a new NOx aftertreatment system for lean burn gasoline and diesel applications. The objective of SNR is NOx removal from lean exhaust gas by NOx adsorption and subsequent selective external recirculation and decomposition of NOx in the combustion process. The SNR-project is composed of two major parts. Firstly the development of NOx adsorbents which are able to store large quantities of NOx in lean exhaust gas, and secondly the NOx decomposition by the combustion process. Emphasis of this paper is the investigation of NOx reduction in the combustion process, including experimental investigation and numerical simulation. The NOx decomposition process has been proven in diesel and lean-burn gasoline engines. Depending on the type of engine NOx-conversion rates up to 90 % have been observed. Regarding the complete SNR-system, including the efficiency of the adsorbing material and the NOx decomposition by the combustion, a NOx removal of more than 50% is achievable.

Selective NOx recirculation (SNR), involving adsorption, selective external recirculation and decomposition of the NOx by the combustion process, is itself a promising technique to abate NOx emissions. Three types of materials containing Ba: barium aluminate, barium tin perovskite and barium Y-zeolites have been developed to adsorb NOx under lean-burn or Diesel conditions, with or without the presence of S02. All these materials adsorb NO2 selectively (lean-burn conditions), and store it as nitrate/nitrite species. The desorption takes place by decomposition of these species at higher temperatures. Nitrate formation implies also sulfate formation in the presence of SO2 and SO3, while the NO2/SO2 competition governs the poisoning of such catalysts.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

Future US emissions limits are likely to mean a sophisticated nitrogen oxide (NOx) reduction technique is required for all vehicles with a diesel engine, which is likely to be either NOx trap or selective catalytic reduction (SCR) technology. To investigate the potential of SCR for NOx reduction on a light duty vehicle, a current model vehicle (EUII M1 calibration), of inertia weight 1810 kg, was equipped with an urea-based SCR injection system and non-vanadium, non-zeolitic SCR catalysts. To deal with carbon monoxide (CO), hydrocarbon (HC) and volatile organic fraction (VOF), a diesel oxidation catalyst was also incorporated into the system for most tests. Investigations into the effect of placing the oxidation catalyst at different positions in the system, changing the volume of the SCR catalysts, increasing system temperature through road load changes, varying the SCR catalyst composition, and changing the urea injection calibration are discussed.

The influence of SCR (selective catalytic reduction) activity on soot regeneration was investigated using engine test measurements with and without urea dosing on a vanadia-SCRF®1, also known as a vanadia SCR coated diesel particulate filter (V.SCR-DPF). The extent and rate of passive soot regeneration is significantly reduced in the presence of SCR activity especially at high temperatures (>250 °C). The reduction in soot regeneration is because some of the NO2, which would otherwise react with the soot, is consumed by SCR reactions and consequently the rate of soot regeneration is lower when urea is dosed. The converse effects of soot oxidation on SCR activity were studied separately by analysing steady-state light-off engine measurements with different initial soot loadings on the V.SCR-DPF. The measurements show an increase in NOX conversion with increasing soot loading.

The reduction of particulate emissions from diesel engines is one of the most challenging problems associated with exhaust pollution control, second only to the control of NOx from any “lean burn” application. Particulate emissions can be controlled by adjustments to the combustion parameters of a diesel engine but these measures normally result in increased emissions of oxides of nitrogen. Diesel particulate filters (DPFs) hold out the prospect of substantially reducing regulated particulate emissions and the task of actually removing the particles from the exhaust gas has been solved by the development of effective filtration materials. The question of the reliable regeneration of these filters in situ, however, remains a difficult hurdle. Many of the solutions proposed to date suffer from high engineering complexity and/or high energy demand. In addition some have special disadvantages under certain operating conditions.

Asymmetric particulate filters (PF), where the inlet channel is wider than the outlet channel, are commonly used because of their greater capacity for ash. Somewhat surprisingly, very few models for asymmetric PFs have been published and none of these gives a correct/detailed description of the geometry. For example, octahedral channels may be treated as if they were square or the tapering walls between the inlet and outlet channels treated as if they were rectangular in cross section. Alternatively, the equations may be presented in generic form in terms of channel cross-sectional areas and perimeters, but without giving any indication of how to calculate these. This paper aims to address these deficiencies with a model that correctly describes the geometry of square and octo-square asymmetric PFs. Expressions for the solid fraction of the PF (which affects thermal mass) and channel cross section and perimeter (both when clean and soot/ash loaded) are presented.

Progress made in reducing engine-out particulate emissions has prompted a revival in the design of flow-through oxidation catalysts for diesel engine applications. Effort in this area has focused primarily in the area of SOF control for the further reduction of particulate emissions. The work reported here covers some of the catalyst design parameters important for SOF and gas phase pollutant control. This is illustrated with both laboratory reactor and engine evaluation data for several formulary and operating parameters. Platinum-based catalysts are shown to be generally the most active, but they require treatments or additives to reduce the inherently high activity of platinum for the oxidation of SO2 present in the exhaust. The effect of additives and their loading on the oxidation activity of Pt/alumina for HC, CO, SOF and SO2 oxidation is discussed in detail and additives are identified which reduce SO2 oxidation with minimal effect on HC, CO or SOF oxidation activity.

Flow-through diesel oxidation catalysts (DOC's) have been shown to be an effective means of reducing emissions from diesel engines. In this work, the further development of diesel oxidation catalysts for the control of emissions from heavy duty engines is illustrated. Laboratory reactor and engine dynamometer data obtained from engine-based accelerated poisoning and aging studies demonstrate that HC, CO and SO2 oxidation by DOC's can be modified by adjusting platinum and vanadium loadings in alumina-based Pt/V catalyst formulations. The performance and durability of this type of catalyst system are demonstrated with several aging cycles on heavy-duty engines. The fresh performance of two catalyst systems was determined on both US Heavy Duty Transient and ECE-R49 Test cycles with a 1991 calibration Perkins Phaser 6.0 L engine. Gas phase emissions were reduced by a similar amount for both catalysts over both cycles (HC: 60-70%, CO: 45-75%).

One possibility to improve the fuel economy of SI-engines is to run the engine with a lean air-fuel-ratio (AFR). Hydrocarbon and carbon monoxide after-treatment has been proven under lean operation, but NOx-control remains a challenge to catalyst and car manufacturers. One strategy that is being considered is to run the engine lean with occasional operation at stoichiometry. This would be in conjunction with a three-way-catalyst (TWC) to achieve stoichiometric conversion of the three main pollutants in the normal way and a NOx trap. The NOx trap stores NOx under lean operation to be released and reduced under rich conditions. The trap also functions as a TWC and has good HC and CO conversion at both lean and stoichiometric AFR's. Under lean conditions NO is oxidised to NO2 on Pt which is then adsorbed on an oxide surface. Typical adsorbent materials include oxides of potassium, calcium, zirconium, strontium, lanthanum, cerium and barium.

A test programme has been conducted to study any potential long term effects of gasoline sulphur on catalyst performance, using a newly developed transient engine-bed ageing cycle. The ageing cycle, which was based on repeated European Extra Urban Drive Cycles, was chosen to ensure that the catalyst experienced a realistically wide range of temperatures and space velocities, together with transients, idle and periods of overrun. Two nominally identical platinum/rhodium catalysts (manufactured from the same batch) with matched lambda sensors, were aged for a period of 80,000 km each, one being aged using a gasoline containing 50 mg/kg (ppm wt) sulphur, the other being aged on the same fuel doped to 450 ppm wt S. The emissions performance of both catalysts was measured after 6,000, 40,000 and 80,000 km ageing, by fitting the catalysts to a test vehicle, and performing emissions tests over the European test cycle at both sulphur levels.

A comparison of two different types of NOx reducing catalysts will be worked out. The potential of two De-NOx catalysts using engine out hydrocarbon emissions for NOx conversion will be shown by variation of different engine parameters. An analysis of the hydrocarbon species upstream and downstream catalyst will demonstrate, which components are responsible for the NOx reduction in the exhaust gas of a lean burn engine. By variation of different parameters during adsorbtion and regeneration phases of the adsorber catalyst the efficiency in NOx reduction will be optimized. An assessment of the suitability for lean burn engines will consider the emission reduction efficiency as well as the influence on engine fuel consumption.

Reduction of nitrogen oxides in Diesel exhaust gas is a challenging task. This paper reports results from an extensive study using Pt-based catalysts involving synthetic gas activity testing (SCAT), engine bench testing and tests on passenger cars. Preliminary SCAT work highlighted the importance of Pt-dispersion, and both SCAT and bench engine testing yielded comparable NOx conversions under steady state conditions at high HC:NOx ratios. On passenger cars in the European cycle without secondary fuel injection NOx conversion was lower than obtained in the steady state tests. Better conversion was obtained in the FTP cycle, where secondary injection was employed. Higher HC:NOx, ratios and more favourable temperature conditions which were present in the exhaust contributed to this higher conversion.

The use of hydrocarbon traps to reduce cold-start emissions is one of the numerous methods that have been suggested to meet ULEV hydrocarbon emission requirements. To aid in our understanding of hydrocarbon traps and in the design of improved hydrocarbon trap systems, in-situ mass spectrometry has been used to speciate several hydrocarbons during the first 505 seconds of an FTP from the exhaust of a 2.0 L vehicle fitted with hydrocarbon traps in the after treatment system. This technique allows second-by-second engine-out and vehicle-out hydrocarbon speciation. The in-situ mass specrometry technique has shown that hydrocarbon traps are generally effective for trapping aromatics and C4+ alkanes and alkenes, but are ineffective in trapping methane, ethane, and ethene: Further improvements in the trapping performance for C3-C5 hydrocarbons can be made by placing a water trap in front of the hydrocarbon trap.

Two campaigns measuring on-road emissions of 23 VN-trucks on a randomly chosen driving cycle, consisting of 10 miles two-lane and 8 miles four-lane road were performed. The first, during October 2004, showed tailpipe NOx emissions on fleet average of 1.06 g/bhp-hr including the time the exhaust gas temperature was below 200°C. The second, during June 2005, showed tailpipe NOx emissions on fleet average of 1.13 g/bhp-hr including the time the exhaust gas temperature was below 200°C. Complementary measurements in a SET-cycle (13 point OICA-cycle) on a chassis dynamometer showed a tailpipe emission of 0.008 g PM per bhp-hr. Moreover, cost analysis show that the diesel fuel consumption remains unchanged whether the truck running on ULSD is equipped with a Combined Exhaust gas AfterTreatment System (CEATS) installed or not.

Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).

A fleet of six 2001 International Class 6 trucks operating in southern California was selected for an operability and emissions study using gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (CDPF). Three vehicles were fueled with CARB specification diesel fuel and no emission control devices (current technology), and three vehicles were fueled with GTL fuel and retrofit with Johnson Matthey's CCRT™ diesel particulate filter. No engine modifications were made. Bench scale fuel-engine compatibility testing showed the GTL fuel had cold flow properties suitable for year-round use in southern California and was additized to meet current lubricity standards. Bench scale elastomer compatibility testing returned results similar to those of CARB specification diesel fuel. The GTL fuel met or exceeded ASTM D975 fuel properties. Researchers used a chassis dynamometer to test emissions over the City Suburban Heavy Vehicle Route (CSHVR) and New York City Bus (NYCB) cycles.

This paper reports the test results from the DPF (diesel particulate filter) portion of the DECSE (Diesel Emission Control - Sulfur Effects) Phase 1 test program. The DECSE program is a joint government and industry program to study the impact of diesel fuel sulfur level on aftertreatment devices. A systematic investigation was conducted to study the effects of diesel fuel sulfur level on (1) the emissions performance and (2) the regeneration behavior of a continuously regenerating diesel particulate filter and a catalyzed diesel particulate filter. The tests were conducted on a Caterpillar 3126 engine with nominal fuel sulfur levels of 3 parts per million (ppm), 30 ppm, 150 ppm and 350 ppm.