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Homogeneous Charge Compression Ignition (HCCI) is good method to be higher efficiency and to reduce NOx emission and particular matter together than conventional SI combustion engine. But HCCI depends on chemical reaction of fuel and air mixture. So controlling of ignition timing is difficult, and HCCI is high THC and CO emissions because temperature can't reach the enough temperature to reduce those. In this study, we investigated factor for auto ignition timing and combustion completion on n-Butane/Air mixture by a two-stroke HCCI engine. Auto Ignition temperature are known to be decided by fuel(1), for n-Butane, the temperature was 1150±30K. And as we researched combustion completion from In-cylinder gas temperature, increasing In-cylinder gas temperature caused high combustion efficiency and low THC, CO emissions.