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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

To promote advanced combustion strategies complying with stringent emission regulations of CI engines, computational models have to accurately predict the injector inner flow and cavitation development in the nozzle. This paper describes a coupled 1D/2D/3D modeling technique for the simulation of fuel flow and nozzle cavitation in diesel injection systems. The new technique comprises 1D fuel flow, 2D multi-body dynamics and 3D modeling of nozzle inner flow using a multi-fluid method. The 1D/2D model of the common rail injector is created with AVL software Boost-Hydsim. The computational mesh including the nozzle sac with spray holes is generated with AVL meshing tool Fame. 3D multi-phase calculations are performed with AVL software FIRE. The co-simulation procedure is controlled by Boost-Hydsim. Initially Hydsim performs a standalone 1D simulation until the needle lift reaches a prescribed tolerance (typically 2 to 5 μm).

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

The present work introduces an extended particulate filter model focusing on capabilities to cover catalytic and surface storage reactions and to serve as a virtual multi-functional reactor/separator. The model can be classified as a transient, non-isothermal 1D+1D two-channel model. The applied modeling framework offers the required modeling depth to investigate arbitrary catalytic reaction schemes and it follows the computational requirement of running in real-time. The trade-off between model complexity and computational speed is scalable. The model is validated with the help of an analytically solved reference and the model parametrization is demonstrated by simulating experimentally given temperatures of a heat-up measurement. The detailed 1D+1D model is demonstrated in a concept study comparing the impact of different spatial washcoat distributions.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

The Particle Measurement Programme (PMP) developed an exhaust particle number measurement protocol that has been adopted by current light duty vehicle emission regulations in Europe. This includes thermal treatment of the exhaust aerosol to isolate solid particles only and a number counting device with a lower cutpoint of 23 nm to avoid measurement of smaller particles that may affect the repeatability of the measurement. In this paper, we examine a potential alternative to the PMP system, where the thermal treatment is replaced by a catalytic stripper (CS). This offers oxidation and not just evaporation of the volatile components. Alternative sampling systems, either fulfilling the PMP recommendations or utilizing a CS, have been explored in terms of their volatile particle removal efficiency. Tests have been conducted on diesel exhaust, diesel equipped with DPF and gasoline direct injection emissions.

Particulate emission reduction has long been a challenge for diesel engines as the diesel diffusion combustion process can generate high levels of soot which is one of the main constituents of particulate matter. Gasoline engines use a pre-mixed combustion process which produces negligible levels of soot, so particulate emissions have not been an issue for gasoline engines, particularly with modern port fuel injected (PFI) engines which provide excellent mixture quality. Future European and US emissions standards will include more stringent particulate limits for gasoline engines to protect against increases in airborne particulate levels due to the more widespread use of gasoline direct injection (GDI). While GDI engines are typically more efficient than PFI engines, they emit higher particulate levels, but still meet the current particulate standards.

The paper describes a zero-dimensional crank angle resolved combustion model which was developed for the analysis and prediction of combustion in compression ignition (CI) engines. The model relies on the multi zone combustion model (MZCM) approach of Hiroyasu. The main sub-models were taken from literature and extended with additional features described in this paper. A special procedure described in a previous paper is used to identify the mechanisms of the combustion process on the basis of the measured cylinder pressure trace. Based on the identified mechanisms the present work concentrates on the analysis of the causal effects that predominantly control the combustion process and the formation of NOx and Soot. The focus lies on the changes of the thermodynamic states and the composition of the reaction zones caused by different emission control strategies.

In recent years, more attentions have been paid to stringent legislations on fuel consumption and emissions. Turbocharged downsized gasoline direct injection (DI) engines are playing an increasing important role in OEM’s powertrain strategies and engine product portfolio. Dongfeng Motor (DFM) has developed a new 1.0 liter 3-cylinder Turbocharged gasoline DI (TGDI) engine (hereinafter referred to as C10TD) to meet the requirements of China 4th stage fuel consumption regulations and the China 6 emission standards. In this paper, the concept of the C10TD engine is explained to meet the powerful performance (torque 190Nm/1500-4500rpm and power 95kW/5500rpm), excellent part-load BSFC and NVH targets to ensure the drivers could enjoy the powerful output in quiet and comfortable environment without concerns about the fuel cost and pollution.

Modern Diesel engines require an integrated development of combustion strategies, air management and exhaust aftertreatment. This study presents a comprehensive simulation approach with the aim to support engine development activities in the virtual environment. A real-time capable engine, vehicle and control model is extended by three key features. First, a pollutant production model is embedded in a two-zone cylinder model. Second, a framework for catalytic pollutant conversion is built focusing on modern diesel exhaust aftertreatment systems. Third, an extended species transport model is introduced considering the transport of pollutants through the air path. The entire plant model is validated on the example of a passenger car Diesel engine. The predicted engine behavior is compared with steady-state measurements. The NO formation model is investigated for a series of steady-state and transient operating conditions.

Direct-injection represents a consolidated technology to increase performance and efficiency in spark-ignition engines. It reduces the knock tendency and makes engine downsizing possible through the use of turbocharging. Better control of CO and HC emissions at cold-start is also ensured since there is no wall-impingement in the intake port. However, to take advantages of all the theoretical benefits derived from GDI technology, detailed investigations of both fuel-air mixing and combustion processes are necessary to extend the stratified charge operations in the engine map and to reduce soot emissions, that are now severely regulated by emission standards. In this work, the authors developed a CFD methodology to investigate and optimize the fuel-air mixing process in direct-injection, spark-ignition engines. The Eulerian-Lagrangian approach is used to model the evolution of the fuel spray emerging from a multi-hole injector.

Faced with the need to reduce development time and cost in view of additional system complexity driven by ever more stringent emission regulations, the Hardware-in-the-Loop (HiL) simulation increasingly proves itself to be an advantageous tool not only in automotive companies but also in the off-road engine industry. The approach offers the possibility to analyze new engine control systems with fewer expensive engine dynamometer experiments and test drives. Thus, development cycles can be shortened and development costs reduced. This paper presents the development of an Internal Combustion Engine (ICE) and the correspondent Exhaust Aftertreatment System (EAS) model, its deployment on a HiL system and its application to pre-calibrate the engine for different vehicle cycles. A zero-dimensional mean value approach was chosen to guarantee adequate real-time factors for the coupling between the models and the Engine Control Unit (ECU).

Direct injection Diesel engines are a propulsion technology that is continuously developed to meet emission standards. Great optimization potential lies in the combustion process itself. The application of closed loop combustion control allows reacting online to environmental conditions and stabilizing the combustion regarding performance and emissions. Dedicated real-time plant models help to develop and calibrate control algorithms in office and hardware in the loop environments. The present work describes a real-time capable, crank-angle resolved engine, cylinder and combustion model. The cylinder applies an 0D, two-zone approach and a phenomenological combustion model describes ignition delay, premixed and diffusive combustion. The latter is enhanced by a quasi-dimensional description of the injection spray. The model is validated with dedicated measurements. The plant model is applied in two use-cases for closed loop combustion control.

The accurate prediction of pollutant emissions generated by IC engines is a key aspect to guarantee the respect of the emission regulation legislation. This paper describes the approach followed by the authors to achieve a strict numerical coupling of two different 1D modeling tools in a co-simulation environment, aiming at a reliable calculation of engine-out and tailpipe emissions. The main idea is to allow an accurate 1D simulation of the unsteady flows and wave motion inside the intake and exhaust systems, without resorting to an over-simplified geometrical discretization, and to rely on advanced thermodynamic combustion models and kinetic sub-models for the calculation of cylinder-out emissions. A specific fluid dynamic approach is then used to track the chemical composition along the exhaust duct-system, in order to evaluate the conversion efficiency of after-treatment devices, such as TWC, GPF, DPF, DOC, SCR and so on.

Gasoline, direct injection engines represent one of the most widely adopted powertrain for passenger cars. However, further development efforts are necessary to meet the future fuel consumption and emission standards imposing an efficiency increase and a reduction of particulate matter emissions. Within this context, computational fluid dynamics is nowadays a consolidated tool to support engine design; this work is focused on the development of a set of CFD models for the prediction of combustion in modern GDI engines. The one-equation Weller model coupled with a zero-dimensional approach to handle initial flame kernel growth was applied to predict flame propagation. To account for mixture fraction fluctuations which might lead to the presence of soot precursor species, burned gas chemical composition is computed using tabulated kinetics with a presumed probability density function.

Most stringent emission legislations have been implemented in all major markets to improve air quality across the past years. This effects the product cost of the vehicles which is considered being critical and needs to be minimized. India suffers from bad air quality and countermeasures have been defined. One being the implementation of similar emission standards than EU VI. By doing so, India takes a large step going from the currently effective BS IV directly to BS VI. Emission reduction is currently mainly handled by the usage of EGR, thus no engine aftertreatment system has been applied. BS VI will require an aftertreatment (EAS) concept with several catalysts and corresponding control system. India is a very cost sensitive market and a carry over of solutions from the EU needs to be evaluated carefully and new approaches need to be found.

The internal combustion engine contains several actuators to control engine performance and emissions. These are controlled within the engine ECU and follow a specific operating strategy to achieve objectives such as NOx reduction and fuel economy. However, these two goals are conflicting and a compromise is required. The operating state depends on system constraints such as engine speed, load, temperature levels, and aftertreatment system efficiency. This results in constantly changing target values to stay within the defined limits, especially the legal emission limits. The conventional approach is to use multiple operating modes. Each mode represents a specific compromise and is activated accordingly. Multiple modes are required to meet emissions regulations under all required conditions, which increases the calibration effort. This new control approach uses an artificial neural network to replace the conventional multiple mode approach.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.

The target of the upcoming automotive emission regulations is to promote a fast transition to near-zero emission vehicles. As such, the range of ambient and operating conditions tested in the homologation cycles is broadening. In this context, the proposed work aims to thoroughly investigate the potential of post-oxidation phenomena in reducing the light-off time of a conventional three-way catalyst. The study is carried out on a turbocharged four-cylinder gasoline engine by means of experimental and numerical activities. Post oxidation is achieved through the oxidation of unburned fuel in the exhaust line, exploiting a rich combustion and a secondary air injection dedicated strategy. The CFD methodology consists of two different approaches: the former relies on a full-engine mesh, the latter on a detailed analysis of the chemical reactions occurring in the exhaust line.