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The prediction of knock onset in spark-ignition engines requires a chemical model for the autoignition of the hydrocarbon fuel-air mixture, and a description of the unburned end-gas thermal state. Previous studies have shown that a reduced chemistry model developed by Keck et al. adequately predicts the initiation of autoignition. However, the combined effects of heat transfer and compression on the state of the end gas have not been thoroughly investigated. The importance of end-gas heat transfer was studied with the objective of improving the ability of our knock model to predict knock onset over a wide range of engine conditions. This was achieved through changing the thermal environment of the end gas by either varying the inlet air temperature or the coolant temperature. Results show that there is significant heating of the in-cylinder charge during intake and a substantial part of the compression process.

The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).

An aerodynamic model of the entrainment of the head wall quench layer during blowdown and exhaust of an internal combustion engine has been developed. The model may be used to calculate the time resolved concentration and mass flowrate of hydrocarbons (HC) in the exhaust, from a knowledge of engine geometry and operating conditions. It predicts that the area As from which HC are swept will be proportional to the cube root of the ratio of the quench layer thickness δq to the thickness of the viscous boundary layer δv. Since the mass of HC emitted is proportional to the product of the HC density ρHC, the area As and the thickness δq, the HC emissions will be proportional to the product ρHC δq4/3 and this is the most important factor determining the emissions.