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NOx emissions from a heavy-duty diesel engine were reduced by more than 90% and 80% utilizing a full-scale ethanol-SCR system for space velocities of 21000/h and 57000/h respectively. These results were achieved for catalyst temperatures between 360 and 400°C and for C1:NOx ratios of 4-6. The SCR process appears to rapidly convert ethanol to acetaldehyde, which subsequently slipped past the catalyst at appreciable levels at a space velocity of 57000/h. Ammonia and N2O were produced during conversion; the concentrations of each were higher for the low space velocity condition. However, the concentration of N2O did not exceed 10 ppm. In contrast to other catalyst technologies, NOx reduction appeared to be enhanced by initial catalyst aging, with the presumed mechanism being sulfate accumulation within the catalyst. A concept for utilizing ethanol (distilled from an E-diesel fuel) as the SCR reductant was demonstrated.

The particulate matter (PM) produced from a diesel engine-simulating combustor was characterized in its morphology, microstructure, and fractal geometry by using a unique thermophoretic sampling and Transmission Electron Microscopy (TEM) system. These results revealed that diesel PM produced from the laboratory-scale burner showed similar morphological characteristics to the particulates produced from diesel engines. The flame air/fuel ratio and the particulate temperature history have significant influences on both particle size and fractal geometry. The primary particle sizes were measured to be 14.7 nm and 14.8 nm under stoichiometric and fuel-rich flame conditions, respectively. These primary particle sizes are smaller than those produced from diesel engines. The radii of gyration for the aggregate particles were 83.8 nm and 47.5 nm under these two flame conditions.