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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO2 oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Technical Paper

Effect of Diesel Fuel Chemistry on Regulated Emissions at High Altitude

1996-10-01
961947
The effect of diesel cetane number, total aromatic content T90, and fuel nitrogen content on regulated emissions (HC, CO, NOx, and PM) from a 1991 DDC Series 60 engine were measured Emissions tests were conducted using the EPA heavy-duty transient test (CFR 40 Part 86 Subpart N) at a laboratory located 5,280 feet (1609 m) above sea level. The objective of this work was to determine if the effect of fuel chemistry at high altitude is similar to what is observed at sea level and to examine the effect of specific fuel chemistry variables on emissions. An initial tea series was conducted to examine the effect of cetane number and aromatics. Transient emissions for this test series indicated much higher (50 to 75%) particulate emissions at high altitude than observed on the same model engine and similar fuels at sea level.
Technical Paper

Rapid Deactivation of Lean-Burn Natural Gas Engine Exhaust Oxidation Catalysts

1996-10-01
961976
Methane emissions from lean-burn natural gas engines can be relatively high. As natural gas fueled vehicles become more prevalent, future regulations may restrict these emissions. Preliminary reports indicated that conventional, precious metal oxidation catalysts rapidly deactivate (in less than 50 hours) in lean-burn natural gas engine exhaust. This investigation is directed at quantifying this catalyst deactivation and understanding its cause. The results may also be relevant to oxidation of lean-burn propane and gasoline engine exhaust. A platinum/palladium on alumina catalyst and a palladium on alumina catalyst were aged in the exhaust of a lean-burn natural gas engine (Cummins B5.9G). The engine was fueled with compressed natural gas. Catalyst aging was accomplished through a series of steady state cycles and heavy-duty transient tests (CFR 40 Part 86 Subpart N) lasting 10 hours. Hydrocarbons in the exhaust were speciated by gas chromatography.
Technical Paper

The Effect of Diesel Sulfur Content and Oxidation Catalysts on Transient Emissions at High Altitude from a 1995 Detroit Diesel Series 50 Urban Bus Engine

1996-10-01
961974
Regulated emissions (THC, CO, NOx, and PM) and particulate SOF and sulfate fractions were determined for a 1995 Detroit Diesel Series 50 urban bus engine at varying fuel sulfur levels, with and without catalytic converters. When tested on EPA certification fuel without an oxidation catalyst this engine does not appear to meet the 1994 emissions standards for heavy duty trucks, when operating at high altitude. An ultra-low (5 ppm) sulfur diesel base stock with 23% aromatics and 42.4 cetane number was used to examine the effect of fuel sulfur. Sulfur was adjusted above the 5 ppm level to 50, 100, 200, 315 and 500 ppm using tert-butyl disulfide. Current EPA regulations limit the sulfur content to 500 ppm for on highway fuel. A low Pt diesel oxidation catalyst (DOC) was tested with all fuels and a high Pt diesel oxidation catalyst was tested with the 5 and 50 ppm sulfur fuels.
Technical Paper

Coordinated Control of Multi-Degree-of Freedom Fuel Systems

1997-04-01
971559
This paper identifies potential performance benefits and computational costs of applying advanced multivariable control theory concepts to coordinate the control of a general multi-degree-of-freedom fuel system. The control variables are injection duration and pressure. The focus is on the design of a robust multi-input multi-output controller using H-infinity and mu synthesis methodology to coordinate the control of injection duration and pressure; reduce overshoots and system sensitivity to parameter variations caused by component aging. Model reduction techniques are used to reduce the order of the H-infinity controller to make it practically implementable. Computer simulation is used to test the robust performance of a generic engine and fuel system model controlled by the reduced order H-infinity controller and a traditional proportional plus integral controller.
Technical Paper

High Performance Biodegradable Fluid Requirements for Mobile Hydraulic Systems

1998-04-08
981518
Technical groups worldwide have been actively developing specifications and requirements for biodegradable hydraulic fluids for mobile applications. These groups have recognized that an industry-wide specification is necessary due to the increase in environmental awareness in the agriculture, construction, forestry, and mining industries, and to the increasing number of local regulations primarily throughout Europe. Caterpillar has responded to this need by publishing a requirement, Caterpillar BF-1, that may be used by Caterpillar dealers, customers, and industry to help select high-performance biodegradable hydraulic fluids. This requirement was written with the input of several organizations that are known to be involved with the development of similar types of specifications and requirements.
Technical Paper

A Study of the Vapor- and Particle-Phase Sulfur Species in the Heavy-Duty Diesel Engine EGR Cooler

1998-05-04
981423
To meet future NO, heavy-duty diesel emissions standards, exhaust gas recirculation (EGR) technology is likely to be used. To improve fuel economy and further lower emissions, the recirculated exhaust gas needs to be cooled, with the possibility that cooling of the exhaust gas may form sulfuric acid condensate in the EGR cooler. This corrosive condensate can cause EGR cooler failure and consequentially result in severe damage to the engine. Both a literature review and a preliminary experimental study were conducted. In this study, a manually controlled EGR system was installed on a 1995 Cummins Ml l-330E engine which was operated at EPA mode 9* (1800 rpm and 75% load). The Goksoyr-Ross method (1)** was used to measure the particle-phase sulfate and vapor-phase H2SO4 and SO2 at the inlet and outlet locations of the EGR cooler, obtaining H2SO4 and SO2 concentrations. About 0.5% of fuel sulfur in the EGR cooler was in the particle-phase.
Technical Paper

Effects of Injection Pressure and Nozzle Geometry on Spray SMD and D.I. Emissions

1995-10-01
952360
A study was performed to correlate the Sauter Mean Diameter (SMD), NOx and particulate emissions of a direct injection diesel engine with various injection pressures and different nozzle geometry. The spray experiments and engine emission tests were conducted in parallel using the same fuel injection system and same operating conditions. With high speed photography and digital image analysis, a light extinction technique was used to obtain the spray characteristics which included spray tip penetration length, spray angle, and overall average SMD for the entire spray. The NOx and particulate emissions were acquired by running the tests on a fully instrumented Caterpillar 3406 heavy duty engine. Experimental results showed that for higher injection pressures, a smaller SMD was observed, i.e. a finer spray was obtained. For this case, a higher NOx and lower particulate resulted.
Technical Paper

Meeting the Customer's Needs - Defining the Next Generation Electronically Controlled Unit Injector Concept for Heavy Duty Diesel Engines

1996-04-01
961285
Diesel engine manufacturers have been asking for new, innovative, flexible fuel injection systems in order to meet future diesel engine emission requirements throughout the world and improve engine performance. Engineers at Caterpillar have listened to these requests and developed a fuel system concept to meet their needs. This new fuel system is called the Next Generation Electronic Unit Injector (NGEUI). The new concept is adaptable to mechanically actuated electronic unit injector, hydraulic electronic unit injector, electronic unit pump, and pump/line/nozzle systems. Features of the new fuel system are listed below: 1. Fully controllable injection pressure independent of engine speed and load 2. Injection pressure capability to 207 MPa (30,000 psi) 3. Reduced drive train torsional excitation and improved hydraulic efficiency 4.
Technical Paper

Nozzle Effect on High Pressure Diesel Injection

1995-02-01
950083
Studies of transient diesel spray characteristics at high injection pressures were conducted in a constant volume chamber by utilizing a high speed photography and light extinction optical diagnostic technique. Two different types of nozzle hole entrances were investigated: a sharp-edged and a round-edged nozzle. The experimental results show that for the same injection delivery, the sharp-edged inlet injector needed a higher injection pressure to overcome the higher friction loss, but it produced longer spray tip penetration length, larger spray angle, smaller droplet sizes, and also lower particulate emission from a parallel engine test. For the round-edged and smooth edged tips at the same injection pressure, the sharp-edged inlet tip took a longer injection duration to deliver a fixed mass of fuel and produced larger overall average Sauter Mean Diameter (SMD) droplets.
Technical Paper

A 2-D Computational Model Describing the Flow and Filtration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980545
A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.
Technical Paper

A 2-D Computational Model Describing the Heat Transfer, Reaction Kinetics and Regeneration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980546
A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.
Technical Paper

Effect of Fuel Composition and Altitude on Regulated Emissions from a Lean-Burn, Closed Loop Controlled Natural Gas Engine

1997-05-01
971707
Natural gas presents several challenges to engine manufacturers for use as a heavy-duty, lean burn engine fuel. This is because natural gas can vary in composition and the variation is large enough to produce significant changes in the stoichiometry of the fuel and its octane number. Similarly, operation at high altitude can present challenges. The most significant effect of altitude is lower barometric pressure, typically 630 mm Hg at 1600 m compared to a sea level value of 760 mm. This can lower turbocharger boost at low speeds leading to mixtures richer than desired. The purpose of this test program was to determine the effect of natural gas composition and altitude on regulated emissions and performance of a Cummins B5.9G engine. The engine is a lean-burn, closed loop control, spark ignited, dedicated natural gas engine. For fuel composition testing the engine was operating at approximately 1600 m (5,280 ft) above sea level.
Technical Paper

The Effect of a Ceramic Particulate Trap on the Particulate and Vapor Phase Emissions of a Heavy-Duty Diesel Engine

1991-02-01
910609
Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.
Technical Paper

Diesel Engine Flame Photographs With High Pressure Injection

1988-02-01
880298
The effect of high pressure injection (using an accumulator type unit injector with peak injection pressure of approximately 20,000 psi, having a decreasing injection rate profile) on combustion was studied. Combustion results were obtained using a DDA Series 3–53 diesel engine with both conventional analysis techniques and high speed photography. Diesel No. 2 fuel and a low viscosity - high volatility fuel, similar to gasoline were used in the study. Results were compared against baseline data obtained with standard injectors. Some of the characteristics of high pressure injection used with Diesel No. 2 fuel include: substantially improved ignition, shorter ignition delay, and higher pressure rise. Under heavy load - high speed conditions, greater smokemeter readings were achieved with the high pressure injection system with Diesel No. 2 fuel. Higher flame speeds and hence, greater resistance to knock were observed with the high volatility low cetane fuel.
Technical Paper

The Effects of Fuel Sulfur Concentration on Regulated and Unregulated Heavy-Duty Diesel Emissions

1993-03-01
930730
The effects of fuel sulfur concentration on heavy-duty diesel emissions have been studied at two EPA steady-state operating conditions, mode 9 (1900 RPM, 75% Load) and mode 11(1900 RPM, 25% Load). Data were obtained using one fuel at two sulfur levels (Low Sulfur, LS = 0.01 wt% S and Doped Low Sulfur DS = 0.29 wt% S). All tests were conducted using a Cummins LTA10-300 heavy-duty diesel engine. No significant changes were found for the nitrogen oxides (NOx), soluble organic fractions (SOF) and XAD-2 (a copolymer of styrene and divinylbenzene) organic component (XOC) due to the fuel sulfur level increase at either engine mode. The hydrocarbon (HC) levels were not significantly affected by sulfur at mode 9; however, at mode 11 the HC levels were reduced by 16%. The total particulate matter (TPM) levels increased by 17% at mode 11 and by 24% at mode 9 (both significantly different).
Technical Paper

Frictional Behavior of Electrogalvanized Sheet Steels

1993-03-01
930809
The frictional behavior of two nominally 70 g/m2 electrogalvanized sheet steels, mechanically processed with a series of surface roughnesses and coating morphologies, were evaluated with the bending under tension test. The crystallographic textures for the as-received materials were different; one was primarily prismatic with a friction coefficient of 0.14 and the other was primarily low angle pyramidal with a friction coefficient of 0.20. The friction coefficients were changed by surface modifications and values as high as 0.31 were observed. Friction data are discussed in terms of surface roughness, interfacial contact pressure, true contact area, and crystallographic texture. Results are interpreted on the basis of the deformation characteristics of the zinc coatings and with respect to overall sheet formability characteristics.
Technical Paper

The Development of a Production Qualified Catalytic Converter

1993-03-01
930133
Catalytic converters have become a viable aftertreatment system for reducing emissions from on-highway diesel engines. This paper addresses the development and production qualification of a catalytic converter. The testing programs that were utilized to qualify the converter system for production included emissions performance, emissions durability, physical durability, and field test programs. This paper reports on the specific tests that were utilized for the emissions performance and emissions durability testing programs. An explanation on the development of an accelerated durability test program is also included. The physical durability section of the paper discusses the development and execution of laboratory bench tests to insure the catalytic converter/muffler maintains acceptable physical integrity.
Technical Paper

Engine Electronics Technology

1993-09-01
932404
Electronics technology has evolved significantly since the first electronically controlled heavy duty on-highway truck engines were introduced in the mid 1980's. Engine control hardware, software, and sensor designs have been driven by many factors. Emissions regulations, fuel economy, engine performance, operator features, fleet management information, diagnostics, vehicle integration, reliability, and new electronics technology are some of those factors. The latest engine electronics technology is not only found in heavy duty on-highway trucks, but in off-highway applications as well. Track-type tractors, haul trucks, wheel loaders, and agricultural tractors now benefit from the advantages of electronic engines. And, many more new applications are being developed.
Technical Paper

Effect of Sulfur on Microstructure and Properties of Medium-Carbon Microalloyed Bar Steels

1992-02-01
920532
Three heats of 0.40% carbon microalloyed steel, containing either 0.03 % or 0.10% sulfur, and with and without a 0.09% vanadium addition, were subjected to metallographic analysis and mechanical property testing. Bars were heated to austenitizing temperatures, between 1000°C and 1300°C. Significant amounts of intragranular ferrite, which has been associated with improved toughness, formed only in specimens containing vanadium and high sulfur which were austenitized above 1100°C. The balance of the microstructure consisted of ferrite which formed at prior austenite grain boundaries and large amounts of pearlite. High densities of manganese sulfide particles in the steels with high sulfur content effectively retarded austenite grain growth. The formation of significant amounts of intragranular ferrite decreased mean free ferrite spacing, effectively refined the pearlite structure, and lowered the Charpy V-notch impact transition temperature.
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