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Video

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications [1,2,3,4]. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH3 storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH3 storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH3 slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.
Video

SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Video

Brief Investigation of SCR High Temperature N2O Production

2012-06-18
Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.
Video

Evaluation of a NOx Transient Response Method for OBD of SCR Catalysts

2012-01-30
OBD requirements for aftertreatment system components require monitoring of the individual system components. One such component can be an NH3-SCR catalyst for NOx reduction. An OBD method that has been suggested is to generate positive or negative spikes in the inlet NH3 concentration, and monitor the outlet NOx transient response. A slow response indicates that the catalyst is maintaining its NH3 storage capacity, and therefore it is probably not degraded. A fast response indicates the catalyst has lost NH3 storage capacity, and may be degraded. The purpose of the work performed at Southwest Research Institute was to assess this approach for feasibility, effectiveness and practicality. The presentation will describe the work performed, results obtained, and implications for applying this method in test laboratory and real-world situations. Presenter Gordon J. Bartley, Southwest Research Institute
Video

Overview of Southwest Research Institute Activities in Engine Technology R&D

2012-05-10
The worldwide drive to improved energy efficiency for engine systems is being supported by several engine R&D programs at Southwest Research Institute (SwRI). This research includes large programs in major-market engine categories, such as heavy-duty, non-road, and light-duty; and includes diesel, gasoline, and alternative fuel aspects. This presentation describes several key diesel engine programs being pursued under the SwRI Clean High Efficiency Diesel Engine consortium (CHEDE-VI), whose goal is to demonstrate future diesel technology exceeding 50% brake thermal efficiency. Additionally, SwRI?s High Efficiency Dilute Gasoline Engines consortium (HEDGE-II), is reviewed, where advanced technology for ultra-high efficiency gasoline engines is being demonstrated. The HEDGE-II program is built upon dilute gasoline engine research, where brake thermal efficiencies in excess of 42% are being obtained for engines applicable to the light-duty market. Presenter Charles E.
Video

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO2 oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Video

Real time Renewable Energy Availability for EV Charging

2012-03-29
Battery Electric Vehicles and Extended Range Electric Vehicles, like the Chevrolet Volt, can use electrical energy from the Grid to meet the majority of a driver�s transportation needs. This has the positive societal effects of displace petroleum consumption and associated pollutants from combustion on a well to wheels basis, as well as reduced energy costs for the driver. CO2 may also be lower, but this depends upon the nature of the grid energy generation. There is a mix of sources � coal-fired, gas -fired, nuclear or renewables, like hydro, solar, wind or biomass for grid electrical energy. This mix changes by region, and also on the weather and time of day. By monitoring the grid mix and communicating it to drivers (or to their vehicles) in real-time, electrically driven vehicles may be recharged to take advantage of the lowest CO2, and potentially lower cost charging opportunities.
Video

The Utility and Fuel Consumption of Hybrid and Electric Vehicles

2012-03-27
There are now a wide variety of Hybrid and Electric Vehicles in or near production. They reduce or displace petroleum consumption with of various combinations of conventional IC engine, mechanical transmission, liquid fuel storage, electrical energy storage, electrical and electro-mechanical energy conversion, and vehicle-to-grid energy interface. These Electrified types of vehicles include Mild Hybrid, Full Hybrid, Plug-In Hybrid, Extended Range Electric, and Battery Electric. Some types differ in their actual usability for the real mixes of driving trips, and further that differ in their effectiveness to reduce or displace fuel in actual real world driving use. Vehicle size is also a factor in total vehicle utility in transporting people. If we may segment drivers by their driving needs, in each segment, we see a particular type of electrified vehicle that is better suited than others at minimizing fuel cost and petroleum consumption for the purposes of transporting people.
Technical Paper

The Effects of Different Input Excitation on the Dynamic Characterization of an Automotive Shock Absorber

2001-04-30
2001-01-1442
This paper deals with the dynamic characterization of an automotive shock absorber, a continuation of an earlier work [1]. The objective of this on-going research is to develop a testing and analysis methodology for obtaining dynamic properties of automotive shock absorbers for use in CAE-NVH low-to-mid frequency chassis models. First, the effects of temperature and nominal length on the stiffness and damping of the shock absorber are studied and their importance in the development of a standard test method discussed. The effects of different types of input excitation on the dynamic properties of the shock absorber are then examined. Stepped sine sweep excitation is currently used in industry to obtain shock absorber parameters along with their frequency and amplitude dependence. Sine-on-sine testing, which involves excitation using two different sine waves has been done in this study to understand the effects of the presence of multiple sine waves on the estimated dynamic properties.
Technical Paper

External Corrosion Resistance of CuproBraze® Radiators

2001-05-14
2001-01-1718
New technology for the manufacturing of copper/brass heat exchangers has been developed and the first automotive radiators are already in operation in vehicles. This new technology is called CuproBraze®. One of the essential questions raised is the external corrosion resistance with reference to the present soldered copper/brass radiators and to the brazed aluminium radiators. Based on the results from electrochemical measurements and from four different types of accelerated corrosion tests, the external corrosion resistance of the CuproBraze® radiators is clearly better than that of the soldered copper/brass radiators and competitive with the brazed aluminum radiators, especially as regards marine atmosphere. Due to the relatively high strength of the CuproBraze® heat exchangers, down gauging of fins and tubes in some applications is attractive. High performance coatings can ensure long lifetime from corrosion point of view, even for thin gauge heat exchangers.
Technical Paper

The Effects of Natural Aging on Fleet and Durability Vehicle Engine Mounts from a Dynamic Characterization Perspective

2001-04-30
2001-01-1449
Elastomers are traditionally designed for use in applications that require specific mechanical properties. Unfortunately, these properties change with respect to many different variables including heat, light, fatigue, oxygen, ozone, and the catalytic effects of trace elements. When elastomeric mounts are designed for NVH use in vehicles, they are designed to isolate specific unwanted frequencies. As the elastomers age however, the desired elastomeric properties may have changed with time. This study looks at the variability seen in new vehicle engine mounts and how the dynamic properties change with respect to miles accumulated on fleet and durability test vehicles.
Technical Paper

Material Damping Properties: A Comparison of Laboratory Test Methods and the Relationship to In-Vehicle Performance

2001-04-30
2001-01-1466
This paper presents the damping effectiveness of free-layer damping materials through standard Oberst bar testing, solid plate excitation (RTC3) testing, and prediction through numerical schemes. The main objective is to compare damping results from various industry test methods to performance in an automotive body structure. Existing literature on laboratory and vehicle testing of free-layer viscoelastic damping materials has received significant attention in recent history. This has created considerable confusion regarding the appropriateness of different test methods to measure material properties for damping materials/treatments used in vehicles. The ability to use the material properties calculated in these tests in vehicle CAE models has not been extensively examined. Existing literature regarding theory and testing for different industry standard damping measurement techniques is discussed.
Technical Paper

Impact of Lubricant Oil on Regulated Emissions of a Light-Duty Mercedes-Benz OM611 CIDI-Engine

2001-05-07
2001-01-1901
The Partnership for a New Generation Vehicle (PNGV) has identified the compression-ignition, direct-injection (CIDI) engine as a promising technology in meeting the PNGV goal of 80 miles per gallon for a prototype mid-size sedan by 2004. Challenges remain in reducing the emission levels of the CIDI-engine to meet future emission standards. The objective of this project was to perform an initial screening of crank case lubricant contribution to regulated engine-out emissions, particularly when low particulate forming diesel fuel formulations are used. The test engine was the Mercedes-Benz OM611, the test oils were a mineral SAE 5W30, a synthetic (PAO based) SAE 5W30, and a synthetic (PAO based) SAE 15W50, and the test fuels were a California-like certification fuel and an alternative oxygenated diesel fuel.
Technical Paper

Real-Time Transient and Steady-State Measurement of Oil Consumption for Several Production SI-Engines

2001-05-07
2001-01-1902
Real-time transient and steady-state oil consumption were measured on three SI-engines, applying two different ring-packs to each engine. Testing of multiple engines enables an assessment of the engine-to-engine variability in oil consumption. Testing of multiple ring-packs on each engine enables an assessment of the ring-pack-to-ring-pack variability in oil consumption. The oil consumption was measured by the Southwest Research Institute (SwRI) novel developed SO2-tracer technique, referred to as RTOC-III. An interesting finding is that the testing shows low engine-to-engine and ring-pack-to-ring-pack variability, in both steady-state, as well as in transient oil consumption. This suggests that the RTOC-III system did not introduce significant variability to the data. The testing results are experimental verification of a design and simulation exercise, in a field of scarcely published literature.
Technical Paper

Fuel Evaporation Parameter Identification during SI Cold Start

2001-03-05
2001-01-0552
The stochastic properties of continuous time model parameters obtained through discrete least squares estimation are examined. Particular attention is given to the application of estimating the fuel evaporation dynamics of a V-8 SI engine. The continuous time parameter distributions in this case are biased. The bias is shown to be a function of both measurement noise and sampling rate selection. Analysis and experimental results suggest that for each particular model, there is a corresponding optimum sampling rate. A bias compensation formula is proposed that improves the accuracy of least squares estimation without iterative techniques.
Technical Paper

Conductive Polyphenylene Ether/Polyamide Blend for Saturn Exterior Body Panels

2001-03-05
2001-01-0446
The evolution toward the use of electrostatic painting processes has been driven primarily by environmental legislation and efforts to improve efficiencies in the painting process. The development of conductive substrate material compliments the industry trend toward a green environment through further reductions in emissions of volatile organic compounds during the painting process. Traditionally, electrostatic painting of thermoplastics requires that a conductive primer be applied to the substrate prior to topcoat application. The conductive polymer blend of polyphenylene ether and polyamide provides sufficient conductivity to eliminate usage of conductive primers. Additional benefits include improved transfer efficiencies of the primer and top coat systems, uniform film builds across the part, and improved painting of complex geometries.
Technical Paper

Heavy-Duty Diesel Truck In-Use Emission Test Program for Model Years 1950 through 1975

2001-03-05
2001-01-1327
Criteria pollutants were measured from ten Class 7 and 8 (i.e., gross vehicle weights > 33,000 lb) heavy-duty diesel trucks with engine model years between 1953 and 1975. The data was used by EPA to estimate that period's particulate matter emission rates for these type engines and will be used to develop dose response relationships with existing epidemiological data. Particulate samples were analyzed for sulfate and volatile organic fraction. Carbon soot was estimated. The trucks had particulate emissions of 2 to 10 g/mi as compared to 1 to 6 g/mi for trucks with model year engines from 1975 through the mid-1980s, and less than 1 g/mi for post-1988 trucks.
Technical Paper

Control Strategies for a Series-Parallel Hybrid Electric Vehicle

2001-03-05
2001-01-1354
Living in the era of rising environmental sensibility and increasing gasoline prices, the development of a new environmentally friendly generation of vehicles becomes a necessity. Hybrid electric vehicles are one means of increasing propulsion system efficiency and decreasing pollutant emissions. In this paper, the series-parallel power-split configuration for Michigan Technological University's FutureTruck is analyzed. Mathematical equations that describe the hybrid power-split transmission are derived. The vehicle's differential equations of motion are developed and the system's need for a controller is shown. The engine's brake power and brake specific fuel consumption, as a function of its speed and throttle position, are experimentally determined. A control strategy is proposed to achieve fuel efficient engine operation. The developed control strategy has been implemented in a vehicle simulation and in the test vehicle.
Technical Paper

Vektron® 6913 Gasoline Additive NOX Evaluation Fleet Test Program

2001-05-07
2001-01-1997
A 28-vehicle fleet test was executed to verify and quantify the NOX emissions reductions achieved through the use of Infineum's Vektron 6913 gasoline additive. The fleet composition and experimental design were finalized in collaborative discussions with US Environmental Protection Agency (EPA) Office of Transportation & Air Quality (OTAQ) and consultation / advice from several major US automotive manufacturers. The test was conducted over a period of five months at Southwest Research Institute. Statistical analysis of the emissions data indicated a 10% average fleet reduction in NOX emissions without any negative impact on other criteria pollutants (CO, HC) or fuel economy.
Technical Paper

Evaluation of the Ignition Hazard Posed by Onboard Refueling Vapor Recovery Canisters

2001-03-05
2001-01-0731
ORVR (Onboard Refueling Vapor Recovery) canisters trap vapors during normal operations of a vehicle's engine, and during refueling. This study evaluates the relative risks involved should a canister rupture in a crash. A canister impactor was developed to simulate real-world impacts and to evaluate the canisters' rupture characteristics. Numerous performance aspects of canisters were evaluated: the energy required to rupture a canister; the spread of carbon particles following rupture; the ease of ignition of vapor-laden particles; the vapor concentration in the area of ruptured, vapor-laden canisters; and the potential of crashes to rupture and ignite canisters. Results from these five items were combined into a risk analysis.
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