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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Technical Paper

The Effect of a Ceramic Particulate Trap on the Particulate and Vapor Phase Emissions of a Heavy-Duty Diesel Engine

1991-02-01
910609
Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.
Technical Paper

A 2-D Computational Model Describing the Heat Transfer, Reaction Kinetics and Regeneration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980546
A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.
Technical Paper

A Study of the Filtration and Oxidation Characteristics of a Diesel Oxidation Catalyst and a Catalyzed Particulate Filter

2007-04-16
2007-01-1123
An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.
Technical Paper

Thermal and Chemical Aging of Diesel Particulate Filters

2007-04-16
2007-01-1266
The effects of thermal and chemical aging on the performance of cordierite-based and high-porosity mullite-based diesel particulate filters (DPFs), were quantified, particularly their filtration efficiency, pressure drop, and regeneration capability. Both catalyzed and uncatalyzed core-size samples were tested in the lab using a diesel fuel burner and a chemical reactor. The diesel fuel burner generated carbonaceous particulate matter with a pre-specified particle-size distribution, which was loaded in the DPF cores. As the particulate loading evolved, measurements were made for the filtration efficiency and pressure drop across the filter using, respectively, a Scanning Mobility Particle Sizer (SMPS) and a pressure transducer. In a subsequent process and on a different bench system, the regeneration capability was tested by measuring the concentration of CO plus CO2 evolved during the controlled oxidation of the carbonaceous species previously deposited on the DPF samples.
Technical Paper

Experimental and Modeling Results Comparing Two Diesel Oxidation Catalyst - Catalyzed Particulate Filter Systems

2008-04-14
2008-01-0484
Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.
Technical Paper

Experimental Studies of an Advanced Ceramic Diesel Particulate Filter

2008-04-14
2008-01-0622
A Cummins ISB 5.9 liter medium-duty engine with cooled EGR has been used to study an early extrusion of an advanced ceramic uncatalyzed diesel particulate filter (DPF). Data for the advanced ceramic material (ACM) and an uncatalyzed cordierite filter of similar dimensions are presented. Pressure drop data as a function of mass loadings (0, 4, and 6 grams of particulate matter (PM) per liter of filter volume) for various flow rate/temperature combinations (0.115 - 0.187 kg/sec and 240 - 375 °C) based upon loads of 15, 25, 40 and 60% of full engine load (684 N-m) at 2300 rpm are presented. The data obtained from these experiments were used to calibrate the MTU 1-D 2-Layer computer model developed previously at MTU. Clean wall permeability determined from the model calibration for the ACM was 5.0e-13 m2 as compared to 3.0e-13 m2 for cordierite.
Technical Paper

A Methodology to Estimate the Mass of Particulate Matter Retained in a Catalyzed Particulate Filter as Applied to Active Regeneration and On-Board Diagnostics to Detect Filter Failures

2008-04-14
2008-01-0764
A methodology to estimate the mass of particulate retained in a catalyzed particulate filter as a function of measured total pressure drop, volumetric flow rate, exhaust temperature, exhaust gas viscosity and cake and wall permeability applicable to real-time computation is discussed. This methodology is discussed from the view point of using it to indicate when to initiate active regeneration and as an On-Board Diagnostic tool to detect filter failures. Steady-state loading characterization experiments were conducted on a catalyzed diesel particulate filter (CPF) in a Johnson Matthey CCRT® (catalyzed continuously regenerating trap) system. The experiments were performed using a 10.8 L 2002 Cummins ISM heavy-duty diesel engine. Experiments were conducted at 20, 60 and 75% of full engine load (1120 Nm) and rated speed (2100 rpm) to measure the pressure drop, transient filtration efficiency, particulate mass balance, and gaseous emissions.
Technical Paper

Development of a 1-D CPF Model to Simulate Active Regeneration of a Diesel Particulate Filter

2009-04-20
2009-01-1283
A quasi-steady 1-dimensional computer model of a catalyzed particulate filter (CPF) capable of simulating active regeneration of the CPF via diesel fuel injection upstream of a diesel oxidation catalyst (DOC) or other means to increase the exhaust gas temperature has been developed. This model is capable of predicting gaseous species concentrations (HC's, CO, NO and NO2) and exhaust gas temperatures within and after the CPF, for given input values of gaseous species and PM concentrations before the CPF and other inlet variables such as time-varying temperature of the exhaust gas at the inlet of the CPF and volumetric flow rate of exhaust gas.
Technical Paper

The Filtration, Oxidation and Pressure Drop Characteristics of a Catalyzed Particulate Filter during Active Regeneration – A 1D Modeling Study

2009-04-20
2009-01-1274
Active regeneration of a catalyzed particulate filter (CPF) is affected by a number of parameters specifically particulate matter loading and inlet temperature. The MTU 1-D 2-Layer CPF model [1] was used to analyze these effects on the pressure drop, oxidation and filtration characteristics of a CPF during active regeneration. In addition, modeling results for post loading experiments were analyzed to understand the difference between loading a clean filter as compared to a partially regenerated filter. Experimental data obtained with a production Cummins regenerative particulate filter for loading, active regenerations and post loading experiments were used to calibrate the MTU 1-D 2-Layer CPF model. The model predicted results are compared with the experimental data and were analyzed to understand the CPF characteristics during active regeneration at 1.1, 2.2 and 4.1 g/L particulate matter (PM) loading and CPF inlet temperatures of 525, 550 and 600°C.
Technical Paper

An Experimental Study of Particulate Thermal Oxidation in a Catalyzed Filter During Active Regeneration

2009-04-20
2009-01-1474
Active regeneration experiments were performed on a Cummins 2007 aftertreatment system by hydrocarbon dosing with injection of diesel fuel downstream of the turbocharger. The main objective was to characterize the thermal oxidation rate as a function of temperature and particulate matter (PM) loading of the catalyzed particulate filter (CPF). Partial regeneration tests were carried out to ensure measureable masses are retained in the CPF in order to model the oxidation kinetics. The CPF was subsequently re-loaded to determine the effects of partial regeneration during post-loading. A methodology for gathering particulate data for analysis and determination of thermal oxidation in a CPF system operating in the engine exhaust was developed. Durations of the active regeneration experiments were estimated using previous active regeneration work by Singh et al. 2006 [1] and were adjusted as the experiments progressed using a lumped oxidation model [2, 3].
Technical Paper

Experimental Study Comparing Particle Size and Mass Concentration Data for a Cracked and Un-Cracked Diesel Particulate Filter

2009-04-20
2009-01-0629
Steady state loading characterization experiments were conducted at three different engine load conditions and rated speed on the cracked catalyzed particulate filter (CPF). The experiments were performed using a 10.8 L 2002 Cummins ISM-330 heavy duty diesel engine. The CPF underwent a ring off failure, commonly seen in particulate filters, due to high radial and axial temperature gradients. The filters were cracked during baking in an oven which was done to regenerate PM collected after every loading characterization experiment. Two different configurations i.e. with and without a diesel oxidation catalyst (DOC) upstream of the CPF were studied. The data were compared with that on an un-cracked CPF at similar engine conditions and configurations. Pressure drop, transient filtration efficiency by particle size and PM mass and gaseous emissions measurements were made during each experiment.
Technical Paper

Lean-NOx and Plasma Catalysis Over γ-Alumina for Heavy Duty Diesel Applications

2001-09-24
2001-01-3569
The NOx reduction performance under lean conditions over γ-alumina was evaluated using a micro-reactor system and a non-thermal plasma-equipped bench test system. Various alumina samples were obtained from alumina manufacturers to assess commercial alumina materials. In addition, γ-alumina samples were synthesized at Caterpillar with a sol-gel technique in order to control alumina properties. The deNOx performances of the alumina samples were compared. The alumina samples were characterized with analytical techniques such as inductively coupled plasma (ICP) emission spectroscopy, temperature programmed desorption (TPD) and surface area measurements (BET) to understand physical and chemical properties. The information derived from these techniques was correlated with the NOx reduction performance to identify key parameters of γ-alumina for optimizing materials for lean-NOx and plasma assisted catalysis.
Technical Paper

A One-Dimensional Computational Model for Studying the Filtration and Regeneration Characteristics of a Catalyzed Wall-Flow Diesel Particulate Filter

2003-03-03
2003-01-0841
A one-dimensional, two layer computational model was developed to predict the behavior of a clean and particulate-loaded catalyzed wall-flow diesel particulate filter (CPF). The model included the mechanisms of particle deposition inside the CPF porous wall and on the CPF wall surface, the exhaust flow field and temperature field inside the CPF, as well as the particulate catalytic oxidation mechanisms accounting for the catalyst-assisted particulate oxidation by the catalytic coating in addition to the conventional particulate thermal oxidation. The paper also develops the methodology for calibrating and validating the model with experimental data. Steady state loading experiments were performed to calibrate and validate the model.
Technical Paper

Modeling and Numerical Simulation of Diesel Particulate Trap Performance During Loading and Regeneration

2002-03-04
2002-01-1019
A 2-dimensional numerical model (MTU-FILTER) for a single channel of a honeycomb ceramic diesel particulate trap has been developed. The mathematical modeling of the filtration, flow, heat transfer and regeneration behavior of the particulate trap is described. Numerical results for the pressure drop and particulate mass were compared with existing experimental results. Parametric studies of the diesel particulate trap were carried out. The effects of trap size and inlet temperature on the trap performance are studied using the trap model. An approximate 2-dimensional analytical solution to the simplified Navier-Stokes equations was used to calculate the velocity field of the exhaust flow in the inlet and outlet channels. Assuming a similarity velocity profile in the channels, the 2-dimensional Navier-Stokes equations are approximated by 1-dimenisonal conservation equations, which is similar to those first developed by Bissett.
Technical Paper

A Combustion Model for Multi-Component Fuels Based on Reactivity Concept and Single-Surrogate Chemistry Representation

2018-04-03
2018-01-0260
High fidelity engine simulation requires realistic fuel models. Although typical automotive fuels consist of more than few hundreds of hydrocarbon species, researches show that the physical and chemical properties of the real fuels could be represented by appropriate surrogate fuel models. It is desirable to represent the fuel using the same set of physical and chemical surrogate components. However, when the reaction mechanisms for a certain physical surrogate component is not available, the chemistry of the unmatched physical component is described using that of a similar chemical surrogate component at the expense of accuracy. In order to reduce the prediction error while maintaining the computational efficiency, a method of on-the-fly reactivity adjustment (ReAd) of chemical reaction mechanism along with fuel re-distribution based on reactivity is presented and tested in this study.
Technical Paper

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-04-16
2012-01-0837
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO₂ oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Technical Paper

Development of a Rotating Plasma Burner for the Regeneration of Diesel Particulate Filters

2013-10-14
2013-01-2503
A Diesel Particulate Filter (DPF) is an effective technology for reducing Particulate Matter (PM) emitted from diesel engines. In modern light duty diesel engines, DPF is regenerated by the post-fuel-injection method. In this method, the fuel is injected into the combustion chamber during the expansion stroke to produce heat to burn out the PM trapped in the DPF. However, this method also causes several problems, such as complicated engine torque control and oil dilution by fuel. In this study, a rotating plasma burner was developed for DPF regeneration as an alternative to the postfuel-injection method. Since it is important to reduce the electric energy consumption for plasma generation, which is directly related with electric noise and system cost, several design factors, such as the boosting voltage of transformers, electrode gaps, and plasma frequency were evaluated. A transformer with a low boosting voltage is desirable to ensure low electric noise.
Technical Paper

A 2-D Computational Model Describing the Flow and Filtration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980545
A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.
Technical Paper

An Experimental Study of Active Regeneration of an Advanced Catalyzed Particulate Filter by Diesel Fuel Injection Upstream of an Oxidation Catalyst

2006-04-03
2006-01-0879
Passive regeneration (oxidation of particulate matter without using an external energy source) of particulate filters in combination with active regeneration is necessary for low load engine operating conditions. For low load conditions, the exhaust gas temperatures are less than 250°C and the PM oxidation rate due to passive regeneration is less than the PM accumulation rate. The objective of this research was to experimentally investigate active regeneration of a catalyzed particulate filter (CPF) using diesel fuel injection in the exhaust gas after the turbocharger and before a diesel oxidation catalyst (DOC) and to collect data for extending the MTU 1-D 2-layer model to include the simulation of active regeneration. The engine used in this study was a 2002 Cummins ISM turbo charged 10.8 L heavy duty diesel engine with cooled EGR. The exhaust after-treatment system consisted of a Johnson Matthey DOC and CPF (a CCRT®).
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