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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

The target of the investigation is the particular influence of a fuel injection system and its components as a noise source in automotive engines. The applied methodology is demonstrated on an automotive Inline 4-cylinder Diesel engine using a common rail system. This methodology is targeted as an extension of a typical standard acoustic simulation approach for combustion engines. Such approaches basically use multi-body dynamic simulation with interacting FEM based flexible structures, where the main excitation crank train, timing drive, valve train system and piston secondary motion are considered. Within the extended approach the noise excitation of the hydraulic and mechanical parts of the entire fuel system is calculated and subsequently considered within the multi-body dynamic simulation for acoustic evaluation of structural vibrations.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

This paper presents a newly developed quasi-dimensional multi-zone dual fuel combustion model, which has been integrated within the commercial engine system simulation framework. Model is based on the modified Multi-Zone Combustion Model and Fractal Combustion Model. Modified Multi-Zone Combustion Model handles the part of the combustion process that is governed by the mixing-controlled combustion, while the modified Fractal Combustion Model handles the part that is governed by the flame propagation through the combustion chamber. The developed quasi-dimensional dual fuel combustion model features phenomenological description of spray processes, i.e. liquid spray break-up, fresh charge entrainment, droplet heat-up and evaporation process. In order to capture the chemical effects on the ignition delay, special ignition delay table has been made.

Nowadays, detailed kinetics is necessary for a proper estimation of both flame structure and pollutant formation in compression ignition engines. However, large mechanisms and the need to include turbulence/chemistry interaction introduce significant computational overheads. For this reason, tabulated kinetics is employed as a possible solution to reduce the CPU time even if table discretization is generally limited by memory occupation. In this work the authors applied tabulated homogeneous reactors (HR) in combination with different turbulent-chemistry interaction approaches to model non-premixed turbulent combustion. The proposed methodologies represent good compromises between accuracy, required memory and computational time. The experimental validation was carried out by considering both constant-volume vessel and Diesel engine experiments.

The modeling of fuel sprays under well-characterized conditions relevant for heavy-duty Diesel engine applications, allows for detailed analyses of individual phenomena aimed at improving emission formation and fuel consumption. However, the complexity of a reacting fuel spray under heavy-duty conditions currently prohibits direct simulation. Using a systematic approach, we extrapolate available spray models to the desired conditions without inclusion of chemical reactions. For validation, experimental techniques are utilized to characterize inert sprays of n-dodecane in a high-pressure, high-temperature (900 K) constant volume vessel with full optical access. The liquid fuel spray is studied using high-speed diffused back-illumination for conditions with different densities (22.8 and 40 kg/m3) and injection pressures (150, 80 and 160 MPa), using a 0.205-mm orifice diameter nozzle.

This paper investigates an optimal design of a diesel engine and after-treatment systems for a series hybrid electric forklift application. A holistic modeling approach is developed in GT-Suite® to establish a model-based hardware definition for a diesel engine and an after-treatment system to accurately predict engine performance and emissions. The used engine model is validated with the experimental data. The engine design parameters including compression ratio, boost level, air-fuel ratio (AFR), injection timing, and injection pressure are optimized at a single operating point for the series hybrid electric vehicle, together with the performance of the after-treatment components. The engine and after-treatment models are then coupled with a series hybrid electric powertrain to evaluate the performance of the forklift in the standard VDI 2198 drive cycle.

Increasing regulatory demand for efficiency has led to development of novel combustion modes such as HCCI, GCI and RCCI for gasoline light duty engines. In order to realize HCCI as a compression ignition combustion mode system, in-cylinder compression temperatures must be elevated to reach the autoignition point of the premixed fuel/air mixture. This should be co-optimized with appropriate fuel formulations that can autoignite at such temperatures. CFD combustion modeling is used to model the auto ignition of gasoline fuel under compression ignition conditions. Using the fully detailed fuel mechanism consisting of thousands of components in the CFD simulations is computationally expensive. To overcome this challenge, the real fuel is represented by few major components of create a surrogate fuel mechanism. In this study, 9 variations of gasoline fuel sets were chosen as candidates to run in HCCI combustion mode.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.

In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

Research into the estimation of diesel engine combustion metrics via non-intrusive means, typically referred to as “remote combustion sensing” has become an increasingly active area of combustion research. Success in accurately estimating combustion metrics with low-cost non-intrusive transducers has been proven and documented by multiple sources on small scale diesel engines (2-4 cylinders, maximum outputs of 67 Kw, 210 N-m). This paper investigates the application of remote combustion sensing technology to a larger displacement inline 6-cylinder diesel with substantially higher power output (280 kW, 1645 N-m) than previously explored. An in-depth frequency analysis has been performed with the goal of optimizing the estimated combustion signature which has been computed based upon the direct relationship between the combustion event measured via a pressure transducer, and block vibration measured via accelerometers.

NOx and PM are the critical emissions to meet the legislation limits for diesel engines. Often a value for these emissions is needed online for on-board diagnostics, engine control, exhaust aftertreatment control, model-based controller design or model-in-the-loop simulations. Besides the obvious method of measuring these emissions, a sensible alternative is to estimate them with virtual sensors. A lot of literature can be found presenting different modeling approaches for NOx emissions. Some are very close to the physics and the chemical reactions taking place inside the combustion chamber, others are only given by adapting general functions to measurement data. Hence, generally speaking, there is not a certain method which is seen as the solution for modeling emissions. Finding the best model approach is not straightforward and depends on the model application, the available measurement channels and the available data set for calibration.

Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.

The continuously decreasing emission limits lead to a growing importance of exhaust aftertreatment in Diesel engines. Hence, methods for achieving a rapid catalyst light-off after engine cold start and for maintaining the catalyst temperature during low load operation will become more and more necessary. The present work evaluates several valve timing strategies concerning their ability for doing so. For this purpose, simulations as well as experimental investigations were conducted. A special focus of simulation was on pointing out the relevance of exhaust temperature, mass flow and enthalpy for these thermomanagement tasks. An increase of exhaust temperature is beneficial for both catalyst heat-up and maintaining catalyst temperature. In case of the exhaust mass flow, high values are advantageous only in case of a catalyst heat-up process, while maintaining catalyst temperature is supported by a low mass flow.

Particulate emission reduction has long been a challenge for diesel engines as the diesel diffusion combustion process can generate high levels of soot which is one of the main constituents of particulate matter. Gasoline engines use a pre-mixed combustion process which produces negligible levels of soot, so particulate emissions have not been an issue for gasoline engines, particularly with modern port fuel injected (PFI) engines which provide excellent mixture quality. Future European and US emissions standards will include more stringent particulate limits for gasoline engines to protect against increases in airborne particulate levels due to the more widespread use of gasoline direct injection (GDI). While GDI engines are typically more efficient than PFI engines, they emit higher particulate levels, but still meet the current particulate standards.

This paper describes a study to demonstrate the feasibility of developing an acoustic encapsulation to reduce airborne noise from a commercial diesel engine. First, the various sources of noise from the engine were identified using Nearfield Acoustical Holography (NAH). Detailed NAH measurements were conducted on the four sides of the engine in an engine test cell. The main sources of noise from the engine were ranked and identified within the frequency ranges of interest. Experimental modal analysis was conducted on the oil pan and front cover plate of the engine to reveal correlations of structural vibration results with the data from the NAH. The second phase of the study involved the design and fabrication of the acoustical encapsulation (noise covers) for the engine in a test cell to satisfy the requirements of space, cost and performance constraints. The acoustical materials for the enclosure were selected to meet the frequency and temperature ranges of interest.

A previously developed CFD-based optimization tool is utilized to find optimal engine operating conditions with respect to fuel consumption and emissions. The optimization algorithm employed is based on the steepest descent method where an adaptive cost function is minimized along each line search using an effective backtracking strategy. The adaptive cost function is based on the penalty method, where the penalty coefficient is increased after every line search. The parameter space is normalized and, thus, the optimization occurs over the unit cube in higher-dimensional space. The application of this optimization tool is demonstrated for the Sulzer S20, a central-injection, non-road DI diesel engine. The optimization parameters are the start of injection of the two pulses of a split injection system, the duration of each pulse, the exhaust gas recirculation rate, the boost pressure and the compression ratio.