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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO2 oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Technical Paper

Overall Results: Phase I Ad Hoc Diesel Fuel Test Program

The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.
Technical Paper

Flame Temperature Correlation of Emissions from Diesels Operated on Alternative Fuels

Work by Plee, Ahmad, and coworkers in the 1980s [1, 2, 3, 4 and 5] showed that for changes in intake air state, Diesel NOx, soot, soluble organic fraction, and HC emissions could be correlated using the stoichiometric flame temperature calculated at SOC or peak pressure conditions. In the present work, similar flame temperature correlations are obtained for emissions from three test engines; a 1.2L high speed direct injection (HSDI) Diesel, a 2.4L HSDI Diesel, and a 2.34 L single cylinder direct injection (DI) Diesel engine, the first of which was tested using four alternative fuels. Use of the flame temperature correlations presented may reduce the number of engine tests required to evaluate the effects of EGR on emissions of NOx, particulate, and HC, even when alternative fuels are used.
Technical Paper

PIV Characterization of a 4-valve Engine with a Camshaft Profile Switching (CPS) system

Particle Image Velocimetry (PIV) measurements were performed on a single cylinder optically accesible version of a 3.0L 4-valve engine using a Camshaft Profile Switching (CPS) system. The flow field was investigated at two engine speeds (750 and 1500 rpm), two manifold pressures (75 and 90 kPa) and two intake cam centerlines (maximum lift at 95° and 115° aTDCi respectively). Images were taken in the swirl plane at 10 mm and 40 mm below the deck with the piston at 300° aTDC of intake (60° bTDC compression) and BDC respectively. In the tumble plane, images were taken in a plane bisecting the intake valves with the piston at BDC and 300° aTDC. The results showed that the swirl ratio was slightly lower for this system compared with a SCV system (swirl control valve in the intake port) under the same operating conditions. The swirl and tumble ratios generated were not constant over the range of engine speeds and manifold pressures (MAP) but instead increased with engine speed and MAP.
Technical Paper

An Experimental Investigation of Spray Transfer Processes in an Electrostatic Rotating Bell Applicator

A better understanding is needed of the electrostatic rotating bell (ESRB) application of metallic basecoat paint to automobile exteriors in order to exploit their high transfer efficiency without compromising the coating quality. This paper presents the initial results from experimental investigation of sprays from an ESRB which is designed to apply water-borne paint. Water was used as paint surrogate for simplicity. The atomization and transport regions of the spray were investigated using laser light sheet visualizations and phase Doppler particle analyzer (PDPA). The experiments were conducted at varying levels of the three important operating parameters: liquid flow rate, shaping-air flow rate, and bellcup rotational speed. The results show that bellcup speed dominates atomization, but liquid and shaping-air flow rate settings significantly influence the spray structure. The visualization images showed that the atomization occurs in ligament breakup regime.
Technical Paper

Transient CFD Simulations of a Bell Sprayer

A methodology is developed that incorporates high resolution CFD flowfield information and a particle trajectory simulation, aimed at addressing Paint Transfer Efficiency (PTE) for bell sprayers. Given a solid model for the bell sprayer, the CFD simulation, through automeshing, determines a high resolution Cartesian volume mesh (14-20 million cells). With specified values of the initial shaping air, transient and steady-state flow field information is obtained. A particle trajectory visualization tool called SpraySIM uses this complicated flowfield information to determine the particle trajectories of the paint particles under the influence of drag, gravity and electrostatic potential. The sensitivity of PTE on shaping air velocity, charge-to-mass ratio, potential, and particle diameter are examined.
Technical Paper

The Effect of Dimethoxy Methane Additive on Diesel Vehicle Particulate Emissions

FTP emissions tests on a passenger vehicle equipped with a 1.8 L IDI turbo-charged diesel engine show that the mass emissions of particles decrease by (36±8)% when 16.6% dimethoxymethane (DMM) by volume is added to a diesel fuel. Particle size measurements reveal log-normal accumulation mode distributions with number weighted geometric mean diameters in the 80 - 100 nm range. The number density is comparable for both base fuel and the DMM/diesel blend; however, the distributions shift to smaller particle diameter for the blend. This shift to smaller size is consistent with the observed reduction in particulate mass. No change is observed in NOx emissions. Formaldehyde emissions increase by (50±25)%, while emissions of other hydrocarbons are unchanged to within the estimated experimental error.
Technical Paper

Laboratory Testing of Cabin Air Filters for the Removal of Reduced-Sulfur Odors

The next generation of cabin air filters will include the ability to remove not only particulate matter, but odors as well. A key element in the development of odor removal filters is the design of laboratory tests to predict in-service performance. The studies described in this report used a combination of subjective and objective test methods to evaluate a series of odor-removal filters for their ability to remove environmentally significant reduced sulfur compounds. The work was performed in two parts. In the first part the detection, recognition, and annoyance thresholds for hydrogen sulfide and methyl mercaptan were measured using a 37-member odor panel. The second part consisted of a group of tests in which the contaminant concentrations upstream and downstream of six types of filters were measured using an instrumental method.
Technical Paper

A 2-D Computational Model Describing the Flow and Filtration Characteristics of a Ceramic Diesel Particulate Trap

A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.
Technical Paper

A 2-D Computational Model Describing the Heat Transfer, Reaction Kinetics and Regeneration Characteristics of a Ceramic Diesel Particulate Trap

A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.
Technical Paper

The Effect of a Ceramic Particulate Trap on the Particulate and Vapor Phase Emissions of a Heavy-Duty Diesel Engine

Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.
Technical Paper

The Effects of Fuel Sulfur Concentration on Regulated and Unregulated Heavy-Duty Diesel Emissions

The effects of fuel sulfur concentration on heavy-duty diesel emissions have been studied at two EPA steady-state operating conditions, mode 9 (1900 RPM, 75% Load) and mode 11(1900 RPM, 25% Load). Data were obtained using one fuel at two sulfur levels (Low Sulfur, LS = 0.01 wt% S and Doped Low Sulfur DS = 0.29 wt% S). All tests were conducted using a Cummins LTA10-300 heavy-duty diesel engine. No significant changes were found for the nitrogen oxides (NOx), soluble organic fractions (SOF) and XAD-2 (a copolymer of styrene and divinylbenzene) organic component (XOC) due to the fuel sulfur level increase at either engine mode. The hydrocarbon (HC) levels were not significantly affected by sulfur at mode 9; however, at mode 11 the HC levels were reduced by 16%. The total particulate matter (TPM) levels increased by 17% at mode 11 and by 24% at mode 9 (both significantly different).
Technical Paper

Unregulated Emissions from a PROCO Engine Powered Vehicle

Unregulated emissions, i.e., emissions which are not currently regulated by EPA, have been measured from a 7.5 L (460 CID) PROCO engine powered vehicle operating at 50 kph on a chassis dynamometer. A dilution tube was used. Emphasis was on particulate emissions, which were characterized physically and chemically. A comparison is made to recent similar measurements on Diesel and conventional gasoline powered vehicles.
Technical Paper

A Modeling Analysis of Fibrous Media for Gasoline Particulate Filters

With an emerging need for gasoline particulate filters (GPFs) to lower particle emissions from gasoline direct injection (GDI) engines, studies are being conducted to optimize GPF designs in order to balance filtration efficiency, backpressure penalty, filter size, cost and other factors. Metal fiber filters could offer additional designs to the GPF portfolio, which is currently dominated by ceramic wall-flow filters. However, knowledge on their performance as GPFs is still limited. In this study, modeling on backpressure and filtration efficiency of fibrous media was carried out to determine the basic design criteria (filtration area, filter thickness and size) for different target efficiencies and backpressures at given gas flow conditions. Filter media with different fiber sizes (8 - 17 μm) and porosities (80% - 95%) were evaluated using modeling to determine the influence of fiber size and porosity.
Technical Paper

Optical Methodology for Characterization of a Gasoline Direct Injection Closing Event Droplet Distribution

The characteristics of gasoline sprayed directly into combustion chambers are of critical importance to engine out emissions and combustion system development. The optimization of the spray characteristics to match the in-cylinder flow field, chamber geometry, and spark location are vital tasks during the development of an engine combustion strategy. Furthermore, the presence of liquid fuel during combustion in Spark-Ignition (SI) engines causes increased hydro-carbon (HC) emissions [1]. Euro 6, LEVIII, and US Tier 3 emissions regulations reduce the allowable particulate mass significantly from the previous standards. LEVIII standards reduce the acceptable particulate emission to 1 mg/mile [2]. A good DISI strategy vaporizes the correct amount of fuel just in time for optimal power output with minimal emissions. The opening and closing phases of DISI injectors is crucial to this task as the spray produces larger droplets during both theses phases.
Technical Paper

The Effects of a Porous Ceramic Particulate Trap on the Physical, Chemical and Biological Character of Diesel Particulate Emissions

Physical, chemical, and biological characterization data for the particulate emissions from a Caterpillar 3208 diesel engine with and without Corning porous ceramic particulate traps are presented. Measurements made at EPA modes 3,4,5,9,lO and 11 include total hydrocarbon, oxides of nitrogen and total particulate matter emissions including the solid fraction (SOL), soluble organic fraction (SOF) and sulfate fraction (SO4), Chemical character was defined by fractionation of the SOF while biological character was defined by analysis of Ames Salmonella/ microsome bioassay data. The trap produced a wide range of total particulate reduction efficiencies (0-97%) depending on the character of the particulate. The chemical character of the SOF was significantly changed through the trap as was the biological character. The mutagenic specific activity of the SOF was generally increased through the trap but this was offset by a decrease in SOF mass emissions.
Technical Paper

A Model and the Methodology for Determining Wear Particle Generation Rate and Filter Efficiency in a Diesel Engine Using Ferrography

Monitoring of the wear rate of a diesel engine will yield valuable information regarding the wear mechanism within a diesel engine and ultimately will improve the predictions of failing engines and/or their components to allow preventive maintenance which will prolong the life of the engine. A mathematical model was developed that describes the wear particle concentration as a function of time in a diesel engine. This model contains engine and lubrication system parameters that determine the concentration of wear particles in the engine sump. These variables are the oil system volume, oil flow rate, particle generation rate, filtering efficiency and the initial particle concentration. The model has been employed to study the wear particle concentrations in the sump and the mass of particles in the filter for the Cummins VT-903 diesel engine.
Technical Paper

The Particle Emission Characteristics of a Light Duty Diesel Engine by Using Different Pilot Injections

Pilot injection has been used widely in diesel engines for its NOx and noise reducing characteristics. In this paper, its impacts to the particle emissions were studied using a light-duty common-rail Euro 4 diesel engine with different pilot injection strategies. Three steady-state engine modes were selected from the EU legislative diesel engine test cycle to represent low, medium and high engine speeds and loads. The quantities and injection timings of the pilot injection strategies were then varied. The particle number concentration and size distributions were investigated along with the smoke and regulated gas emissions such as the NOx trade-off. These results indicate how a pilot injection alongside a main injection can increase the particle size compared to a single main injection event. Furthermore, the split injection was closely related to the engine mode.
Technical Paper

Study of Particle Number Emissions from a Turbocharged Gasoline Direct Injection (GDI) Engine Including Data from a Fast-Response Particle Size Spectrometer

A study has been conducted to measure the particle number emissions from a current-generation 1.6-liter, Euro IV-compliant turbo-charged Gasoline Direct Injection (GDI) passenger car engine. A fast-response particle size spectrometer was used along with a PMP-compliant particulate measurement system to measure the effect of various engine parameters on the particulate emissions during the New European Drive Cycle (NEDC). Overall particle number is shown along with further analysis of the transient particle emissions. The cold start clearly affects particle formation with approximately 50% of the cumulative particle number being emitted within 200 seconds of the start. Even beyond 200 seconds, the particle number emissions fall as the test progresses and are generally consistent with increases in engine coolant temperature indicating that cold engine fuel preparation issues are contributing to the particle number count.
Technical Paper

Experimental Study Comparing Particle Size and Mass Concentration Data for a Cracked and Un-Cracked Diesel Particulate Filter

Steady state loading characterization experiments were conducted at three different engine load conditions and rated speed on the cracked catalyzed particulate filter (CPF). The experiments were performed using a 10.8 L 2002 Cummins ISM-330 heavy duty diesel engine. The CPF underwent a ring off failure, commonly seen in particulate filters, due to high radial and axial temperature gradients. The filters were cracked during baking in an oven which was done to regenerate PM collected after every loading characterization experiment. Two different configurations i.e. with and without a diesel oxidation catalyst (DOC) upstream of the CPF were studied. The data were compared with that on an un-cracked CPF at similar engine conditions and configurations. Pressure drop, transient filtration efficiency by particle size and PM mass and gaseous emissions measurements were made during each experiment.