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The measurement of the various pollutant species (HC, CO, NO, etc.) has become one of the main issues in internal combustion engine research. This interest concerns not only their quantitative measurement but also the study of the mechanism of their formation. In fact, pollutant species concentration can be used as an indicator for the combustion characteristics. For instance, it enables the determination of a lean or a rich combustion, the percentage of EGR, etc. The purpose of this research is to investigate the behavior of pollutant gas particles in the first part of an engine exhaust system through a detailed study of the unsteady flow in the exhaust pipe. The results are intended to designate the appropriate sensor positions which ensure accurate measurement results. This investigation wants to track an inert component in the exhaust system, namely the NO gas.