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Video

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications [1,2,3,4]. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH3 storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH3 storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH3 slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.
Video

SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Video

Brief Investigation of SCR High Temperature N2O Production

2012-06-18
Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.
Video

Evaluation of a NOx Transient Response Method for OBD of SCR Catalysts

2012-01-30
OBD requirements for aftertreatment system components require monitoring of the individual system components. One such component can be an NH3-SCR catalyst for NOx reduction. An OBD method that has been suggested is to generate positive or negative spikes in the inlet NH3 concentration, and monitor the outlet NOx transient response. A slow response indicates that the catalyst is maintaining its NH3 storage capacity, and therefore it is probably not degraded. A fast response indicates the catalyst has lost NH3 storage capacity, and may be degraded. The purpose of the work performed at Southwest Research Institute was to assess this approach for feasibility, effectiveness and practicality. The presentation will describe the work performed, results obtained, and implications for applying this method in test laboratory and real-world situations. Presenter Gordon J. Bartley, Southwest Research Institute
Video

Overview of Southwest Research Institute Activities in Engine Technology R&D

2012-05-10
The worldwide drive to improved energy efficiency for engine systems is being supported by several engine R&D programs at Southwest Research Institute (SwRI). This research includes large programs in major-market engine categories, such as heavy-duty, non-road, and light-duty; and includes diesel, gasoline, and alternative fuel aspects. This presentation describes several key diesel engine programs being pursued under the SwRI Clean High Efficiency Diesel Engine consortium (CHEDE-VI), whose goal is to demonstrate future diesel technology exceeding 50% brake thermal efficiency. Additionally, SwRI?s High Efficiency Dilute Gasoline Engines consortium (HEDGE-II), is reviewed, where advanced technology for ultra-high efficiency gasoline engines is being demonstrated. The HEDGE-II program is built upon dilute gasoline engine research, where brake thermal efficiencies in excess of 42% are being obtained for engines applicable to the light-duty market. Presenter Charles E.
Video

Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO2 oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.
Technical Paper

The Effects of Different Input Excitation on the Dynamic Characterization of an Automotive Shock Absorber

2001-04-30
2001-01-1442
This paper deals with the dynamic characterization of an automotive shock absorber, a continuation of an earlier work [1]. The objective of this on-going research is to develop a testing and analysis methodology for obtaining dynamic properties of automotive shock absorbers for use in CAE-NVH low-to-mid frequency chassis models. First, the effects of temperature and nominal length on the stiffness and damping of the shock absorber are studied and their importance in the development of a standard test method discussed. The effects of different types of input excitation on the dynamic properties of the shock absorber are then examined. Stepped sine sweep excitation is currently used in industry to obtain shock absorber parameters along with their frequency and amplitude dependence. Sine-on-sine testing, which involves excitation using two different sine waves has been done in this study to understand the effects of the presence of multiple sine waves on the estimated dynamic properties.
Technical Paper

The Effects of Natural Aging on Fleet and Durability Vehicle Engine Mounts from a Dynamic Characterization Perspective

2001-04-30
2001-01-1449
Elastomers are traditionally designed for use in applications that require specific mechanical properties. Unfortunately, these properties change with respect to many different variables including heat, light, fatigue, oxygen, ozone, and the catalytic effects of trace elements. When elastomeric mounts are designed for NVH use in vehicles, they are designed to isolate specific unwanted frequencies. As the elastomers age however, the desired elastomeric properties may have changed with time. This study looks at the variability seen in new vehicle engine mounts and how the dynamic properties change with respect to miles accumulated on fleet and durability test vehicles.
Technical Paper

Material Damping Properties: A Comparison of Laboratory Test Methods and the Relationship to In-Vehicle Performance

2001-04-30
2001-01-1466
This paper presents the damping effectiveness of free-layer damping materials through standard Oberst bar testing, solid plate excitation (RTC3) testing, and prediction through numerical schemes. The main objective is to compare damping results from various industry test methods to performance in an automotive body structure. Existing literature on laboratory and vehicle testing of free-layer viscoelastic damping materials has received significant attention in recent history. This has created considerable confusion regarding the appropriateness of different test methods to measure material properties for damping materials/treatments used in vehicles. The ability to use the material properties calculated in these tests in vehicle CAE models has not been extensively examined. Existing literature regarding theory and testing for different industry standard damping measurement techniques is discussed.
Technical Paper

Impact of Lubricant Oil on Regulated Emissions of a Light-Duty Mercedes-Benz OM611 CIDI-Engine

2001-05-07
2001-01-1901
The Partnership for a New Generation Vehicle (PNGV) has identified the compression-ignition, direct-injection (CIDI) engine as a promising technology in meeting the PNGV goal of 80 miles per gallon for a prototype mid-size sedan by 2004. Challenges remain in reducing the emission levels of the CIDI-engine to meet future emission standards. The objective of this project was to perform an initial screening of crank case lubricant contribution to regulated engine-out emissions, particularly when low particulate forming diesel fuel formulations are used. The test engine was the Mercedes-Benz OM611, the test oils were a mineral SAE 5W30, a synthetic (PAO based) SAE 5W30, and a synthetic (PAO based) SAE 15W50, and the test fuels were a California-like certification fuel and an alternative oxygenated diesel fuel.
Technical Paper

Real-Time Transient and Steady-State Measurement of Oil Consumption for Several Production SI-Engines

2001-05-07
2001-01-1902
Real-time transient and steady-state oil consumption were measured on three SI-engines, applying two different ring-packs to each engine. Testing of multiple engines enables an assessment of the engine-to-engine variability in oil consumption. Testing of multiple ring-packs on each engine enables an assessment of the ring-pack-to-ring-pack variability in oil consumption. The oil consumption was measured by the Southwest Research Institute (SwRI) novel developed SO2-tracer technique, referred to as RTOC-III. An interesting finding is that the testing shows low engine-to-engine and ring-pack-to-ring-pack variability, in both steady-state, as well as in transient oil consumption. This suggests that the RTOC-III system did not introduce significant variability to the data. The testing results are experimental verification of a design and simulation exercise, in a field of scarcely published literature.
Technical Paper

Visualization techniques to identify and quantify sources and paths of exterior noise radiated from stationary and nonstationary vehicles

2000-06-12
2000-05-0326
In recent years, Nearfield Acoustical Holography (NAH) has been used to identify stationary vehicle exterior noise sources. However that application has usually been limited to individual components. Since powertrain noise sources are hidden within the engine compartment, it is difficult to use NAH to identify those sources and the associated partial field that combine to create the complete exterior noise field of a motor vehicle. Integrated Nearfield Acoustical Holography (INAH) has been developed to address these concerns: it is described here. The procedure entails sensing the sources inside the engine compartment by using an array of reference microphones, and then calculating the associated partial radiation fields by using NAH. In the second part of this paper, the use of farfield arrays is considered. Several array techniques have previously been applied to identify noise sources on moving vehicles.
Technical Paper

Performance and Durability Evaluation of Continuously Regenerating Particulate Filters on Diesel Powered Urban Buses at NY City Transit

2001-03-05
2001-01-0511
Particulate emission from diesel engines is one of the most important pollutants in urban areas. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled “Clean Diesel Demonstration Program” has been initiated by NY City Transit under the supervision of NY State DEC and with active participation from several industrial partners. Under this program, several NY City transit buses with DDC Series 50 engines have been equipped with continuously regenerating diesel particulate filter system and are operating with ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000. These buses are being evaluated over a 8-9 month period for operations, maintainability and durability of the particulate filter.
Technical Paper

Fuel Evaporation Parameter Identification during SI Cold Start

2001-03-05
2001-01-0552
The stochastic properties of continuous time model parameters obtained through discrete least squares estimation are examined. Particular attention is given to the application of estimating the fuel evaporation dynamics of a V-8 SI engine. The continuous time parameter distributions in this case are biased. The bias is shown to be a function of both measurement noise and sampling rate selection. Analysis and experimental results suggest that for each particular model, there is a corresponding optimum sampling rate. A bias compensation formula is proposed that improves the accuracy of least squares estimation without iterative techniques.
Technical Paper

Heavy-Duty Diesel Truck In-Use Emission Test Program for Model Years 1950 through 1975

2001-03-05
2001-01-1327
Criteria pollutants were measured from ten Class 7 and 8 (i.e., gross vehicle weights > 33,000 lb) heavy-duty diesel trucks with engine model years between 1953 and 1975. The data was used by EPA to estimate that period's particulate matter emission rates for these type engines and will be used to develop dose response relationships with existing epidemiological data. Particulate samples were analyzed for sulfate and volatile organic fraction. Carbon soot was estimated. The trucks had particulate emissions of 2 to 10 g/mi as compared to 1 to 6 g/mi for trucks with model year engines from 1975 through the mid-1980s, and less than 1 g/mi for post-1988 trucks.
Technical Paper

Control Strategies for a Series-Parallel Hybrid Electric Vehicle

2001-03-05
2001-01-1354
Living in the era of rising environmental sensibility and increasing gasoline prices, the development of a new environmentally friendly generation of vehicles becomes a necessity. Hybrid electric vehicles are one means of increasing propulsion system efficiency and decreasing pollutant emissions. In this paper, the series-parallel power-split configuration for Michigan Technological University's FutureTruck is analyzed. Mathematical equations that describe the hybrid power-split transmission are derived. The vehicle's differential equations of motion are developed and the system's need for a controller is shown. The engine's brake power and brake specific fuel consumption, as a function of its speed and throttle position, are experimentally determined. A control strategy is proposed to achieve fuel efficient engine operation. The developed control strategy has been implemented in a vehicle simulation and in the test vehicle.
Technical Paper

Diesel Emission Control in Review

2001-03-05
2001-01-0184
This paper gives a comprehensive overview of the current state-of-the-art in diesel emission control. The nature of diesel particulates is summarized. The variety of diesel particulate filter regeneration strategies that will become so important to filter application are reviewed. Filter retrofit and durability issues are addressed. DeNOx catalysts, SCR, NOx traps for diesel, and non-thermal plasma methods are summarized. Integrated NOx/PM systems are described. And reduction of exhaust toxics is discussed. The paper covers all major conferences in the year 2000 that occurred in the US and Europe. US and Europe.
Technical Paper

Vektron® 6913 Gasoline Additive NOX Evaluation Fleet Test Program

2001-05-07
2001-01-1997
A 28-vehicle fleet test was executed to verify and quantify the NOX emissions reductions achieved through the use of Infineum's Vektron 6913 gasoline additive. The fleet composition and experimental design were finalized in collaborative discussions with US Environmental Protection Agency (EPA) Office of Transportation & Air Quality (OTAQ) and consultation / advice from several major US automotive manufacturers. The test was conducted over a period of five months at Southwest Research Institute. Statistical analysis of the emissions data indicated a 10% average fleet reduction in NOX emissions without any negative impact on other criteria pollutants (CO, HC) or fuel economy.
Technical Paper

Emissions Reduction Performance of a Bimetallic Platinum/Cerium Fuel Borne Catalyst with Several Diesel Particulate Filters on Different Sulfur Fuels

2001-03-05
2001-01-0904
Results of engine bench tests on a 1998 heavy-duty diesel engine have confirmed the emissions reduction performance of a U.S. Environmental Protection Agency (EPA) registered platinum/cerium bimetallic fuel borne catalyst (FBC) used with several different catalyzed and uncatalyzed diesel particulate filters (DPF's). Performance was evaluated on both a 450ppm sulfur fuel (No.2 D) and a CARB 50ppm low sulfur diesel (LSD) fuel. Particulate emissions of less than 0.02g/bhp-hr were achieved on several combinations of FBC and uncatalyzed filters on 450ppm sulfur fuel while levels of 0.01g/bhp-hr were achieved for both catalyzed and uncatalyzed filters using the FBC with the low sulfur CARB fuel. Eight-mode steady state testing of one filter and FBC combination with engine timing changes produced a 20% nitrogen oxide (NOx) reduction with particulates (PM) maintained at 0.01g/bhp-hr and no increase in measured fuel consumption.
Technical Paper

Validation of a Model and Development of a Simulator for Predicting the Pressure Drop of Diesel Particulate Filters

2001-03-05
2001-01-0911
As demand for wall-flow Diesel Particulate Filters (DPF) increases, accurate predictions of DPF behavior, and in particular their pressure drop, under a wide range of operating conditions bears significant engineering applications. In this work, validation of a model and development of a simulator for predicting the pressure drop of clean and particulate-loaded DPFs are presented. The model, based on a previously developed theory, has been validated extensively in this work. The validation range includes utilizing a large matrix of wall-flow filters varying in their size, cell density and wall thickness, each positioned downstream of light or heavy duty Diesel engines; it also covers a wide range of engine operating conditions such as engine load, flow rate, flow temperature and filter soot loading conditions. The validated model was then incorporated into a DPF pressure drop simulator.
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