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This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.

The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon

Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

The use of a diesel oxidation catalyst (DOC) in conjunction with a diesel particulate filter (DPF) is now a well-established aftertreatment system design for on-road heavy duty diesel. For non-road applications, the DOC must respond to the need for performance under more diverse and less favorable conditions, such as operation at low loads in cold weather. To choose a DOC technology for such applications, one must have practical and meaningful tests that address the specific catalytic functions of interest such as hydrocarbon oxidation to produce heat for regenerating DPF. This paper describes the development of an engine test protocol that focuses on resistance to the phenomenon known as quenching, the cessation of hydrocarbon (HC) oxidation that occurs when the exhaust temperature decreases below the light-off temperature of the catalyst. During development, the sensitivity and repeatability of the test were carefully scrutinized.

HiSiMo cast irons are frequently used as material for high temperature components in engines as e.g. exhaust manifolds and turbo chargers. These components must withstand severe cyclic mechanical and thermal loads throughout their life cycle. The combination of thermal transients with mechanical load cycles results in a complex evolution of damage, leading to thermomechanical fatigue (TMF) of the material and, after a certain number of loading cycles, to failure of the component. In Part I of the paper, a fracture mechanics model for TMF life prediction was developed based on results of uniaxial tests. In this paper (Part II), the model is formulated for three-dimensional stress states, so that it can be applied in a post-processing step of a finite-element analysis. To obtain reliable stresses and (time dependent plastic) strains in the finite-element calculation, a time and temperature dependent plasticity model is applied which takes non-linear kinematic hardening into account.

HiSiMo cast irons are frequently used as material for high temperature components in engines as e.g. exhaust manifolds and turbo chargers. These components must withstand severe cyclic mechanical and thermal loads throughout their service life. The combination of thermal transients with mechanical load cycles results in a complex evolution of damage, leading to thermomechanical fatigue (TMF) of the material and, after a certain number of loading cycles, to failure of the component. In this paper (Part I), the low-cycle fatigue (LCF) and TMF properties of HiSiMo are investigated in uniaxial tests and the damage mechanisms are addressed. On the basis of the experimental results a fatigue life model is developed which is based on elastic, plastic and creep fracture mechanics results of short cracks, so that time and temperature dependent effects on damage are taken into account.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

The California Air Resources Board (CARB)-funded Stage 3 Heavy-Duty Low NOX program focusses on evaluating different engine and after-treatment technologies to achieve 0.02g/bhp-hr of NOX emission over certification cycles. This paper highlights the controls architecture of the engine and after-treatment systems and discusses the effects of various strategies implemented and tested in an engine test cell over various heavy-duty drive cycles. A Cylinder De-Activation (CDA) system enabled engine was integrated with an advanced after-treatment controller and system package. Southwest Research Institute (SwRI) had implemented a model-based controller for the Selective Catalytic Reduction (SCR) system in the CARB Stage 1 Low-NOX program. The chemical kinetics for the model-based controller were further tuned and implemented in order to accurately represent the reactions for the catalysts used in this program.

An aqueous urea solution is used as the source of ammonia for selective catalytic reduction (SCR) of NOx to reduce the emissions of NOx in the exhaust of diesel vehicles. However, the decomposition of urea into ammonia is not always complete, resulting in solid urea deposit formation in the decomposition tube or on the SCR catalyst. These solid deposits can impede the flow of the exhaust gases (and uniformity of NH3 supply) and reduce SCR catalyst performance over time. To minimize the formation of urea deposit and to meet EPA NOx emission regulations, it is important to understand the chemistry of formation or removal of the deposit in the decomposition tube and SCR catalyst. In this report, IR spectroscopy, UV-visible spectroscopy, thermogravimetric analysis and elemental analysis have been used to determine the chemical composition of the solid urea deposits formed by the thermal decomposition of urea.

Human exposure to vehicle exhaust during engine start-up can be encountered on a daily basis in parking lots, home garages, and vehicle stop/star traffic environment. This work is the first pilot study to characterize solid particle number and size distribution during engine start-up using various light-duty vehicles with different technology engines. A total of 84 vehicles were tested in this pilot study, consisting of post-2007 diesel engines equipped with high efficiency diesel particulate filters (DPFs) as well as modern gasoline port fuel injected (PFI) and gasoline direct injected (GDI) engines equipped with three-way-catalysts (TWCs). Particle concentration from DPF equipped diesel engines were found to be the lowest, while GDI and 8-cylinder PFI engines had the highest particle emissions.

Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.

California Air Resources Board (CARB) has instituted requirements for on-board diagnostics (OBD) that makes a spark-plug sized exhaust particulate matter (PM) sensor a critical component of the OBD system to detect diesel particulate filter (DPF) failure. Currently, non-real-time resistive-type sensors are used by engine OEMs onboard vehicles. Future OBD regulations are likely to lower PM OBD thresholds requiring higher sensitivity sensors with better data yield for OBD decision making. The focus of this work was on the experimental evaluation of a real-time PM sensor manufactured by EmiSense Technologies, LLC that may offer such benefits. A 2011 model year on-highway heavy-duty diesel engine fitted with a diesel oxidation catalyst (DOC) and a catalyzed DPF followed by urea-based selective catalytic reducer (SCR) and ammonia oxidation (AMOX) catalysts was used for this program.

Gasoline Direct Injection (GDI) engines have been widely adopted by manufacturers in the light-duty market due to their fuel economy benefits. However, several studies have shown that GDI engines generate higher levels of particulate matter (PM) emissions relative to port fuel injected (PFI) engines and diesel engines equipped with optimally functioning diesel particulate filters (DPF). With stringent particle number (PN) regulations being implemented in both, the European Union and China, gasoline particulate filters (GPF) are expected to be widely utilized to control particulate emissions. Currently, evaluating GPF technologies on a vehicle can be challenging due to a limited number of commercially available vehicles that are calibrated for a GPF in the United States as well as the costs associated with vehicle procurement and evaluations utilizing a chassis dynamometer facility.

Selective Catalytic Reduction (SCR) systems provide excellent NOX control for diesel engines provided the exhaust aftertreatment inlet temperature remains at 200° C or higher. Since diesel engines run lean, extended light load operation typically causes exhaust temperatures to fall below 200° C and SCR conversion efficiency diminishes. Heated urea dosing systems are being developed to allow dosing below 190° C. However, catalyst face plugging remains a concern. Close coupled SCR systems and lower temperature formulation of SCR systems are also being developed, which add additional expense. Current strategies of post fuel injection and retarded injection timing increases fuel consumption. One viable keep-warm strategy examined in this paper is cylinder deactivation (CDA) which can increase exhaust temperature and reduce fuel consumption.

In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.

Four high-efficiency alternative combustion modes were modeled to determine the potential brake thermal efficiency (BTE) relative to a traditional lean burn compression ignition diesel engine with selective catalytic reduction (SCR) aftertreatment. The four combustion modes include stoichiometric pilot-ignited gasoline with EGR dilution (SwRI HEDGE technology), dual fuel premixed compression ignition (University of Wisconsin), gasoline partially premixed combustion (Lund University), and homogenous charge compression ignition (HCCI) (SwRI Clean Diesel IV). For each of the alternative combustion modes, zero-D simulation of the peak torque condition was used to show the expected BTE. For all alternative combustion modes, simulation showed that the BTE was very dependent on dilution levels, whether air or EGR. While the gross indicated thermal efficiency (ITE) could be shown to improve as the dilution was increased, the required pumping work decreased the BTE at EGR rates above 40%.

Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.

The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III emissions standard which will require significant reductions of hydrocarbon (HC) and oxides of nitrogen (NOx) from current levels. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines so the time required to achieve effective emissions control with current aftertreatment devices is considerably longer. The objective of this study was to determine the potential of a novel diesel cold-start emissions control strategy for achieving LEV III emissions. The strategy combines several technologies to reduce HC and NOx emissions before the start of the second hill of the FTP75.

Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.