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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Technical Paper

An Analytical Energy-budget Model for Diesel Droplet Impingement on an Inclined Solid Wall

2020-04-14
2020-01-1158
The study of spray-wall interaction is of great importance to understand the dynamics that occur during fuel impingement onto the chamber wall or piston surfaces in internal combustion engines. It is found that the maximum spreading length of an impinged droplet can provide a quantitative estimation of heat transfer and energy transformation for spray-wall interaction. Furthermore, it influences the air-fuel mixing and hydrocarbon and particle emissions at combusting conditions. In this paper, an analytical model of a single diesel droplet impinging on the wall with different inclined angles (α) is developed in terms of βm (dimensionless maximum spreading length, the ratio of maximum spreading length to initial droplet diameter) to understand the detailed impinging dynamic process.
Technical Paper

Comparison of Partial and Total Dilution Systems for the Measurement of Polycyclic Aromatic Hydrocarbons and Hydrocarbon Speciation in Diesel Exhaust

2020-09-15
2020-01-2190
Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.
Journal Article

Extension of Analytical Methods for Detailed Characterization of Advanced Combustion Engine Emissions

2016-10-17
2016-01-2330
Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.
Journal Article

Impact of EGR Quality on the Total Inert Dilution Ratio

2016-04-05
2016-01-0713
A series of tests were performed on a gasoline powered engine with a Dedicated EGR® (D-EGR®) system. The results showed that changes in engine performance, including improvements in burn rates and stability and changes in emissions levels could not be adequately accounted for solely due to the presence of reformate in the EGR stream. In an effort to adequately characterize the engine's behavior, a new parameter was developed, the Total Inert Dilution Ratio (TIDR), which accounts for the changes in the EGR quality as inert gases are replaced by reactive species such as CO and H2.
Technical Paper

Optimization of Diesel Engine and After-treatment Systems for a Series Hybrid Forklift Application

2020-04-14
2020-01-0658
This paper investigates an optimal design of a diesel engine and after-treatment systems for a series hybrid electric forklift application. A holistic modeling approach is developed in GT-Suite® to establish a model-based hardware definition for a diesel engine and an after-treatment system to accurately predict engine performance and emissions. The used engine model is validated with the experimental data. The engine design parameters including compression ratio, boost level, air-fuel ratio (AFR), injection timing, and injection pressure are optimized at a single operating point for the series hybrid electric vehicle, together with the performance of the after-treatment components. The engine and after-treatment models are then coupled with a series hybrid electric powertrain to evaluate the performance of the forklift in the standard VDI 2198 drive cycle.
Journal Article

Development of a Synthetic Diesel Exhaust

2008-04-14
2008-01-0067
A two-phase study was performed to establish a standard diesel exhaust composition which could be used in the future development of light-duty diesel exhaust aftertreatment. In the first phase, a literature review created a database of diesel engine-out emissions. The database consisted chiefly of data from heavy-duty diesel engines; therefore, the need for an emission testing program for light- and medium-duty engines was identified. A second phase was conducted to provide additional light-duty vehicle emissions data from current technology vehicles. Engine-out diesel exhaust from four 2004 model light-duty vehicles with a variety of engine displacements was collected and analyzed. Each vehicle was evaluated using five steady-state engine operating conditions and two transient test cycles (the Federal Test Procedure and the US06). Regulated emissions were measured along with speciation of both volatile and semi-volatile components of the hydrocarbons.
Journal Article

Development of a Solid Exhaust Particle Number Measurement System Using a Catalytic Stripper Technology

2011-04-12
2011-01-0635
A solid particle number measurement system (SPNMS) was developed using a catalytic stripper (CS) technology instead of an evaporation tube (ET). The ET is used in commercially available systems, compliant with the Particle Measurement Program (PMP) protocol developed for European Union (EU) solid particle number regulations. The catalytic stripper consists of a small core of a diesel exhaust oxidation catalyst. The SPNMS/CS met all performance requirements under the PMP protocol. It showed a much better performance in removing large volatile tetracontane particles down to a size well below the PMP lower cut-size of 23 nm, compared to a SPNMS equipped with an ET instead of a CS. The SPNMS/CS also showed a similar performance to a commercially available system when used on a gasoline direct injection (GDI) engine exhaust.
Journal Article

The Effects of Piston Crevices and Injection Strategy on Low-Speed Pre-Ignition in Boosted SI Engines

2012-04-16
2012-01-1148
The spark ignition (SI) engine has been known to exhibit several different abnormal combustion phenomena, such as knock or pre-ignition, which have been addressed with improved engine design or control schemes. However, in highly boosted SI engines, Low-Speed Pre-Ignition (LSPI), a pre-ignition event typically followed by heavy knock, has developed into a topic of major interest due to its potential for engine damage. Previous experiments associated increases in hydrocarbon emissions with the blowdown event of an LSPI cycle [1]. Also, the same experiments showed that there was a dependency of the LSPI activity on fuel and/or lubricant compositions [1]. Based on these findings it was hypothesized that accumulated hydrocarbons play a role in LSPI and are consumed during LSPI events. A potential source for accumulated HC is the top land piston crevice.
Technical Paper

The Effect of a Ceramic Particulate Trap on the Particulate and Vapor Phase Emissions of a Heavy-Duty Diesel Engine

1991-02-01
910609
Exhaust emissions were characterized from a Cummins LTA10 heavy-duty diesel engine operated at two EPA steady-state modes with and without an uncatalyzed Corning ceramic particulate trap. The regulated emissions of nitrogen oxides (NOx), hydrocarbons (HC), and total particulate matter (TPM) and its components as well as the unregulated emissions of PAH, nitro-PAH, mutagenic activity and particle size distributions were measured. The consistently significant effects of the trap on regulated emissions included reductions of TPM and TPM-associated components. There were no changes in NOx and HC were reduced only at one operating condition. Particle size distribution measurements showed that nuclei-mode particles were formed downstream of the trap, which effectively removed accumulation-mode particles. All of the mutagenicity was direct-acting and the mutagenic activity of the XOC was approximately equivalent to that of the SOF without the trap.
Technical Paper

Aging of Zeolite Based Automotive Hydrocarbon Traps

2007-04-16
2007-01-1058
This paper analyzes the aging of zeolite based hydrocarbon traps to guide development of diagnostic algorithms. Previous research has shown the water adsorption ability of zeolite ages along with the hydrocarbon adsorption ability, and this leads to a possible diagnostic algorithm: the water concentration in the exhaust can be measured and related to aging. In the present research, engine experiments demonstrate that temperature measurements are also related to aging. To examine the relationship between temperature-based and moisture-based diagnostic algorithms, a transient, nonlinear heat and mass transfer model of the exhaust during cold-start is developed. Despite some idealizations, the model replicates the qualitative behavior of the exhaust system. A series of parametric studies reveals the sensitivity of the system response to aging and various noise factors.
Technical Paper

Performance Test Results of a New On Board Emission Measurement System Conformed with CFR Part 1065

2007-04-16
2007-01-1326
A new on-board portable emission measurement system (PEMS) for gaseous emissions has been designed and developed to meet CFR Part 1065 requirements. The new system consists of a heated flame ionization detector (HFID) for the measurement of total hydrocarbon, a heated chemiluminescence detector (HCLD) for the measurement of NOx, and a heated non-dispersive infra-red detector (HNDIR) for the measurement of CO and CO2. The oxygen interference and relative sensitivity of several hydrocarbon components have been optimized for the HFID. The CO2 and H2O quenching effect on the HCLD have been compensated using measured CO2 and H2O concentration. The spectral overlap and molecular interaction of H2O on the HNDIR measurement has also been compensated using an independent H2O concentration measurement. The basic performance of the new on-board emission measurement system has been verified accordingly with CFR part 1065 and all of the performances have met with CFR part 1065 requirement.
Technical Paper

The Potential for Achieving Low Hydrocarbon and NOx Exhaust Emissions from Large Light-Duty Gasoline Vehicles

2007-04-16
2007-01-1261
Two large, heavy light-duty gasoline vehicles (2004 model year Ford F-150 with a 5.4 liter V8 and GMC Yukon Denali with a 6.0 liter V8) were baselined for emission performance over the FTP driving cycle in their stock configurations. Advanced emission systems were designed for both vehicles employing advanced three-way catalysts, high cell density ceramic substrates, and advanced exhaust system components. These advanced emission systems were integrated on the test vehicles and characterized for low mileage emission performance on the FTP cycle using the vehicle's stock engine calibration and, in the case of the Denali, after modifying the vehicle's stock engine calibration for improved cold-start and hot-start emission performance.
Technical Paper

Lower Explosion Limits and Compositions of Middle Distillate Fuel Vapors

1998-10-19
982485
Lower explosion limits (LEL) and the chemical compositions of JP-8, Jet A and JP-5 fuel vapors were determined in a sealed combustion vessel equipped with a spark igniter, a gas-sampling probe, and sensors to measure pressure rise and fuel temperature. Ignition was detected by pressure rise in the vessel. Pressure rises up to 60 psig were observed near the flash points of the test fuels. The fuel vapors in the vessel ignited from as much as 11°F below flash-point measurements. Detailed hydrocarbon speciation of the fuel vapors was performed using high-resolution gas chromatography. Over 300 hydrocarbons were detected in the vapors phase. The average molecular weight, hydrogen to carbon ratio, and LEL of the fuel vapors were determined from the concentration measurements. The jet fuel vapors had molecular weights ranging from 114 to 132, hydrogen to carbon ratios of approximately 1.93, and LELs comparable to pure hydrocarbons of similar molecular weight.
Technical Paper

Calibrating and Protecting Microphones to Allow Acoustic Measurements in Hazardous Environments

2009-05-19
2009-01-2163
Performing acoustic measurements on or near engines, transmissions, as well as in other circumstances where the environment is hazardous and harsh for microphones requires special precautions. Fluids inevitably leak, and the possibility of transducer damage can be very high without proper protection. Properly protecting microphones during testing allows for consistent data quality in these hazardous and difficult environments. While this paper will present the use of a 5 mil Nitrile cover which protects against many fluids within the scope of automotive testing, including water, hydrocarbons, and alcohols, as well as having good heat resistance and high strength, the concepts developed are applicable to other types of microphone protective mechanisms. Acoustic sensitivity was measured and used to calculate the change of the microphone's response after the treatment is applied, as well as after being exposed to various contaminants.
Technical Paper

Comparison of Four Sampling Methods for Semi-volatile Organic Compounds in Gas Phase Diesel Engine Exhausts

2008-10-06
2008-01-2435
Newly designed Teflon® O-rings along with XAD-2 resin, stainless steel screens, lock rings, and glass cartridges were used to construct a new semi-volatile organic compounds (SVOC's) sampling device. This new sampling device allows direct and repeated sampling, extraction, and cleaning without ever having to be disassembled or reassembled. This new XAD-2 glass cartridge (X2) was compared with three other sampling methods namely Empore® membrane (EM), hexane impinger (HI), and “Cold Trap” (CT) for SVOC sampling efficiency on diesel engine exhaust emissions. The X2 method showed the highest overall SVOC collection efficiency, followed by the EM and HI methods. The X2 method has higher trapping efficiency for the oxygenates, polycyclic aromatic hydrocarbons (PAH's), alkyl cyclohexanes, and the alkyl aromatics than the other three SVOC sampling methods. The HI method has the highest trapping efficiency for the normal alkanes.
Technical Paper

An Investigation of Sample Bag Hydrocarbon Emissions and Carbon Dioxide Permeation Properties

2004-03-08
2004-01-0593
The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.
Technical Paper

Comparison of Emission Characteristics of Conventional, Hydrotreated, and Fischer-Tropsch Diesel Fuels in a Heavy-Duty Diesel Engine

2001-09-24
2001-01-3519
This study compared diesel exhaust emission from four different diesel fuels: a conventional low sulfur D2 diesel (0.03% sulfur, 28% aromatics), California Air Resources Board (CARB) diesel (0.015% sulfur, 8% aromatics), “Swedish” diesel (<0.001% sulfur, 4% aromatics), and a Fischer-Tropsch (F-T) diesel (<0.0001% sulfur, <0.1% aromatics) fuel. The comparison included regulated emissions, hydrocarbon speciation, air toxics, aldehydes and ketones, particle size distribution, and greenhouse gas emissions. Testing was conducted using a Cummins B-Series engine installed both in a heavy light-duty truck operating on a chassis dynamometer and on an engine dynamometer. The chassis driving cycles included city, highway, and aggressive driving operation. Engine dynamometer tests included the U.S. transient cycle.
Technical Paper

Oxidation Catalytic Converter and Emulsified Fuel Effects on Heavy-Duty Diesel Engine Emissions

2002-03-04
2002-01-1277
A study was conducted to assess the effects of a water-diesel fuel emulsion with and without an oxidation catalytic converter (OCC) on steady-state heavy-duty diesel engine emissions. Two OCCs with different metal loading levels were used in this study. A 1988 Cummins L10-300 heavy-duty diesel engine was operated at the rated speed of 1900 rpm and at 75% and 25% load conditions (EPA modes 9 and 11 respectively) of the 13 mode steady-state test as well as at idle. Raw exhaust emissions' measurements included total hydrocarbons (HC), oxides of nitrogen (NOx) and nitric oxide (NO). Diluted exhaust measurements included total particulate matter (TPM) and its primary constituents, the soluble organic (SOF), sulfate (SO42-) and the carbonaceous solids (SOL) fractions. Vapor phase organic compounds (XOC) were also analyzed. The SOF and XOC samples were analyzed for selected polynuclear aromatic hydrocarbons (PAHs).
Technical Paper

Cold-Start Hydrocarbon Collection for Advanced Exhaust Emission Control

1992-02-01
920847
This paper describes the findings of a laboratory effort to demonstrate improved automotive exhaust emission control with a cold-start hydrocarbon collection system. The emission control strategy developed in this study incorporated a zeolite molecular sieve in the exhaust system to collect cold-start hydrocarbons for subsequent release to an active catalytic converter. A prototype emission control system was designed and tested on a gasoline-fueled vehicle. Continuous raw exhaust emission measurements upstream and downstream of the zeolite molecular sieve revealed collection, storage, and release of cold-start hydrocarbons. Federal Test Procedure (FTP) emission results show a 35 percent reduction in hydrocarbons emitted during the cold-transient segment (Bag 1) due to adsorption by the zeolite.
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