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The presentation describes technology developments and the integration of these technologies into new emission control systems. As in other years, the reader will find a wide range of topics from various parts of the world. This is reflective of the worldwide scope and effort to reduce diesel exhaust emissions. Topics include the integration of various diesel particulate matter (PM) and Nitrogen Oxide (NOx) technologies as well as sensors and other emissions related developments. Presenter Atsuo Kondo, NGK Insulators, Ltd.

The reduction of greenhouse gas is becoming increasingly important for humankind, and vehicles with low CO₂ emissions have a part to play in any reduction initiatives. Diesel engines emit 30% less CO₂ than gasoline engines, so diesel engines will make an important contribution to the overall decrease. Unfortunately diesel exhaust gas contains particulate matter (PM) which may cause health problems, and such PM emissions are regulated by law. In order to reduce PM, especially soot, diesel particulate filters (DPFs) are widely fitted to diesel vehicles. A DPF can remove more than 99% by weight of soot from exhaust gas under normal operating conditions, and they are one of the most important methods to achieve any regulation targets. But if the system malfunctions, the PM emissions may exceed the regulation limit. To detect such PM leakage, on-board diagnostics (OBD) are required.

Ceramic wall-flow type diesel particulate filters (DPF) are being investigated for the aftertreatment systems of heavy duty engines. To use ceramic DPF more reliably and easily, electric heating regenerations are studied varying combustion air flow rates and amounts of accumulated soot. Despite electric heater capacity limitations, it is possible to regenerate DPF at a certain combustion air flow rate without thermal shock failure. The maximum withstood temperature against thermal shock failure of electric heating regeneration is similar to that of diesel burner regeneration on DPF with a nine inch diameter and a twelve inch length.

Since the implementation of Euro 6 in September 2014, diesel engines are facing another drastic reduction of NOx emission limits from 180 to only 80 mg/km during NEDC and real driving emissions (RDE) are going to be monitored until limit values are enforced from September 2017. Considering also long term CO2 targets of 95 g/km beyond 2020, diesel engines must become cleaner and more efficient. However, there is a tradeoff between NOx and CO2 and, naturally, engine developers choose lower CO2 because NOx can be reduced by additional devices such as EGR or a catalytic converter. Lower CO2 engine calibration, unfortunately, leads to lower exhaust gas temperatures, which delays the activation of the catalytic converter. In order to overcome both problems, higher NOx engine out emission and lower exhaust gas temperatures, new aftertreatment systems will incorporate close-coupled DeNOx systems.

The in-line hydrocarbon (HC) adsorber is a passive after-treatment technology to address cold-start hydrocarbons in automotive engine exhaust gas. A major technical challenge of the in-line HC adsorber is the difference between the HC release temperature of the adsorber and the light-off temperature of the burn-off (BO) Catalyst. We call this phenomenon the “reversed-temperature difference”. To reduce the reversed temperature difference, NGK has proposed a new “In-line HC Adsorber System” which consists of light-off (LO) Catalyst + Barrel Zeolite Adsorber (BZA), with a hole through the center, BO Catalyst and secondary air injection management (SAE 970266). This, our latest paper, describes the evaluation of various adsorbents and the effect of the center hole on the Adsorber BZA. The adsorber system, which had the Adsorber BZA with a 25mm ϕ center hole and adsorbent coated, confirmed 30% lower FTP NMHC emission versus a system with no center hole or adsorbent coating.

Due to its better fuel efficiency and low CO2 emissions, the number of diesel engine vehicles is increasing worldwide. Since they have high Particulate Matter (PM) emissions, tighter emission regulations will be enforced in Europe, the US, and Japan over the coming years. The Diesel Particulate Filter (DPF) has made it possible to meet the tighter regulations and Silicon Carbide and Cordierite DPF's have been applied to various vehicles from passenger cars to heavy-duty trucks. However, it has been reported that nano-size PM has a harmful effect on human health. Therefore, it is desirable that PM regulations should be tightened. This paper will describe the influence of the DPF material characteristics on PM filtration efficiency and emissions levels, in addition to pressure drop.

This paper is Part-1 of two papers discussing the filtration behavior of diesel particulate filters. Results of the fundamental study are presented in Part-1, and test results for real size DPFs are reported in the supplement, Part-2. In this paper, a fundamental experimental study was performed on the effect of pore size and pore size distribution on the PM filtration efficiency of the ceramic, wall-flow Diesel Particulate Filter (DPF). Small round plates of various average mean pore sizes (4.6, 9.4, 11.7, 17.7 micro-meters) with a narrow pore size distribution were manufactured for the tests. During the DPF filtration efficiency tests, ZnCl2 particles in the range of 10 nm to 500 nm were used instead of PM from actual diesel engine exhaust. ZnCl2 particles were made using an infrared furnace and separated into monodisperse particles by DMA (Differential Mobility Analyzer).

A wall flow diesel particulate filter (DPF) having a novel wall pore structure design for reducing backpressure, increasing robustness, and increasing filtration efficiency is presented. The filter offers a linear relationship between soot loading and backpressure, offering greater accuracy in estimating the amount of soot loading from backpressure. Basic experiments were performed on small plate test pieces having various pore structure designs. Soot generated by a Cast-2F propane burner having a controlled size distribution was used. Cold flow test equipment that was carefully designed for flow distribution and soot/air mixing was used for precise measurement of backpressure during soot loading. The upstream and downstream PM numbers were counted by Scanning Mobility Particle Sizer (SMPS) to determine soot concentration in the gas flow and filtration efficiency of the test pieces. Microscope observations of the soot trapped in the wall were also carried out.

Although diesel engines are superior to gasoline engines in terms of the demand to reduce CO2 emissions, diesel engines suffer from the problem of emitting Particulate Matter (PM). Therefore, a Diesel Particulate Filter (DPF) has to be fitted in the engine exhaust aftertreatment system. From the viewpoint of reducing CO2 emissions, there is a strong demand to reduce the exhaust system pressure drop and for DPF designs that are able to help reduce the pressure drop. A wall flow DPF having a novel wall pore structure design for reducing pressure drop, increasing robustness and increasing filtration efficiency is presented. The filter offers a linear relationship between PM loading and pressure drop, offering lower pressure drop and greater accuracy in estimating the accumulated PM amount from pressure drop. First, basic experiments were performed on small plate test samples having various pore structure designs.

The Diesel Particulate Filter (DPF) system has been developed as one of key technologies to comply with tight diesel PM emission regulations. For the DPF control system, it is necessary to maintain temperature inside the DPF below the allowable service temperature, especially during soot regeneration to prevent catalyst deterioration and cracks. Therefore, the evaluation of soot regeneration is one of the key development items for the DPF system. On the other hand, regeneration evaluation requires a lot of time and cost since many different regeneration conditions should be investigated in order to simulate actual driving. The simulation tool to predict soot regeneration behavior is a powerful tool to accelerate the development of DPF design and safe regeneration control strategies. This paper describes the soot regeneration model applied to fuel additive and catalyzed types, and shows good correlation with measured data.

Among the durability items of the DPF (Diesel Particulate Filter), high accumulated soot mass limit is important for the low fuel consumption and also for the robustness. In case of catalyzed DPF, it depends on the following two properties during soot regeneration. One is the lower maximum-temperature inside of the DPF during usual regeneration in order to preserve the catalyst performance. The other is the higher thermal resistance against the unusual regeneration of excess amount of soot. This paper presents the improvement in the soot mass limit of Si bonded SiC DPF. Maximum-temperature inside of the DPF was lowered by the improvement of thermal conductivity of the material, resulted from the controlling of the microstructure. Additionally the thermal resistance was improved by the surface treatment of the Si and SiC.

Modern filter systems allow a significant reduction of diesel particulate emissions. The new silicon bonded silicon carbide particulate filters (Si-SiC filters) play an important role in this application, because they provide flexibility in terms of mean pore size and porosity and also have a high thermal shock capability to meet both engineering targets and emission limits for 2005 and beyond. Particulate filters are exposed to high temperatures and a harsh chemical environment in the exhaust gas of diesel vehicles. This paper will present further durability evaluation results of the new Si bonded SiC particulate filters which have been collected in engine bench tests and vehicle durability runs. The Si-SiC filters passed both 100 and 200 regeneration cycles under severe ageing conditions and without any problems. The used filters were subjected to a variety of analytical tests. The back pressure and ash distribution were determined. The filter material was also analysed.

To reduce flow restriction of the wall flow type diesel particulate filters, the pore size distribution of DPF material was improved. Large pore material is preferred to reduce the flow restriction of the DPF. However pore diameter should be controlled within a certain limit to maintain high trapping efficiency against diesel particulates. In order to solve these conflicting matters, the mean pore diameter was enlarged from 13μm of the current material to 20 μm or more, while maintaining the cumulative volume of pores above 100μm within 8% of the total pore volume. The safe limit against thermal shock failure of the improved DPF material having 9″D x 12″/, 12.5/ volume was also determined using diesel burner regeneration system.

In order to meet the challenging CO2 targets beyond 2020 despite keeping high performance engines, Gasoline Direct Injection (GDI) technology usually combined with charged aspiration is expanding in the automotive industry. While providing more efficient powertrains to reduce fuel consumption one side effect of GDI is the increased particle formation during the combustion process. For the first time for GDI from September 2014 there is a Particle Number (PN) limit in EU of 6x10 sup 12 #/km, which will be further reduced by one order of magnitude to 6x10 sup 11 #/km effective from September 2017 to be the same level as applied to Diesel engines. In addition to the PN limit of the certification cycle NEDC further certification of Real Driving Emissions (RDE) including portable PN measurements are under discussion by the European Commission. RDE test procedure requires stable and low emissions in a wide range of engine operations and durable over a distance of 160 000 km.

Particle Number (PN) regulation was firstly introduced for European light-duty diesel vehicles back in 2011[1]. Since then, PN regulation has been and is being expanded to heavy-duty diesel vehicles and non-road diesel machineries. PN regulation will also be expanded to China and India around 2020 or later. Diesel Particulate Filter (DPF) is significant factor for the above-mentioned PN regulation. This filter technology is to be continuously evolved for the near future tighter PN regulation. Generally, PN filtration performance test for filter technology development is carried out with chassis dynamometer, engine dynamometer or simulator [2]. This paper describes a simplified and relatively quicker alternative PN filtration performance test method for accelerating filter technology development compared to the current test method.

Reducing the fuel consumption of powertrains in internal combustion engines is still a major objective from an environmental viewpoint. Internal combustion engines waste a huge part of the fuel energy as heat in the exhaust line. Currently, exhaust heat recovery (EHR) systems are attracting attention as an effective means of reducing fuel consumption by collecting heat from waste exhaust gas and using it for rapid warming up of the engine and cabin heating [1, 2, 3, 4]. The benefits of the EHR system are affected by a trade-off between the efficacy of the recovered useful thermal energy and the adverse effect of the additional weight (heat mass) of the system [5]. Conventional EHR systems have a complex heat exchanger structure and a structure in which a bypass pipe and heat exchanger are connected in parallel, giving them a large size and heavy weight. We have developed a new-concept silicon carbide (SiC) heat exchanger with a dense SiC honeycomb.

Diesel particulate filters (DPF) are a common component in emission-control systems of modern clean diesel vehicles. Several DPF materials have been used in various applications. Silicone Carbide (SiC) is common for passenger vehicles because of its thermal robustness derived from its high specific gravity and heat conductivity. However, a segmented structure is required to relieve thermal stress due to SiC's higher coefficient of thermal expansion (CTE). Cordierite (Cd) is a popular material for heavy-duty vehicles. Cordierite which has less mass per given volume, exhibits superior light-off performance, and is also adequate for use in larger monolith structures, due to its lower CTE. SiC and cordierite are recognized as the most prevalent DPF materials since the 2000's. The DPF traps not only combustible particles (soot) but also incombustible ash. Ash accumulates in the DPF and remains in the filter until being physically removed.

Diesel engines are more fuel efficient due to their high thermal efficiency, compared to gasoline engines and therefore, have a higher potential to reduce CO2 emissions. Since diesel engines emit higher amounts of Particulate Matter (PM), DPF systems have been introduced. Today, DPF systems have become a standard technology. Nevertheless, with more stringent NOx emission limits and CO2 targets, additional NOx emission control is needed. For high NOx conversion efficiency, SCR catalysts technology shows high potential. Due to higher temperature at the close coupled position and space restrictions, an integrated SCR concept on the DPFs is preferred. A high SCR catalyst loading will be required to have high conversion efficiency over a wide range of engine operations which causes high pressure for conventional DPF materials.

With the push towards more stringent on-road US heavy duty diesel regulations (i.e. HD GHG Phase 2 and the proposed ARB 20 mg/bhp-hr NOx), emission system packaging has grown critical while improving fuel economy and NOx emissions. The ARB regulations are expected to be implemented post 2023 while regulation for EU off-road segment will begin from 2019. The regulation, called Stage V, will introduce particle number (PN) regulation requiring EU OEMs to introduce a diesel particulate filter (DPF) while customer demands will require the OEMs to maintain current emission system packaging. A viable market solution to meet these requirements, especially for EU Stage V being implemented first, is a DPF coated with a selective catalyst reduction (SCR) washcoat (i.e. SCRonDPF).

It is well known that an EHC (Electrically Heated Catalyst) is very effective in reducing cold start HC emissions. However, the large electric power consumption of the EHC is a major technical issue. When installed in the exhaust manifold, the EHC can take advantage of exhaust heat to warm up faster, resulting in a reduced electric power demand. Therefore, a structurally durable EHC which can withstand the severe manifold conditions is desirable. Through the use of a extruded monolithic metal substrate, with a flexible hexagonal cell structure and a special canning method, we have succeeded in developing a structurally durable EHC. This new EHC installed in the exhaust manifold with a light-off catalyst directly behind it demonstrated a drastic reduction in FTP (Federal Test Procedure) Total HC emissions.