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Ionic Liquids as Novel Lubricants or Lubricant Additives

2012-05-10
For internal combustion engines and industrial machinery, it is well recognized that the most cost-effective way of reducing energy consumption and extending service life is through lubricant development. This presentation summarizes our recent R&D achievements on developing a new class of candidate lubricants or oil additives ionic liquids (ILs). Features of ILs making them attractive for lubrication include high thermal stability, low vapor pressure, non-flammability, and intrinsic high polarity. When used as neat lubricants, selected ILs demonstrated lower friction under elastohydrodynamic lubrication and less wear at boundary lubrication benchmarked against fully-formulated engine oils in our bench tests. More encouragingly, a group of non-corrosive, oil-miscible ILs has recently been developed and demonstrated multiple additive functionalities including anti-wear and friction modifier when blended into hydrocarbon base oils.
Journal Article

Fuels for Advanced Combustion Engines Research Diesel Fuels: Analysis of Physical and Chemical Properties

2009-11-02
2009-01-2769
The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and1H/13C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT™) apparatus.
Technical Paper

Numerical Parametric Study of a Six-Stroke Gasoline Compression Ignition (GCI) Engine Combustion- Part II

2020-04-14
2020-01-0780
In order to extend the operability limit of the gasoline compression ignition (GCI) engine, as an avenue for low temperature combustion (LTC) regime, the effects of parametric variations of engine operating conditions on the performance of six-stroke GCI (6S-GCI) engine cycle are numerically investigated, using an in-house 3D CFD code coupled with high-fidelity physical sub-models along with the Chemkin library. The combustion and emissions were calculated using a skeletal chemical kinetics mechanism for a 14-component gasoline surrogate fuel. Authors’ previous study highlighted the effects of the variation of injection timing and split ratio on the overall performance of 6S-GCI engine and the unique mixing-controlled burning mode of the charge mixtures during the two additional strokes. As a continuing effort, the present study details the parametric studies of initial gas temperature, boost pressure, fuel injection pressure, compression ratio, and EGR ratio.
Journal Article

Effects of Fuel Physical Properties on Diesel Engine Combustion using Diesel and Bio-diesel Fuels

2008-04-14
2008-01-1379
A computational study using multi-dimensional CFD modeling was performed to investigate the effects of physical properties on diesel engine combustion characteristics with bio-diesel fuels. Properties of typical bio-diesel fuels that were either calculated or measured are used in the study and the simulation results are compared with those of conventional diesel fuels. The sensitivity of the computational results to individual physical properties is also investigated, and the results provide information about the desirable characteristics of the blended fuels. The properties considered in the study include liquid density, vapor pressure, surface tension, liquid viscosity, liquid thermal conductivity, liquid specific heat, latent heat, vapor specific heat, vapor diffusion coefficient, vapor viscosity and vapor thermal conductivity. The results show significant effects of the fuel physical properties on ignition delay and burning rates at various engine operating conditions.
Journal Article

Fatigue Behavior of Dissimilar Ultrasonic Spot Welds in Lap-Shear Specimens of Magnesium and Steel Sheets

2011-04-12
2011-01-0475
Fatigue behavior of dissimilar ultrasonic spot welds in lap-shear specimens of magnesium AZ31B-H24 and hot-dipped-galvanized mild steel sheets is investigated based on experimental observations, closed-form stress intensity factor solutions, and a fatigue life estimation model. Fatigue tests were conducted under different load ranges with two load ratios of 0.1 and 0.2. Optical micrographs of the welds after the tests were examined to understand the failure modes of the welds. The micrographs show that the welds mainly fail from kinked fatigue cracks growing through the magnesium sheets. The optical micrographs also indicate that failure mode changes from the partial nugget pullout mode under low-cycle loading conditions to the transverse crack growth mode under high-cycle loading conditions. The closed-form stress intensity factor solutions at the critical locations of the welds are used to explain the locations of fatigue crack initiation and growth.
Journal Article

Failure Modes of Friction Stir Spot Welds in Lap-Shear Specimens of Dissimilar Advanced High Strength Steels under Quasi-Static and Cyclic Loading Conditions

2012-04-16
2012-01-0479
Failure modes of friction stir spot welds in lap-shear specimens of dissimilar high strength dual phase steel (DP780GA) and hot stamped boron steel (HSBS) sheets are investigated under quasi-static and cyclic loading conditions based on experimental observations. Optical micrographs of dissimilar DP780GA/HSBS friction stir spot welds made by a concave tool before and after failure are examined. The micrographs indicate that the failure modes of the welds under quasi-static and cyclic loading conditions are quite similar. The micrographs show that the DP780GA/HSBS welds mainly fail from cracks growing through the upper DP780GA sheets where the concave tool was plunged into during the welding process. Based on the observed failure modes, a kinked fatigue crack growth model is adopted to estimate fatigue lives.
Journal Article

Combustion Studies with FACE Diesel Fuels: A Literature Review

2012-09-10
2012-01-1688
The CRC Fuels for Advanced Combustion Engines (FACE) Working Group has provided a matrix of experimental diesel fuels for use in studies on the effects of three parameters, Cetane number (CN), aromatics content, and 90 vol% distillation temperature (T90), on combustion and emissions characteristics of advanced combustion strategies. Various types of fuel analyses and engine experiments were performed in well-known research institutes. This paper reviews a collection of research findings obtained with these nine fuels. An extensive collection of analyses were performed by members of the FACE working group on the FACE diesel fuels as a means of aiding in understanding the linkage between fuel properties and combustion and emissions performance. These analyses included non-traditional chemical techniques as well as established ASTM tests. In a few cases, both ASTM tests and advanced analyses agreed that some design variables differed from their target values when the fuels were produced.
Journal Article

Failure Mode and Fatigue Behavior of Friction Stir Spot Welds in Lap-Shear Specimens of Dissimilar Advanced High Strength Steels

2013-04-08
2013-01-1023
Failure mode and fatigue behavior of friction stir spot welds made with convex and concave tools in lap-shear specimens of dissimilar high strength dual phase steel (DP780GA) and hot stamped boron steel (HSBS) sheets are investigated based on experiments and a kinked fatigue crack growth model. Lap-shear specimens with the welds were tested under both quasistatic and cyclic loading conditions. Optical micrographs indicate that under both quasi-static and cyclic loading conditions, the welds mainly fail from cracks growing through the upper DP780GA sheets where the tools were plunged in during the welding processes. Based on the observed failure mode, a kinked fatigue crack growth model is adopted to estimate fatigue lives of the welds. In the kinked crack fatigue crack growth model, the stress intensity factor solutions for fatigue life estimations are based on the closed-form solutions for idealized spot welds in lap-shear specimens.
Journal Article

Failure Mode and Fatigue Behavior of Ultrasonic Spot Welds with Adhesive in Lap-Shear Specimens of Magnesium and Steel Sheets

2013-04-08
2013-01-1020
Failure modes and fatigue behaviors of ultrasonic spot welds in lap-shear specimens of magnesium AZ31B-H24 and hot-dipped-galvanized mild steel sheets with and without adhesive are investigated. Ultrasonic spot welded, adhesive-bonded, and weld-bonded lap-shear specimens were made. These lap-shear specimens were tested under quasi-static and cyclic loading conditions. The ultrasonic spot weld appears not to provide extra strength to the weld-bonded lap-shear specimen under quasi-static and cyclic loading conditions. The quasi-static and fatigue strengths of adhesive-bonded and weld-bonded lap-shear specimens appear to be the same. For the ultrasonic spot welded lap-shear specimens, the optical micrographs indicate that failure mode changes from the partial nugget pullout mode under quasi-static and low-cycle loading conditions to the kinked crack growth mode under high-cycle loading conditions.
Technical Paper

Residual Stress Analysis for Additive Manufactured Large Automobile Parts by Using Neutron and Simulation

2020-04-14
2020-01-1071
Metal additive manufacturing has high potential to produce automobile parts, due to its shape flexibility and unique material properties. On the other hand, residual stress which is generated by rapid solidification causes deformation, cracks and failure under building process. To avoid these problems, understanding of internal residual stress distribution is necessary. However, from the view point of measureable area, conventional residual stress measurement methods such as strain gages and X-ray diffractometers, is limited to only the surface layer of the parts. Therefore, neutron which has a high penetration capability was chosen as a probe to measure internal residual stress in this research. By using time of flight neutron diffraction facility VULCAN at Oak Ridge National Laboratory, residual stress for mono-cylinder head, which were made of aluminum alloy, was measured non-distractively. From the result of precise measurement, interior stress distribution was visualized.
Technical Paper

Experimental Investigation of Low Cost, Low Thermal Conductivity Thermal Barrier Coating on HCCI Combustion, Efficiency, and Emissions

2020-04-14
2020-01-1140
In-cylinder surface temperature is of heightened importance for Homogeneous Charge Compression Ignition (HCCI) combustion since the combustion mechanism is thermo-kinetically driven. Thermal Barrier Coatings (TBCs) selectively manipulate the in-cylinder surface temperature, providing an avenue for improving thermal and combustion efficiency. A surface temperature swing during combustion/expansion reduces heat transfer losses, leading to more complete combustion and reduced emissions. At the same time, achieving a highly dynamic response sidesteps preheating of charge during intake and eliminates the volumetric efficiency penalty. The magnitude and temporal profile of the dynamic surface temperature swing is affected by the TBC material properties, thickness, morphology, engine speed, and heat flux from the combustion process. This study follows prior work of authors with Yttria Stabilized Zirconia, which systematically engineered coatings for HCCI combustion.
Technical Paper

A 2-D Computational Model Describing the Heat Transfer, Reaction Kinetics and Regeneration Characteristics of a Ceramic Diesel Particulate Trap

1998-02-23
980546
A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.
Technical Paper

Effects of Silicon and Boron Additions on the Susceptibility to Quench Embrittlement and the Bending Fatigue Performance of Vacuum Carburized Modified 4320 Steel

2007-04-16
2007-01-1005
The effect of B and Si additions on fracture and fatigue performance of vacuum carburized 4320 steel and modifications of 4320 steel containing additions of Si (1.0 and 2.0 wt pct) and B (0 and 17 ppm) was evaluated by bending fatigue testing. Three rates of gas quenching, in 10 bar nitrogen and 15 and 20 bar helium, were used to cool specimens after carburizing. The B, protected by Ti additions, together with the Si additions, increased core hardenability. The B/Si modified steels showed no improvement in fatigue resistance, as measured by endurance limits established by 10 million cycle runouts without fracture. However, scanning electron microscopy showed that Si reduced sensitivity to intergranular fracture or quench embrittlement, a major cause of bending fatigue crack initiation, and contributed to variable fatigue performance, with both low-cycle failures and runout performance at applied stresses significantly above measured endurance limits.
Technical Paper

Direct Measurement of EGR Cooler Deposit Thermal Properties for Improved Understanding of Cooler Fouling

2009-04-20
2009-01-1461
Exhaust gas recirculation (EGR) cooler fouling has become a significant issue for compliance with NOx emissions standards. This paper reports results of a study of fundamental aspects of EGR cooler fouling. An apparatus and procedure were developed to allow surrogate EGR cooler tubes to be exposed to diesel engine exhaust under controlled conditions. The resulting fouled tubes were removed and analyzed. Volatile and non-volatile deposit mass was measured for each tube. Thermal diffusivity of the deposited soot cake was measured by milling a window into the tube and using the Xenon flash lamp method. The heat capacity of the deposit was measured at temperatures up to 430°C and was slightly higher than graphite, presumably due to the presence of hydrocarbons. These measurements were combined to allow calculation of the deposit thermal conductivity, which was determined to be 0.041 W/mK, only ∼1.5 times that of air and much lower than the 304 stainless steel tube (14.7 W/mK).
Technical Paper

Wood-to-Wheels: A Multidisciplinary Research Initiative in Sustainable Transportation Utilizing Fuels and Co-Products from Forest Resources

2008-10-20
2008-21-0026
Michigan Technological University has established a broad-based university-wide research initiative, termed Wood-to-Wheels (W2W), to develop and evaluate improved technologies for growing, harvesting, converting, and using woody biomass in renewable transportation fuel applications. The W2W program bridges the entire biomass development-production-consumption life cycle with research in areas including forest resources, bioprocessing, engine/vehicle systems, and sustainable decisions. The W2W chain establishes a closed cycle of carbon between the atmosphere, woody biomass, fuels, and vehicular systems that can reduce the accumulation of CO2 in the atmosphere. This paper will summarize the activities associated with the Wood-to-Wheels initiative and describe challenges and the potential benefits that are achievable.
Technical Paper

Steel Processing Effects on Impact Deformation of UltraLight Steel Auto Body

2001-03-05
2001-01-1056
The objective of the research presented in this paper was to assess the influence of stamping process on crash response of UltraLight Steel Auto Body (ULSAB) [1] vehicle. Considered forming effects included thickness variations and plastic strain hardening imparted in the part forming process. The as-formed thickness and plastic strain for front crash parts were used as input data for vehicle crash analysis. Differences in structural performance between crash models with and without forming data were analyzed in order to determine the effects and feasibility of integration of forming processes and crash models.
Technical Paper

The Effects of Natural Aging on Fleet and Durability Vehicle Engine Mounts from a Dynamic Characterization Perspective

2001-04-30
2001-01-1449
Elastomers are traditionally designed for use in applications that require specific mechanical properties. Unfortunately, these properties change with respect to many different variables including heat, light, fatigue, oxygen, ozone, and the catalytic effects of trace elements. When elastomeric mounts are designed for NVH use in vehicles, they are designed to isolate specific unwanted frequencies. As the elastomers age however, the desired elastomeric properties may have changed with time. This study looks at the variability seen in new vehicle engine mounts and how the dynamic properties change with respect to miles accumulated on fleet and durability test vehicles.
Technical Paper

Exhaust Aftertreatment Research for Heavy Vehicles

2001-05-14
2001-01-2064
The Office of Heavy Vehicle Technologies supports research to enable high-efficiency diesel engines to meet future emissions regulations, thus clearing the way for their use in light trucks as well as continuing as the most efficient powerplant for freight-haulers. Compliance with Tier 2 emission regulations for light-duty vehicles will require effective exhaust emission controls (aftertreatment) for diesels in these applications. Diesel-powered heavy trucks face a similar situation for the 2007 regulations announced by EPA in December 2000. DOE laboratories are working with industry to improve emission control technologies in projects ranging from application of new diagnostics for elucidating key mechanisms, to development and evaluation of prototype devices. This paper provides an overview of these R&D efforts, with examples of key findings and developments.
Technical Paper

Performance of a NOX Adsorber and Catalyzed Particle Filter System on a Light-Duty Diesel Vehicle

2001-05-07
2001-01-1933
A prototype emissions control system consisting of a close-coupled lightoff catalyst, catalyzed diesel particle filter (CDPF), and a NOX adsorber was evaluated on a Mercedes A170 CDI. This laboratory experiment aimed to determine whether the benefits of these technologies could be utilized simultaneously to allow a light-duty diesel vehicle to achieve levels called out by U.S. Tier 2 emissions legislation. This research was carried out by driving the A170 through the U.S. Federal Test Procedure (FTP), US06, and highway fuel economy test (HFET) dynamometer driving schedules. The vehicle was fueled with a 3-ppm ultra-low sulfur fuel. Regeneration of the NOX adsorber/CDPF system was accomplished by using a laboratory in-pipe synthesis gas injection system to simulate the capabilities of advanced engine controls to produce suitable exhaust conditions. The results show that these technologies can be combined to provide high pollutant reduction efficiencies in excess of 90% for NOX and PM.
Technical Paper

Collaborative Development of Lightweight Metal and Alloys for Automotive Applications

2002-06-03
2002-01-1938
In September 1993, the Partnership for a New Generation of Vehicles (PNGV) program, initiated a cooperative research and development (R&D) program between the federal government and the United States Council Automotive Research (USCAR) to develop automotive technologies to reduce the nation's dependence on petroleum and reduce emissions of greenhouse gases by improving fuel economy. A key enabler for the attainment of these goals is a significant reduction in vehicle weight. Thus the major focus of the PNGV materials program is the development of materials and technologies that would result in the reduction of vehicle weight by up to 40%. The Automotive Lightweighting Materials (ALM) Program in the Office of Advanced Automotive Technologies (OAAT) of the Department of Energy (DOE), the PNGV Materials Technical Team and the United States Automotive Materials Partnership (USAMP) collaborate to conduct research and development on these materials.
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