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In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

A numerical investigation on a series of Diesel spray experiments in constant-volume vessels is proposed. Non reacting conditions were used to assess the spray models and to determine the grid size required to correctly predict the fuel-air mixture formation process. To this end, not only computed liquid and vapor penetrations were compared with experimental data, but also a detailed comparison between computed and experimental mixture fraction distributions was performed at different distances from the injector. Grid dependency was reduced by introducing an Adaptive Local Mesh Refinement technique (ALMR) with an arbitrary level of refinement. Once the capabilities of the current implemented spray models have been assessed, reacting conditions at different ambient densities and temperatures were considered. A Perfectly Stirred Reactor (PSR) combustion model, based on a direct integration of complex chemistry mechanisms over a homogenous cell, was adopted.

Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

In this work a multilevel CFD analysis have been applied for the design of an intake air-box with improved characteristics of noise reduction and fluid dynamic response. The approaches developed and applied for the optimization process range from the 1D to fully 3D CFD simulation, exploring hybrid approaches based on the integration of a 1D model with quasi-3D and 3D tools. In particular, the quasi-3D strategy is exploited to investigate several configurations, tailoring the best trade-off between noise abatement at frequencies below 1000 Hz and optimization of engine performances. Once the best configuration has been defined, the 1D-3D approach has been adopted to confirm the prediction carried out by means of the simplified approach, studying also the impact of the new configuration on the engine performances.

The selective catalytic reduction has seen widespread adoption as the best technology to reduce the NOx emissions from internal combustion engines, particularly for Diesels. This technology uses ammonia as a reducing agent, which is obtained injecting an ammonia carrier into the exhaust gas stream. The dosing of the ammonia carrier, usually AdBlue, is the major concern during the design and engine calibration phases, since the interaction between the injected liquid and the components of the exhaust system can lead to the undesired formation of solid deposits. To avoid this, the thermal and kinematic interaction between the spray and the components of the after treatment system (ATS) must be modeled accurately. In this work, the authors developed a Conjugate Heat Transfer (CHT) framework to model the kinetic and thermal interaction among the spray, the eventual liquid layer and the pipe walls.

The reliable prediction of pollutant emissions generated by IC engine powertrains during the WLTP driving cycle is a key aspect to test and optimize different configurations, in order to respect the stringent emission limits. This work describes the application of an integrated modeling tool in a co-simulation environment, coupling a 1D fluid dynamic code for engine simulation with a specific numerical code for aftertreatment modelling by means of a robust numerical approach, to achieve a complete methodology for detailed simulations of driving cycles. The main goal is to allow an accurate 1D simulation of the unsteady flows along the intake and exhaust systems and to apply advanced thermodynamic combustion models for the calculation of cylinder-out emissions.

The injection process of urea-water solution (AdBlue) determines initial conditions for reactions and catalysis and is fundamentally responsible for optimal operation of selective catalytic reduction (SCR) systems. The spray characteristics of four, commercially available, injectors (one air-assisted and three pressure-driven with different nozzle-hole configurations) are investigated with non-intrusive measuring techniques. Injection occurred in the crossflow of a channel blowing preheated air in an exhaust duct similar configuration. The effect of several gas temperatures and flows on the spray propagation and entrainment has been extensively studied by shadow imaging. Shadow images, in addition, show that the spray of the pressure-driven injectors is only marginally affected by the gas crossflow. In contrast, the air assisted spray is strongly deflected by the gas, the effect increasing with increasing gas flow.

Nowadays quasi-3D approaches are included in many commercial and research 1D numerical codes, in order to increase their simulation accuracy in presence of complex shape 3D volumes, e.g. plenums and silencers. In particular, these are regarded as valuable approaches for application during the design phase of an engine, for their capability of predicting non-planar waves motion and, on the other hand, for their low requirements in terms of computational runtime. However, the generation of a high-quality quasi-3D computational grid is not always straightforward, especially in case of complex elements, and can be a time-consuming operation, making the quasi-3D tool a less attractive option. In this work, a quasi-3D module has been implemented on the basis of the open-source CFD code OpenFOAM and coupled with the 1D code GASDYN.

In this work, a promising technique, consisting of a liquid Water Injection (WI) at the intake ports, is investigated to overcome over-fueling and delayed combustions typical of downsized boosted engines, operating at high loads. In a first stage, experimental tests are carried out in a spark-ignition twin-cylinder turbocharged engine at a fixed rotational speed and medium-high loads. In particular, a spark timing and a water-to-fuel ratio sweep are both specified, to analyze the WI capability in increasing the knock-limited spark advance. In a second stage, the considered engine is schematized in a 1D framework. The model, developed in the GT-Power™ environment, includes user defined procedures for the description of combustion and knock phenomena. Computed results are compared with collected data for all the considered operating conditions, in terms of average performance parameters, in-cylinder pressure cycles, burn rate profiles, and knock propensity, as well.

In the last decades numerical simulations have become reliable tools for the design and the optimization of silencers for internal combustion engines. Different approaches, ranging from simple 1D models to detailed 3D models, are nowadays commonly applied in the engine development process, with the aim to predict the acoustic behavior of intake and exhaust systems. However, the acoustic analysis is usually performed under the hypothesis of infinite stiffness of the silencer walls. This assumption, which can be regarded as reasonable for most of the applications, can lose validity if low wall thickness are considered. This consideration is even more significant if the recent trends in the automotive industry are taken into account: in fact, the increasing attention to the weight of the vehicle has lead to a general reduction of the thickness of the metal sheets, due also to the adoption of high-strength steels, making the vibration of the components a non negligible issue.

In this work an integration between a 1D code (Gasdyn) with a CFD code (OpenFOAM®) has been applied to improve the performance of a Moto3TM engine. The four-stroke, single cylinder S.I. engine was modeled, in order to predict the wave motion in the intake and exhaust systems and study how it affects the cylinder gas exchange process. The engine considered was characterized by having an air induction system with integrated filter cartridge, air-box and intake runner, resulting in a complex air-path form the intake mouth to the intake valves, which presents critical aspects when a 1D modeling is addressed. This paper presents a combined and integrated simulation, in which the intake systems was modeled as a 3D geometry whereas the exhaust system, which presented a simpler geometry, was modeled by means of a 1D approach.

Metallic foams or sponges are materials with a cell structure suitable for many industrial applications, such as reformers, heat catalytic converters, etc. The success of these materials is due to the combination of various characteristics such as mechanical strength, low density, high specific surface, good thermal exchange properties, low flow resistance and sound absorption. Different materials and manufacturing processes produce different type of structure and properties for various applications. In this work a genetic algorithm has been developed and applied to support the design of catalytic devices. In particular, two substrates were considered, namely the traditional honeycomb and an alternative open-cell foam type. CFD simulations of pressure losses and literature based correlations for the heat and mass transfer were used to support the genetic algorithm in finding the best compromise between flow resistance and pollutant abatement.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Nowadays a great attention is paid to the level and quality of noise radiated from the tailpipe end of intake and exhaust systems, to control the gas dynamic noise emitted by the engine as well as the characteristics of the cabin interior sound. The muffler geometry can be optimized consequently, to attenuate or remark certain spectral components of the engine noise, according to the result expected. Evidently the design of complex silencing systems is a time-consuming operation, which must be carried out by means of concurrent experimental measurements and numerical simulations. In particular, 1D and multiD linear/non-linear simulation codes can be applied to predict the silencer behavior in the time and frequency domain. This paper describes the development of a 1D-multiD integrated approach for the simulation of complex muffler configurations such as reverse chambers with inlet and outlet pipe extensions and perforated silencers with the addition of sound absorbing material.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

The influence of the inertia properties (mass, centre of gravity location, and inertia tensor) on the dynamic behaviour of the engine-gearbox system of a car is studied in this paper, devoting particular attention to drivability and comfort. The vibration amplitudes and the natural frequencies of the engine-gearbox system have been considered. Additionally, the loads transmitted to the car body have been taken into account. Both the experimental and the theoretical simulations confirmed that the engine-gearbox vibrations in the range 10 - 15 Hz are particularly sensitive to slight variation of the inertia properties. The effects on engine-gearbox vibrations due to half-axles, exhaust system, pipes and inner engine-gearbox fluids have been highlighted.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

In the last decades the continuously tightening limitations on pollutant emissions has led to an extensive adoption of after-treatment devices on the exhaust systems of modern internal combustion engines. While these devices are primarily introduced for reducing and controlling the emissions, they also play an important role influencing the wave motion inside the exhaust system and so affecting the acoustics and the performances of the engine. In this paper a novel approach is proposed for the modeling of two after-treatment devices: the catalyst and the Diesel Particulate Filter. The models are based on a fast quasi-3D approach, named 3Dcell, originally developed by the authors for the acoustic modeling of silencers. This approach allows to model the wave motion by solving the momentum equation along the three directions.

Today, Direct-Injection systems are widely used on Spark-Ignition engines in combination with turbo-charging to reduce the fuel-consumption and the knock risks. In particular, the spread of Gasoline Direct Injection (GDI) systems is mainly related to the use of new generations of multi-hole, high-pressure injectors whose characteristics are quite different with respect to the hollow-cone, low-pressure injectors adopted in the last decade. This paper presents the results of an experimental campaign conducted on the spray produced by a GDI six-holes injector into a constant volume vessel with optical access. The vessel was filled with air at atmospheric pressure. Different operating conditions were considered for an injection pressure ranging from 3 to 20 MPa. For each operating condition, spray images were acquired by a CCD camera and then post processed to evaluate the spray penetration and cone angles.