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With a high thermal efficiency and low CO2 (carbon dioxide) emissions, Diesel engines become leader of transport market. However, the exhaust-gas legislation evolution leads to a drastic reduction of NOx (nitrogen oxide) standards with very low particulate, HC (unburned hydrocarbons) and CO (carbon monoxide) emissions, while combustion noise and fuel consumption must be kept under control. The reduction of the volumetric compression ratio (CR) is a key factor to reach this challenge, but it is today limited by the capabilities to provide acceptable performances during very cold operation: start and idle below −10°C. This paper focuses on the understanding of the main parameter’s impacts on cold operation. Effects of parameters like hardware configuration and calibration optimization are investigated on a real 4 cylinder Diesel 14:1 CR engine, with a combination of specific advanced tools.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

The formation mechanisms of unburned hydrocarbons (HC) in low NOx, homogeneous type Diesel combustion have been investigated in both standard and optical access single cylinder engines operating under low load (2 and 4 bar IMEP) conditions. In the standard (i.e. non-optical) engine, parameters such as injection timing, intake temperature and global equivalence ratio were varied in order to analyse the role of bulk quenching on HC emissions formation. Laser-induced fluorescence (LIF) imaging of in-cylinder unburned HC within the bulk gases was performed on the optical-access engine. Furthermore, studies were performed in order to ascertain whether the piston top-land crevice volume contributes significantly to engine-out HC emissions. Finally, the role of piston-top fuel films and their impact on HC emissions was studied. This was investigated on the all-metal engine using two fuels of different volatilities.

The reduction of NOx emissions required by the future Euro 6 standards leads engine manufacturers to develop Diesel Homogeneous Charge Compression Ignition (HCCI) combustion processes. Because this concept allows reducing both NOx and particulates simultaneously, it appears as a promising way to meet the next environmental challenges. Unfortunately, HCCI combustion often increases CO and HC emissions. Conventional oxidation catalyst technologies, currently used for Euro 4 vehicles, may not be able to convert these emissions because of the saturation of active catalytic sites. As a result, such increased CO and HC emissions have to be reduced under standard levels using innovative catalysts or emergent technologies. The work reported in this paper has been conducted within the framework of the PAGODE project (PSA, IFP, Chalmers University, APTL, CRF, Johnson Matthey and Supelec) and financed by the European Commission.

A 3 way catalytic converter (3WCC) model based on a global kinetic model was developed and validated against laboratory scale and engine test bench experiments. Various equivalence ratios and temperatures were tested. A methodology was finalized and applied to calibrate the kinetic constants. Laboratory scale experiments were first used to characterize the reaction mechanism during light-off, including the way reduction and oxidation reactions begin and compete with each other when temperature increases. The numerical results are in good agreement with the laboratory scale light-off results. Also, when adapted to simulate the engine test bench experiments, the model is able to correctly reproduce both the light-off tests and the 3WCC conversion efficiency evolution versus equivalence ratio. A calibration method in two steps was thus established and successfully used. The combination of modeling with experimental work appeared to be a powerful tool to determine the reaction mechanism.

The influence of the type of fuel and the feeding means to a DOC, in order to regenerate a DPF, was investigated. Diesel fuel in cylinder late post-injection was compared to the injection in the exhaust line, through an exhaust port injector, of diesel fuel, B10 (diesel fuel containing 10% of esters) and gasoline. Diesel fuel exhaust injection resulted in a deteriorated conversion efficiency, while the incorporation of esters to the diesel fuel was demonstrated to have no influence. Gasoline exhaust injection led to less HC slip than diesel fuels. Temperature dynamics resulting from injection steps showed taught that the shorter the hydrocarbons (within the tested fuels), the slower the response. These differences can be caught by simple models, leading to interesting opportunities for the model-based control of the DPF inlet temperature during active regenerations.

Latest emissions standards impose very low NOx and particle emissions that have led to new Diesel combustion operating conditions, such as low temperature combustion (LTC). The principle of LTC is based on enhancing air fuel mixing and reducing combustion temperature, reducing raw nitrogen oxides (NOx) and particle emissions. However, new difficulties have arisen. LTC is typically achieved through high dilution rates and low CR, resulting in increased auto-ignition delay that produces significant noise and deteriorates the combustion phasing. At the same time, lower combustion temperature and reduced oxygen concentration increases hydrocarbon (HC) and carbon oxide (CO) emissions, which can be problematic at low load. Therefore, if LTC is a promising solution to meet future emission regulations, it imposes a new emissions, fuel consumption and noise trade-off. For this, the injection strategy is the most direct mean of controlling the heat release profile and fuel air mixture.

In order to asses the durability of DPF, a study has been performed in order to study the evolution of several taxis (Peugeot 607) and the performance of this after-treatment systems over 80,000 km mileage in hard urban driving conditions, which corresponds to the recommended mileage before the first DPF maintenance (this periodicity is applied on the first generation of DPF technology launched in 2000). More specifically, the following evaluations are being performed at regular intervals (around 20 000 km): Regulated gaseous pollutant emissions on NEDC cycle (New European Driving Cycle) Particulate emissions, by mass measurement on NEDC but also by particle number and size measurement with SMPS (Scanning Mobility Particle Sizer) technique on NEDC and on unconventional steady-state running points.

Due to their high thermal efficiency coupled with low CO2 emissions, Diesel engines are promised to an increasing part of the transport market if their NOx and particulate emissions are reduced. Today, adequate after-treatments, NOx and PM traps are under industrialization with still concerns about fuel economy, robustness, sensitivity to fuel sulfur and cost because of their complex and sophisticated strategy. New combustion process such as Homogeneous Charge Compression Ignition (HCCI) are investigated for their potential to achieve near zero particulate and NOx emissions. Their main drawbacks are too high hydrocarbons (HC) and carbon monoxide (CO) emissions, combustion control at high load and then limited operating range and power output. As an answer for challenges the Diesel engine is facing, IFP has developed a combustion system able to reach near zero particulate and NOx emissions while maintaining performance standards of the D.I Diesel engines.

Air quality improvement, especially in urban areas, is one of the major concerns for the coming years. For this reason, car manufacturers, equipment manufacturers and refiners have explored development issues to comply with increasingly severe anti-pollution requirements. In such a context, the identification of the most promising improvement options is essential. A research program, carried out by IFP (Institut Français du Pétrole), and supported by the French Ministry of Industry, IFP, PSA-Peugeot-Citroën, Renault and RVI (Renault Véhicules Industriels), has been built to study this point. It is based on a three years program with different steps focused on new engine technologies which will be available in the next 20 years in order to answer to more and more severe pollutant and CO2 emission regulations. This program is divided into three main parts: the first one for Diesel car engines, the second for Diesel truck engines and the third for spark ignition engines.

The use of Diesel engines has strongly increased during the last years and now represents 30% of the sales in Europe and up to 50% of the number of cars in circulation for some countries. This success is linked not only to the economical aspect of the use of such vehicles, but also to the recent technological improvements of these engines. The new technical solutions (high pressure direct injection, turbocharging…) have indeed allowed the increase of these engine performances while decreasing their fuel consumption, pollutant emissions and noise level. From an environmental point of view, Diesel engines are nevertheless penalized by their particulate and NOx emissions. The study and the treatment of the particulate, highly criticized for their potential impact on health, are the subject of numerous works of characterization and developments. PSA Peugeot-Citroën has recently launched its particulate filter technology on several types of vehicles.

The influence of spray-wall interaction on air entrainment in an unsteady non-evaporating diesel spray was studied using laser Doppler anemometry. The spray was injected into confined quiescent air at ambient pressure and temperature and made to impact on a flat wall. The air velocity component normal to a cylindrical surface surrounding the spray was measured during the entire injection period, allowing to evaluate the time history of the entrained air mass flow rate. The influence of wall distance and spray impingement angle on air entrainment characteristics has been investigated and the results indicate that the presence of a wall increases the entrained mass flow rate in the region close to the surface, during the main injection period. Normal impingement appears to produce stronger effects than oblique incidence at 30 and 45 deg. A qualitative explanation of the results is also proposed, based on the drop-gas momentum exchange mechanism.

Aim of this work is to present and discuss the possibility and the limits of two zone models for spark-ignition engines using a detailed kinetic scheme for the characterization of the evolution of the air-fuel mixture, while an equilibrium approach is used for the burnt zone. Simple experimental measurements of knocking tendency of different fuels in ideal reactors, such as rapid compression machines and shock tube reactors, cannot be directly used for the analysis of octane numbers and sensitivity of hydrocarbon mixtures. Thus a careful investigation is very useful, not only of the combustion chamber behavior, including the modelling of the turbulent flame front propagation, but also of the fluid dynamic behavior of the intake and exhaust system, accounting for the volumetric efficiency of the engine.

The reduction of particulate emissions from Diesel engines is a key issue to meet future emission standards. Particulate traps represent an attractive solution to the problem of this source of pollution. However, they have the disadvantage of requiring periodic and safe regeneration to release exhaust back pressure and to recover filtration efficiency. Natural regeneration of the particulate filter may occur. Nevertheless, with light-duty vehicles and their low level of exhaust gas temperature, it may be necessary to facilitate or force the regeneration. The objective of this work is to give an overview of the possibilities offered by the engine management system to increase significantly exhaust gas temperatures. Thus, different engine tunes, through injection timing, boost pressure or EGR rate, may be sufficient to ensure safe regeneration of the trap.

The Computational Chemistry Consortium (C3) is dedicated to leading the advancement of combustion and emissions modeling. The C3 cluster combines the expertise of different groups involved in combustion research aiming to refine existing chemistry models and to develop more efficient tools for the generation of surrogate and multi-fuel mechanisms, and suitable mechanisms for CFD applications. In addition to the development of more accurate kinetic models for different components of interest in real fuel surrogates and for pollutants formation (NOx, PAH, soot), the core activity of C3 is to develop a tool capable of merging high-fidelity kinetics from different partners, resulting in a high-fidelity model for a specific application. A core mechanism forms the basis of a gasoline surrogate model containing larger components including n-heptane, iso-octane, n-dodecane, toluene and other larger hydrocarbons.

NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.