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Although soot-formation processes in diesel engines have been well characterized during the mixing-controlled burn, little is known about the distribution of soot throughout the combustion chamber after the end of appreciable heat release during the expansion and exhaust strokes. Hence, the laser-induced incandescence (LII) diagnostic was developed to visualize the distribution of soot within an optically accessible single-cylinder direct-injection diesel engine during this period. The developed LII diagnostic is semi-quantitative; i.e., if certain conditions (listed in the Appendix) are true, it accurately captures spatial and temporal trends in the in-cylinder soot field. The diagnostic features a vertically oriented and vertically propagating laser sheet that can be translated across the combustion chamber, where “vertical” refers to a direction parallel to the axis of the cylinder bore.

The detailed mechanisms by which oxygenated diesel fuels reduce engine-out soot emissions are not well understood. The literature contains conflicting results as to whether a fuel's overall oxygen content is the only important parameter in determining its soot-reduction potential, or if oxygenate molecular structure or other variables also play significant roles. To begin to resolve this controversy, experiments were conducted at a 1200-rpm, moderate-load operating condition using a modern-technology, 4-stroke, heavy-duty DI diesel engine with optical access. Images of broadband natural luminosity (i.e., light emission without spectral filtering) from the combustion chamber, coupled with heat-release and efficiency analyses, are presented for three test-fuels. One test-fuel (denoted GE80) was oxygenated with tri-propylene glycol methyl ether; the second (denoted BM88) was oxygenated with di-butyl maleate. The overall oxygen contents of these two fuels were matched at 26% by weight.

Fuel-injection schedules that use two injection events per cycle (“dual-injection” approaches) have the potential to simultaneously attenuate engine-out soot and NOx emissions. The extent to which these benefits are due to enhanced mixing, low-temperature combustion modes, altered combustion phasing, or other factors is not fully understood. A traditional single-injection, an early-injection-only, and two dual-injection cases are studied using a suite of imaging diagnostics including spray visualization, natural luminosity imaging, and planar laser-induced fluorescence (PLIF) imaging of nitric oxide (NO). These data, coupled with heat-release and efficiency analyses, are used to enhance understanding of the in-cylinder processes that lead to the observed emissions reductions.

The accurate quantification and control of mixture stoichiometry is critical in many applications using new combustion strategies and fuels (e.g., homogeneous charge compression ignition, gasoline direct injection, and oxygenated fuels). The parameter typically used to quantify mixture stoichiometry (i.e., the proximity of a reactant mixture to its stoichiometric condition) is the equivalence ratio, ϕ. The traditional definition of ϕ is based on the relative amounts of fuel and oxidizer molecules in a mixture. This definition provides an accurate measure of mixture stoichiometry when the fuel molecule does not contain oxidizer elements and when the oxidizer molecule does not contain fuel elements. However, the traditional definition of ϕ leads to problems when the fuel molecule contains an oxidizer element, as is the case when an oxygenated fuel is used, or once reactions have started and the fuel has begun to oxidize.