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Well-mixed lean SI engine operation can provide improvements of the fuel economy relative to that of traditional well-mixed stoichiometric SI operation. This work examines the use of two methods for improving the stability of lean operation, namely multi-pulse transient plasma ignition and intake air preheating. These two methods are compared to standard SI operation using a conventional high-energy inductive ignition system without intake air preheating. E85 is the fuel chosen for this study. The multi-pulse transient plasma ignition system utilizes custom electronics to generate 10 kHz bursts of 10 ultra-short (12ns), high-amplitude pulses (200 A). These pulses were applied to a custom spark plug with a semi-open ignition cavity. High-speed imaging reveals that ignition in this cavity generates a turbulent jet-like early flame spread that speeds up the transition from ignition to the main combustion event.

The downsizing of internal combustion engines to increase fuel economy leads to challenges in both obtaining ignition and stabilizing combustion at boosted intake pressures and high exhaust gas recirculation dilution conditions. The use of non-thermal plasma ignition technologies has shown promise as a means to more reliably ignite dilute charge mixtures at high pressures. Despite progress in fundamental research on this topic, both the capabilities and operation implications of emerging non-thermal plasma ignition technologies in internal combustion engine applications are not yet fully explored. In this work, we document the effects of using a corona discharge ignition system in a single cylinder gasoline direct injection research engine relative to using a traditional inductive spark ignition system under conditions associated with both naturally aspirated (8 bar BMEP) and boosted (20 bar BMEP) loads at moderate (2000 rpm) and high (4000 rpm) engine speeds.

Lithium-Ion batteries are being considered as a high-energy density replacement for Nickel Metal Hydride (NiMH) batteries in Hybrid Electric Vehicles (HEVs) and in the new Plug-In Hybrids (PHEVs). Although these cells can result in significant reduction in weight and volume, they have several safety related issues that still need to be addressed. We report here on the thermal response of Li-ion cells specifically assembled in our laboratory to test new materials, electrolytes and additives. Improvements in the thermal abuse tolerance of cells will be presented and discussed in terms of the need for overall battery system safety.

This study investigates the potential of partial fuel stratification for reducing the knocking propensity of intake-boosted HCCI engines operating on conventional gasoline. Although intake boosting can substantially increase the high-load capability of HCCI, these engines would be more production-viable if the knock/stability load limit could be extended to allow higher loads at a given boost and/or to provide even higher thermal efficiencies. A technique termed partial fuel stratification (PFS) has recently been shown to greatly reduce the combustion-induced pressure-rise rate (PRR), and therefore the knocking propensity of naturally aspirated HCCI, when the engine is fueled with a φ-sensitive, two-stage-ignition fuel. The current work explores the potential of applying PFS to boosted HCCI operation using conventional gasoline, which does not typically show two-stage ignition. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) at 1200 rpm.

We present a parametric analysis of electric vehicle (EV) adoption rates and the corresponding contribution to greenhouse gas (GHG) reduction in the US light-duty vehicle (LDV) fleet through 2050. The analysis is performed with a system dynamics based model of the supply-demand interactions among the fleet, its fuels, and the corresponding primary energy sources. The differentiating feature of the model is the ability to conduct global sensitivity and parametric trade-space analyses. We find that many factors impact the adoption rates of EVs. These include, in particular, policy initiatives that encourage consumers to consider lifetime ownership costs, the price of oil, battery performance, as well as the pace of technological development for all powertrains (conventional internal combustion engines included). Widespread EV adoption can have noticeable impact on petroleum consumption and GHG emissions by the LDV fleet.

In light-duty direct-injection (DI) diesel engines, combustion chamber geometry influences the complex interactions between swirl and squish flows, spray-wall interactions, as well as late-cycle mixing. Because of these interactions, piston bowl geometry significantly affects fuel efficiency and emissions behavior. However, due to lack of reliable in-cylinder measurements, the mechanisms responsible for piston-induced changes in engine behavior are not well understood. Non-intrusive, in situ optical measurement techniques are necessary to provide a deeper understanding of the piston geometry effect on in-cylinder processes and to assist in the development of predictive engine simulation models. This study compares two substantially different piston bowls with geometries representative of existing technology: a conventional re-entrant bowl and a stepped-lip bowl. Both pistons are tested in a single-cylinder optical diesel engine under identical boundary conditions.

Direct injection (DI) has proven to be a promising option in Diesel and low temperature combustion engines. In conventional Diesel and homogeneous charge compression ignition (HCCI) applications, DI lowers soot and NOx production and improves fuel economy. In hydrogen fueled engines, DI provides the appropriate energy density required for high efficiency and low NOx emissions. To realize the full benefit of DI, however, the effect of various injection parameters, such as injection timing, duration, pressure, and dilution, must be investigated and optimized under a range of engine operating conditions. In this work, we have developed a model for high-fidelity calculations of DI processes using the Large Eddy Simulation (LES) technique and an advanced property evaluation scheme. Calculations were performed using an idealized domain to establish a baseline level of validation.

Sandia National Laboratories has been investigating a new, integrated approach to generating electricity with ultra low emissions and very high efficiency for low power (30 kW) applications such as hybrid vehicles and portable generators. Our approach utilizes a free piston in a double-ended cylinder. Combustion occurs alternately at each cylinder end, with intake/exhaust processes accomplished through a two stroke cycle. A linear alternator is mounted in the center section of the cylinder, serving to both generate useful electrical power and to control the compression ratio by varying the rate of electrical generation. Thus, a mechanically simple geometry results in an electronically controlled variable compression ratio configuration. The capability of the homogeneous charge compression ignition combustion process employed in this engine with regards to reduced emissions and improved thermal efficiency has been investigated using a rapid compression expansion machine.

The engine-out emissions and fuel consumption rates for a modern, heavy-duty diesel engine were compared when fueling with a conventional diesel fuel and three water-blend-fuel emulsions. Four different fuels were studied: (1) a conventional diesel fuel, (2) PuriNOx,™ a water-fuel emulsion using the same conventional diesel fuel, but having 20% water by mass, and (3,4) two other formulations of the PuriNOx™ fuel that contained proprietary chemical additives intended to improve combustion efficiency and emissions characteristics. The emissions data were acquired with three different injection-timing strategies using the AVL 8-Mode steady-state test method in a Caterpillar 3176 engine, which had a calibration that met the 1998 nitrogen oxides (NOX) emissions standard.

This paper describes the experimental evaluation of a prototype free piston engine - linear alternator (FPLA) system developed at Sandia National Laboratories. The opposed piston design was developed to investigate its potential for use in hybrid electric vehicles (HEVs). The system is mechanically simple with two-stroke uniflow scavenging for gas exchange and timed port fuel injection for fuel delivery, i.e. no complex valving. Electrical power is extracted from piston motion through linear alternators which also provide a means for passive piston synchronization through electromagnetic coupling. In an HEV application, this electrical power would be used to charge the batteries. The engine-alternator system was designed, assembled and operated over a 2-year period at Sandia National Laboratories in Livermore, CA.

The Advanced Battery Readiness Ad Hoc Working Group, a government- industry forum sponsored by the United States Department of Energy, is charged with assessing environmental and safety issues associated with advanced batteries for electric and hybrid electric vehicles. Electric and hybrid electric vehicles require sophisticated advanced battery storage systems. Frequently, toxic, reactive, and flammable substances are used in the energy storage systems. Often, the substances have safety, recycling, and shipping implications with respect to U.S. Environmental Protection Agency and Department of Transportation regulations. To facilitate commercialization, reg-ulations must either be modified or newly developed. Government-industry coordination has expedited needed regulatory changes, and promoted other partnerships to achieve environmental and safety solutions.

The desire to move high-energy Pulsed Power systems from the laboratory to practical field systems requires the development of compact lightweight drivers. This paper concerns an effort to develop such a system based on a plastic laminate strip Blumlein as the final pulse shaping stage for a 600 kV, 50ns, 5-ohm driver. A lifetime and breakdown study conducted with small-area samples identified Kapton sheet impregnated with Propylene Carbonate as the best material combination of those evaluated. The program has successfully demonstrated techniques for folding large area systems into compact geometry's and vacuum impregnating the laminate in the folded systems. The major operational challenges encountered revolve around edge grading and low inductance, low impedance switching. The design iterations and lessons learned will be discussed. A multistage prototype testing program has demonstrated 600kV operation on a short 6ns line.

Advanced rechargeable lithium-ion batteries are presently being developed and commercialized worldwide for use in consumer electronics, military and space applications. The motivation behind these efforts involves, among other things, a favorable combination of energy and power density. For some of the applications the power sources may need to perform at a reasonable rate at subambient temperatures. Given the nature of the lithium-ion cell chemistry the low temperature performance of the cells may not be very good. At Sandia National Laboratories, we have used different electrochemical techniques such as impedance and charge/discharge at ambient and subambient temperatures to probe the various electrochemical processes that are occurring in Li-ion cells. The purpose of this study is to identify the component that reduces the cell performance at subambient temperatures.

Thermal batteries are normally constructed using pressed-powder anode, separator, and cathode pellets (discs). However, parts less than 0.010” thick are difficult to press from the starting powders. The use of plasma spraying to deposit thin pyrite films onto a stainless steel substrate was examined as an alternative to pressed-powder cathodes. The electrodes were tested under isothermal conditions and constant-current discharge over a temperature range of 400°C to 550°C using a standard LiSi anode and a separator based on the LiCIKCI eutectic. The plasma-sprayed cathodes were also evaluated in similar 5-cell thermal batteries. Cells and batteries using pressed-powder cathodes were tested under the same conditions for comparative purposes.

Silica aerogels have 1/3 the thermal conductivity of the best commercial composite insulations, or ~13 mW/m-K at 25 °C. However, aerogels are transparent in the near IR region of 4-7 μm, which is where the radiation peak from a thermal-battery stack occurs. Titania and carbon-black powders were examined as thermal opacifiers, to reduce radiation at temperatures between 300°C and 600°C, which spans the range of operating temperature for most thermal batteries. The effectiveness of the various opacifiers depended on the loading, with the best overall results being obtained using aerogels filled with carbon black. Fabrication and strength issues still remain, however.

The influence of early induction stroke direct injection on late-cycle flows was investigated for a lean-burn, high-tumble, gasoline engine. The engine features side-mounted injection and was operated at a moderate load (8.5 bar brake mean effective pressure) and engine speed (2000 revolutions per minute) condition representative of a significant portion of the duty cycle for a hybridized powertrain system. Thermodynamic engine tests were used to evaluate cam phasing, injection schedule, and ignition timing such that an optimal balance of acceptable fuel economy, combustion stability, and engine-out nitrogen oxide (NOx) emissions was achieved. A single cylinder of the 4-cylinder thermodynamic engine was outfitted with an endoscope that enabled direct imaging of the spark discharge and early flame development.

This work is a comprehensive technical review of existing literature and a synthesis of current understanding of the governing physics behind the interaction of multiple fuel injections, ignition, and combustion behavior of multiple-injections in diesel engines. Multiple-injection is a widely adopted operating strategy applied in modern compression-ignition engines, which involves various combinations of small pre-injections and post-injections of fuel before and after the main injection and splitting the main injection into multiple smaller injections. This strategy has been conclusively shown to improve fuel economy in diesel engines while achieving simultaneous NOX, soot, and combustion noise reduction - in addition to a reduction in the emissions of unburned hydrocarbons (UHC) and CO by preventing fuel wetting and flame quenching at the piston wall.