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Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.

A solid particle number measurement system (SPNMS) was developed using a catalytic stripper (CS) technology instead of an evaporation tube (ET). The ET is used in commercially available systems, compliant with the Particle Measurement Program (PMP) protocol developed for European Union (EU) solid particle number regulations. The catalytic stripper consists of a small core of a diesel exhaust oxidation catalyst. The SPNMS/CS met all performance requirements under the PMP protocol. It showed a much better performance in removing large volatile tetracontane particles down to a size well below the PMP lower cut-size of 23 nm, compared to a SPNMS equipped with an ET instead of a CS. The SPNMS/CS also showed a similar performance to a commercially available system when used on a gasoline direct injection (GDI) engine exhaust.

A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.

Lower explosion limits (LEL) and the chemical compositions of JP-8, Jet A and JP-5 fuel vapors were determined in a sealed combustion vessel equipped with a spark igniter, a gas-sampling probe, and sensors to measure pressure rise and fuel temperature. Ignition was detected by pressure rise in the vessel. Pressure rises up to 60 psig were observed near the flash points of the test fuels. The fuel vapors in the vessel ignited from as much as 11°F below flash-point measurements. Detailed hydrocarbon speciation of the fuel vapors was performed using high-resolution gas chromatography. Over 300 hydrocarbons were detected in the vapors phase. The average molecular weight, hydrogen to carbon ratio, and LEL of the fuel vapors were determined from the concentration measurements. The jet fuel vapors had molecular weights ranging from 114 to 132, hydrogen to carbon ratios of approximately 1.93, and LELs comparable to pure hydrocarbons of similar molecular weight.

Newly designed Teflon® O-rings along with XAD-2 resin, stainless steel screens, lock rings, and glass cartridges were used to construct a new semi-volatile organic compounds (SVOC's) sampling device. This new sampling device allows direct and repeated sampling, extraction, and cleaning without ever having to be disassembled or reassembled. This new XAD-2 glass cartridge (X2) was compared with three other sampling methods namely Empore® membrane (EM), hexane impinger (HI), and “Cold Trap” (CT) for SVOC sampling efficiency on diesel engine exhaust emissions. The X2 method showed the highest overall SVOC collection efficiency, followed by the EM and HI methods. The X2 method has higher trapping efficiency for the oxygenates, polycyclic aromatic hydrocarbons (PAH's), alkyl cyclohexanes, and the alkyl aromatics than the other three SVOC sampling methods. The HI method has the highest trapping efficiency for the normal alkanes.

This paper summarizes the validation testing of the Horiba Instruments OBS-2200 gaseous portable emissions measurement system (PEMS) for in-use compliance testing per Title 40 of the Code of Federal Regulations (CFR) Part 1065.920 (Section 1065.920). The qualification process included analyzer verifications as well as engine testing on a model-year 2007 heavy-duty diesel engine produced by Volvo Powertrain. The measurements of brake-specific emissions with the OBS-2200 were compared to those of a CFR Part 1065-compliant CVS test cell over a series of not-to-exceed (NTE) events. The OBS-2200 passed all linearity verifications and analyzer checks required of PEMS. Engine test validation was achieved for all three regulated gaseous emissions (CO, NMHC, and NOX) per 40 CFR Part 1065.920(b)(5)(i), which requires a minimum of 91 percent of the measurement allowance adjusted deltas to be less than or equal to zero.

The discrete droplet model is widely used to describe two-phase flows such as high-velocity dense sprays. The interaction between the liquid and the gas phase is modeled via appropriate source terms in the gas phase equations. This approach can lead to a strong dependence of the liquid-gas coupling on the spatial resolution of the gas phase. The liquid-gas coupling requires the computation of source terms using the gas phase properties, and, subsequently, these sources are then distributed onto the gas phase mesh. In this study, a Lagrange polynomial interpolation method has been developed to evaluate the source terms and also to distribute these source terms onto the gas mesh. The focus of this investigation has been on the momentum exchange between the two phases. The Lagrange polynomial interpolation and source term distribution methods are evaluated for non-evaporating sprays using KIVA3 as a modeling platform.

Non-evaporating diesel sprays have been simulated utilizing the ETAB and the WAVE atomization and breakup models and have been compared with experimental data. The experimental penetrations and widths were determined from back-lit spray images and the droplet sizes have been measured by means of a Malvern particle sizer. The model evaluation criteria include the spray penetration, the spray width and the local droplet size. The comparisons have been performed for variations of the injection pressure, the gas density and the fuel viscosity. The fuel nozzle exit velocities used in the simulations have been computed with a special code that considers the effect of in-nozzle cavitation. The simulations showed good overall agreement with experimental data. However, the capabilities of the models to predict the droplet size for different fuels could be improved.

Particle size distribution, number, and mass emissions from the exhaust of a 92 kW 1999 Isuzu 6BG1 nonroad naturally aspirated diesel engine were measured. The engine exhaust was equipped with a Dry System Technologies® (DST) auxiliary emission control device that included an oxidation catalyst, a heat exchanger, and a disposable paper particulate filter. Particle measurement was taken during the ISO 8178 8-mode test for engine out and engine with the DST using a scanning mobility particle sizer (SMPS) in parallel to the standard filter method (SFM), specified in 40 CFR, Part 89. The DST efficiency of removing particles was about 99.9 percent based on particle number, 99.99 percent based on particle mass derived from number and size. However, the efficiency based on mass derived from the SFM was much lower on the order of 90 to 93 percent.

Objective of this work is the incorporation of the flame stretch effects in an Eulerian-Lagrangian model for premixed SI combustion in order to describe ignition and flame propagation under highly inhomogeneous flow conditions. To this end, effects of energy transfer from electrical circuit and turbulent flame propagation were fully decoupled. The first ones are taken into account by Lagrangian particles whose main purpose is to generate an initial burned field in the computational domain. Turbulent flame development is instead considered only in the Eulerian gas phase for a better description of the local flow effects. To improve the model predictive capabilities, flame stretch effects were introduced in the turbulent combustion model by using formulations coming from the asymptotic theory and recently verified by means of DNS studies. Experiments carried out at Michigan Tech University in a pressurized, constant-volume vessel were used to validate the proposed approach.

The engine intake process governs many aspects of the flow within the cylinder. The inlet valve is the minimum area, so gas velocities at the valve are the highest velocities seen. Geometric configuration of the inlet ports and valves, and the opening schedule create organized large scale motions in the cylinder known as swirl and tumble. Good charge motion within the cylinder will produce high turbulence levels at the end of the compression stroke. As the turbulence resulting from the conversion energy of the inlet jet decays fast, the strategy is to encapsulate some of the inlet jet in the organized motions. In this work the baseline port of a 2.0 L gasoline engine was modified by inserting a tumble plate. The work was done in support of an experimental study for which a new single-cylinder research engine was set up to allow combustion system parameters to be varied in steps over an extensive range. Tumble flow was one such parameter.

This paper aims to extend the existing Volume of Fluid (VOF) model by implementing an evaporation sub-model in an open source Computational Fluid Dynamics (CFD) software, OpenFOAM. The paper applies the new model to numerically study the evaporation of spherical n-heptane droplets impinging on a hot wall at atmospheric pressure and a temperature above the Leidenfrost temperature. Volume of Fluid (VOF) method is chosen to track the liquid gas interface and the capability of VOF method implemented in interDyMFoam solver of OpenFOAM to simulate hydrodynamics during droplet-droplet interaction and droplet-film interaction is explored. Firstly, the in-built solver is used to simulate problems in isothermal conditions and the simulation results are compared qualitatively with the published results to validate the solver. A numerical method for modeling heat and mass transfer during evaporation is implemented in conjunction with the VOF.

Diesel combustion and emissions formation is largely spray and mixing controlled and hence understanding spray parameters, specifically vaporization, is key to determine the impact of fuel injector operation and nozzle design on combustion and emissions. In this study, an eight-hole common rail piezoelectric injector was tested in an optically accessible constant volume combustion vessel at charge gas conditions typical of full load boosted engine operation. Liquid penetration of the eight sprays was determined via processing of images acquired from Mie back scattering under vaporizing conditions by injecting into a charge gas at elevated temperature with 0% oxygen. Conditions investigated included a charge temperature sweep of 800 to 1300 K and injection pressure sweep of 1034 to 2000 bar at a constant charge density of 34.8 kg/m₃.

The paper describes an experimental activity on the spatial and temporal liquid- and vapor-phase distributions of diesel fuel at engine-like conditions. The influence of the k-factor (0 and 1.5) of a single-hole axial-disposed injector (0.100 mm diameter and 10 L/d ratio) has been studied by spraying fuel in an optically-accessible constant-volume combustion vessel. A high-speed imaging system, capable of acquiring Mie-scattering and Schlieren images in a near simultaneous fashion mode along the same line of sight, has been developed at the Michigan Technological University using a high-speed camera and a pulsed-wave LED system. The time resolved pair of schlieren and Mie-scattering images identifies the instantaneous position of both the vapor and liquid phases of the fuel spray, respectively. The studies have been performed at three injection pressures (70, 120 and 180 MPa), 23.9 kg/m3 ambient gas density and 900 K gas temperature in the vessel.

High-speed movie films, and laser-diffraction drop sizing were used to evaluate the structure, penetration rate, cone angle, and drop size distribution of diesel sprays in a constant volume pressure vessel. As further means of evaluating the data, comparisons are made between the film measurements, and calculations from a dense gas jet model. In addition to the high-speed film data that describes the overall structure of the spray as a function of time, a laser diffraction instrument was used to measure drop size distribution through a cross-section of the spray. In terms of the growth of the total spray volume (a rough measure of the amount of air entrained in the spray), spray impingement causes an initial delay, but generally the same overall growth rate as an equivalent unimpeded spray. Agreement between measurements and calculations is excellent for a diesel spray with a 0.15 mm D orifice and relatively high injection pressures.

A technique is presented that has been successfully demonstrated to non-intrusively and quickly sample gases typically found in PCV systems. Color Detection Tubes (CDTs) were used with a simple sampling arrangement to monitor CO2, NOx, O2, and H2O(g) at the closure line, crankcase, and PCV line. Measurements were accurate and could be made instantaneously. Short Path Thermal Desorbtion Tubes (SPTDTs) were used at the same engine locations for the characterization of fuel- and oil-derived hydrocarbon (HC) fractions and required only 50 cc samples. High engine loads caused pushover of blowby vapors as indicated by increased concentrations of CO2, NOx, H2O(g), and fuel HCs in the engines' fresh air inlets during WOT operation. Peak concentrations of blowby vapors were measured in the crankcase under no load and part throttle conditions. Oxygen concentrations always opposed the trends of CO2, NOx, and H2O(g).

Previously we reported (SAE Paper 2005-01-0475) that emissions of toxicologically relevant compounds from an engine operating at low NOx conditions using Fischer-Tropsch fuel (FT100) were lower than those emissions from the engine using an ultra-low sulfur (15 PPM sulfur) diesel fuel (BP15). Those tests were performed at two operating modes: Mode 6 (4.2 bar BMEP, 2300 RPM) and Mode 11 (2.62 bar BMEP, 1500 RPM). We wanted to evaluate the effect on emissions of operating the engine at low power (near idle) in conjunction with the low NOx strategy. Specifically, we report on emissions of total hydrocarbon (HC), carbon monoxide (CO), NOx, particulates (PM), formaldehyde, acetaldehyde, benzene, 1,3-butadiene, gas phase polyaromatic hydrocarbons (PAH's) and particle phase PAH's from a DaimlerChrysler OM611 CIDI engine using a low NOx engine operating strategy at Mode 22 (1.0 bar BMEP and 1500 RPM).

A 1-D 2-layer model developed previously at MTU was used in this research to predict the pressure drop, filtration characteristics and various properties of the particulate filter and the particulate deposit layer. The model was used along with dilute emission data to characterize two catalyzed particulate filters (CPFs) having different catalyst loading and catalyst application processes. The model was calibrated and validated with data obtained from steady state experiments conducted using a 1995 Cummins M11-330E heavy-duty diesel engine with manual EGR with different fuels for the two different CPFs. The two different catalyzed particulate filters were CPF III (5 gms/ft3 Pt) and CPF V (50 gms/ft3 Pt). Both the CPFs had cordierite substrates with CPF III and CPF V had MEX and NEX catalyst type formulation respectively. The CPF III filter was catalyzed using a solution-impregnated process while the CPF V filter was catalyzed using a wash coat process.

This investigation is a continuation of a previous study by these authors in which a Lagrange polynomial interpolation method was developed to evaluate spray source terms and also to distribute the source terms onto the gas mesh; the method was applied to the liquid-gas momentum exchange. For this investigation, the method has been extended to the mass exchange between the liquid and gas phases due to evaporation. The Lagrange polynomial interpolation and source term distribution methods are applied to the liquid-gas mass and momentum exchange and are evaluated for evaporating sprays using KIVA3 as a modeling platform. These methods are compared with the standard “nearest neighbor” method of KIVA3, and experimental data are used to establish their validity. The evaluation criteria used include the liquid and vapor spray penetration, gas velocities and the computational stability.

This paper examines the role of inhalation toxicity of the products of combustion that are generated in post-collision motor vehicle fires by automotive materials used under the hood. Small-scale toxic gas measurements were performed at Southwest Research Institute® (SwRI®) on eighteen components of two of the vehicles that were tested previously at the Factory Mutual Test Center (FMTC). The small-scale toxic gas measurements were obtained under dynamic flow-through conditions in the Cone Calorimeter (ASTM E 1354) and under static conditions in two smoke chamber methods (ASTM E 662 and ASTM E 1995); all methods were supplemented with FTIR gas analysis. Average yields of toxic gases measured in the Cone Calorimeter are comparable to but consistently lower than values reported in the literature for the Fire Propagation Apparatus (ASTM E 2058).