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Methane abatement in the exhaust gas of natural gas engines is much more challenging in respect to the oxidation of other higher order hydrocarbons. Under steady state λ sweep, the methane conversion efficiency is high at exact stoichiometric, and decreases steeply under both slightly rich and slightly lean conditions. Transient lean to rich transitions can improve methane conversion at the rich side. Previous experimental work has attributed the enhanced methane conversion to activation of methane steam reforming. The steam reforming rate, however, attenuates over time and the methane conversion rate gradually converges to the low steady state values. In this work, a reactor model is established to predict steady state and transient transition characteristics of a three-way catalyst (TWC) mounted in the exhaust of a natural gas heavy-duty engine.

To characterize the effects of renewable fuels on particulate emissions from GDI engines, engine experiments were conducted using EN228-compliant gasoline fuel blends containing no oxygenates, 10% ethanol (EtOH), or 22% ethyl tert-butyl ether (ETBE). The experiments were conducted in a single cylinder GDI engine using a 6-hole fuel injector operated at 200 bar injection pressure. Both PN in raw exhaust and solid PN (SPN) were measured at two load points and various start of injection (SOI) timings. Raw PN and SPN results were classified into various size ranges, corresponding to current and future legislations. At early SOI timings, where particulate formation is dominated by diffusion flames on the piston due to liquid film, the oxygenated blends yielded dramatically higher PN and SPN emissions than reference gasoline because of fuel effects.

The interaction of turbulent premixed methane combustion with the surrounding flow field can be studied using optically accessible test rigs such as a rapid compression expansion machine (RCEM). The high flexibility offered by such a test rig allows its operation at various thermochemical conditions at ignition. However, limitations inherent to such test rigs due to the absence of an intake stroke do not allow turbulence production as found in IC-engines. Hence, means to introduce turbulence need to be implemented and the relevant turbulence quantities have to be identified in order to enable comparability with engine relevant conditions. A dedicated high-pressure direct injection of air at the beginning of the compression phase is considered as a measure to generate adjustable turbulence intensities at spark timing and during the early flame propagation.

Combustion characteristics of dimethyl ether, DME, have been investigated experimentally, in a heavy duty single cylinder engine equipped with an adapted common rail fuel injection system, and the effects of varying injection timing, rail pressure and exhaust gas recirculation on the combustion and emission parameters. The results show that DME combustion does not produce soot and with the use of exhaust gas recirculation NOX emissions can also be reduced to very low levels. However, high injection pressure and/or a DME adopted combustion system is required to improve the mixing process and thus reduce the combustion duration and carbon monoxide emissions.

Experiments were performed using a Light-Duty, single-cylinder, research engine in which the emissions, fuel consumption and combustion characteristics of two Fischer-Tropsch (F-T) Diesel fuels derived from natural gas and two conventional Diesel fuels (Swedish low sulfur Diesel and European EN 590 Diesel) were compared. Due to their low aromatic contents combustion with the F-T Diesel fuels resulted in lower soot emissions than combustion with the conventional Diesel fuels. The hydrocarbon emissions were also significantly lower with F-T fuel combustion. Moreover the F-T fuels tended to yield lower CO emissions than the conventional Diesel fuels. The low emissions from the F-T Diesel fuels, and the potential for producing such fuels from biomass, are powerful reason for future interest and research in this field.

In the study reported here the combustion and emission characteristics of a heavy duty six-cylinder diesel engine fuelled with dimethyl ether (DME) of chemical grade and DME with small and varying amounts of methanol and/or water were experimentally investigated. In addition, the size distribution of emitted particles and selected unregulated emissions were sampled. Methanol and water additions had a very limited effect on emissions, but affected the combustion processes in a way that accentuated the premixed combustion and thus caused more energy to be released early in the cycle. At high load, however, the effect was reversed, due to the lack of distinct premixed combustion. The results confirm that DME combustion does not generate any accumulation mode particles. The particles that are detected are smaller than the soot size range and do not occur in greater numbers than those from a diesel engine in the corresponding size range.

The sustainability of Martian outposts development is strongly based on the capability of achieving a high level of autonomy both in terms of operations management and of resources availability. In situ production of consumables is a key point to allow humans to work and live on Mars avoiding or limiting the need for re-supplies of materials from Earth. Required consumables can be produced in situ exploiting the locally available resources, but also by means of green-houses and waste recycle systems. Dedicated robotic missions for in situ demonstration of this type of technologies are a fundamental step of the Martian In Situ Resources Utilization (ISRU) development roadmap. This paper is focused on the extraction of oxygen and fuels (e.g. methane) from the Martian atmosphere, and presents a feasibility study for a small technological demonstration plant.

The CFD model, based on the LANL KIVA-3 computer code, modified to account for the multi-step dimethyl ether, DME/air, oxidation chemistry, was developed and used to study the neat DME combustion dynamics in a constant volume at Diesel-like conditions and in the Volvo AH10A245DI Diesel engine. Constant volume simulations confirm high ignition quality of neat DME in air. The results of engine modeling illustrate that the injection schedule used for Diesel fuel is not optimal for DME. Surprisingly, the positive gain and peak pressure levels comparable with those for Diesel fuel were obtained using an early (∼ -20 ATDC) injection through a nozzle of a larger diameter at reduced injection pressures and velocities (∼150m/s) preventing too rapid spray atomization. At these conditions, combustion heat release has a specific two-stage character with a peak value placed behind the TDC.

This paper depicts the main topics of the experimental investigation on alcohol engine development field, aiming at the engineering targets for the emission levels. The first part of this study was focused on engine design optimization for running on ethanol mixed with poly-ethylene glycol (PEG) as ignition improver. It was shown that some design changes in compression ratio, turbine casing, injector nozzle configuration and exhaust pressure governor (EPG) activation, lead to a better engine thermodynamics and its thermochemistry. The second objective of this study was the investigation of engine performance and emission levels, when the ignition improver diethyl ether (DEE) would be generated on board via catalytically dehydration of ethanol, and used directly as soluble mixture or separately fumigated.

DME was tested in a heavy duty diesel engine and in an optically accessible high-temperature and pressure spray chamber in order to investigate and understand the effect of nozzle parameters on emissions, combustion and fuel spray concentration. The engine study clearly showed that smaller nozzle orifices were advantageous from combustion, efficiency and emissions considerations. Heat release analysis and fuel concentration images indicate that smaller orifices result in higher mixing rate between fuel and air due to reductions in the turbulence length scale, which reduce both the magnitude of fuel-rich regions and the steepness of fuel gradients in the spray, which enable more fuel to burn and thereby shorten the combustion duration.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

Laws concerning to emissions from heavy duty (HD) internal combustion engines are becoming increasingly stringent. New engine technologies are therefore needed to satisfy these new legal requirements and reduce fossil fuel dependency. One way to achieve both objectives is to partially replace fossil fuels with alternatives that are more sustainable with respect to emissions of greenhouse gas, particulates and NOx. As a first step towards the development of a direct injected dual fuel engine using diesel fuel and renewable alcohols such as methanol or ethanol, we have studied ethanol (E100) sprays generated with a standard high pressure diesel fuel injection system in a high pressure/temperature spray chamber with optical access. The experiments were performed at a gas density of ∼27kg/m3 at ∼550 °C and ∼60 bar, representing typical operating conditions for a HD engine at low loads.

The evaporation of different fuels and fuel components in hollow-cone sprays at conditions similar to those at stratified cold start has been investigated using a combination of planar laser-induced fluorescence (LIF) and Mie scattering. Ketones of different volatility were used as fluorescent tracers for different fuel components in gasoline-like model fuels and ethanol-based fuels. LIF and Mie images were compared to evaluate to what extent various fuel components had evaporated and obtained a spatial distribution different from that of the liquid drops, as a function of fuel temperature and time after start of injection. A selective and sequential evaporation of fuel components of different volatility was found.

Over the past few years, an open-source code called OpenFOAM has been becoming a promising CFD tool for multi-dimensional numerical simulations of internal combustion engines. The primary goal of the present study is to assess the feasibility of the code for computations of hollow-cone sprays discharged by an outward-opening pintle-type injector by simulating the experiments performed recently by Hemdal et al., (SAE 2009-01-1496) with gasoline and ethanol sprays under the following conditions: air temperature Tair = 295 or 350 K, air pressure pair = 6 bar, fuel temperature Tfuel = 243, or 295, or 320 K, and fuel injection pressure pinj = 50, or 125, or 200 bar. To simulate the experiments, a pintle injector model and the physical properties of gasoline were implemented in OpenFOAM. The flow field calculated using the pintle injector model is more realistic than that yielded by the default unit injector model normally used in OpenFOAM.

The use of biodiesel in conventional diesel engines results in increased NOx emissions; this presents a barrier to the widespread use of biodiesel. The origins of this phenomenon were investigated using the CFD KIVA3V code, which was modified to account for the physical properties of biodiesel and to incorporate semi-detailed mechanisms for its combustion and the formation of emissions. Parametric φ-T maps and 3D engine simulations were used to assess the impact of using oxygen-containing fuels on the rate of NO formation. It was found that using oxygen-containing fuels allows more O₂ molecules to present in the engine cylinder during the combustion of biodiesel, and this may be the cause of the observed increase in NO emissions.

This work utilizes previously developed VSB2 (VSB2 Stochastic Blob and Bubble) multicomponent fuel spray model to study significance of using non-ideal thermodynamics for droplet evaporation under direct injection engine like operating conditions. Non-ideal thermodynamics is used to account for vapor-liquid equilibrium arising from evaporation of multicomponent fuel droplets. In specific, the evaporation of ethanol/iso-octane blend is studied in this work. Two compositions of the blend are tested, E-10 and E-85 respectively (the number denotes percentage of ethanol in blend). The VSB2 spray model is implemented into OpenFoam CFD code which is used to study evaporation of the blend in constant volume combustion vessel. Liquid and vapor penetration lengths for the E-10 case are calculated and compared with the experiment. The simulation results show reasonable agreement with the experiment. Simulation is performed with two methods- ideal and non-ideal thermodynamics respectively.

The ignition delay of ethanol with different nitrate and polyethylene glycol based ignition improvers was investigated in a single-cylinder DI Diesel engine. The nitrate-based improvers provided a shorter ignition delay than the polyethylene glycol improvers, but the results indicate that the efficiency of the polyethylene glycol improvers increases with the length of the molecular chains. Comparison with reference fuels gives a cetane number of approximately 44 for ethanol with 4% of the best nitrate-based improver versus 40 for ethanol with 7% polyethylene glycol improver. It is shown, that the random ignition delay for all the fuels has a normal distribution, and that the reference fuel of every measurement series has a constant expected ignition delay. Ignition delay measurements in a constant-volume combustion vessel failed to produce the same trends as in the engine for the ethanol fuels.

Methanol, MeOH, is one of the most attractive alternative fuels for internal combustion engines. In diesel applications, methanol's poor ignition properties necessitate the use of expensive additives for ignition improvement [1]. Dimethyl ether, DME, as a combustion improver for methanol, was recently evaluated in [2]. This study is directed towards a better understanding of the auto-ignition and combustion of a blend fuel composition consisting of liquid methanol and gaseous dimethyl ether aspirated with the combustion air by using the results of numerical simulation. The numerical model was based on the computer code KIVA-3. The computational results show that the use of DME as an ignition improver is only reasonable for gas temperatures below 900 K. At typical diesel conditions, an amount of DME in a quantity less than 10-15 volumetric percent of oxygen content in the combustion volume is sufficient for ignition improvement.

The free piston internal combustion engine used in conjunction with a linear alternator offers an interesting choice for use in hybrid vehicles. The linear motion of the pistons is directly converted to electricity by the alternator, and the result is a compact and efficient energy converter that has only one moving part. The movement of the pistons is not prescribed by a crank mechanism, but is the result of the equilibrium of forces acting on the pistons, and the engine will act like a mass-spring system. This feature is one of the most prominent advantages of the FPE (Free Piston Engine), as the lack of mechanical linkage gives means of varying the compression ratio in simple manners, without changing the hardware of the engine. By varying the compression ratio, it is also it possible to run on a multitude of different fuels and to use HCCI (Homogeneous Charge Compression Ignition) combustion.

Dimethyl ether (DME) represents a promising fuel for heavy-duty engines thanks to its high cetane number, volatility, absence of aromatics, reduced tank-to-wheel CO2 emissions compared to Diesel fuel and the possibility to be produced from renewable energy sources. However, optimization of compression-ignition engines fueled with DME requires suitable computational tools to design dedicated injection and combustion systems: reduced injection pressures and increased nozzle diameters are expected compared to conventional Diesel engines, which influences both the air-fuel mixing and the combustion process. This work intends to evaluate the validity of two different combustion models for the prediction of performance and pollutant emissions in compression-ignition engines operating with DME. The first one is the Representative Interactive Flamelet while the second is the Approximated Diffusive Flamelet.