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A passive thermal management system (TMS) using composite phase change material (PCM) for large-capacity, rectangular lithium-ion batteries is designed. A battery module consisting of six Li-ion cells connected in series was investigated as a basic unit. The passive TMS for the module has three configurations according to the contact area between cells and the composite PCM, i.e., surrounding, front-contacted and side-contacted schemes. Firstly, heat generation rate of the battery cell was calculated using the Bernardi equation based on experimentally measured heat source terms (i.e. the internal resistance and the entropy coefficient). Physical and thermal properties such as density, phase change temperature, latent heat and thermal conductivity of the composite PCM were also obtained by experimental methods. Thereafter, thermal response of the battery modules with the three TMS configurations was simulated using 3D finite element analysis (FEA) modeling in ANSYS Fluent.

The thermophysical parameters and amount of composite phase change materials (PCMs) have decisive influence on the thermal control effects of thermal management systems (TMSs). At the same time, the various thermophysical parameters of the composite PCM are interrelated. For example, increasing the thermal conductivity is bound to mean a decrease in the latent heat of phase change, so a balance needs to be achieved between these parameters. In this paper, a prismatic LiFePO4 battery cell cooled by composite PCM is comprehensively analyzed by changing the phase change temperature, thermal conductivity and amount of composite PCM. The influence of the composite PCM parameters on the cooling and temperature homogenization effect of the TMS is analyzed. which can give useful guide to the preparation of composite PCMs and design of the heat transfer enhancement methods for TMSs.

As one of the most crucial components in electric vehicles, power batteries generate abundant heat during charging and discharging processes. Thermal management system (TMS), which is designed to keep the battery cells within an optimum temperature range and to maintain an even temperature distribution from cell to cell, is vital for the high efficiency, long calendar life and reliable safety of these power batteries. With the desirable features of low system complexity, light weight, high energy efficiency and good battery thermal uniformity, thermal management using composite phase change materials (PCMs) has drawn great attention in the past fifteen years. In the hope of supplying helpful guidelines for the design of the PCM-based TMSs, this work begins with the summarization of the most commonly applied heat transfer enhancement methods (i.e., the use of thermally conductive particles, metal fin, expanded graphite matrix and metal foam) for PCMs by different researchers.