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An EURO 3 certified common rail diesel engine was fueled with pure petroleum diesel (EURO 4 standard) and three different alternative blended diesel fuels, 10% biodiesel blended diesel (B10), 10% gas to liquid blended diesel (G10) and 10% water emulsified diesel (E10). Tests were performed at different engine speeds and load states. Particle number concentration and size distribution data were obtained from an engine exhaust particle sizer (EEPS). Over all the working conditions, total particle and nucleation mode particle number concentration among these fuels from high to low were in this order: B10, E10, pure diesel and G10. Proportions for nucleation mode particle over all the operating states in that order were 89%, 82%, 59% and 66%. Particle size distributions of B10 and E10 presented bimodal logarithmic distributions with outstanding nucleation mode peaks at all working conditions.

Based on pure diesel, pure biodiesel, and two biodiesel blends at volumetric mixture ratio of 10% and 20%, NEDC emission tests were carried out on a Euro 3-compliant diesel car. Results showed that pure biodiesel and biodiesel blends had decreasing effects on CO and HC emissions under warm-up situations, but deteriorations of CO and HC emissions were observed under cold start-up and low vehicle speed operating conditions, and this caused increasing results of CO and HC emission factors in NEDC tests when substituting pure diesel with both of pure biodiesel and biodiesel blend of 20%. Pure biodiesel aroused an increase in NOX emissions compared with pure diesel, but the two low mixture ratio biodiesel blends were observed in different increasing effects and even decreasing effects on NOX emissions. Only pure biodiesel had limited increasing effects on CO₂ emissions.