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The exhaust aftertreatment strategy is one of the most fundamental aspects of spark ignition engine technologies. For various types of engines (e.g., carburetor engine, PFI engine and GDI engine), measuring, purifying, modeling, and control strategies regarding the exhaust aftertreatment systems vary significantly. The primary goal of exhaust aftetreatment systems is to reduce the exhaust emission levels of NOx, HC and CO as well as to lower combustion soot. In general, there is a tradeoff among different engine performance aspects. The exhaust catalytic systems, such as the three way catalyst (TWC) and lean NOx trap (LNT) converters, can be applied together with the development of other engine technologies (e.g., variable valve timing, cold start). With respect to engine soot, some advanced diagnosing techniques are essential to obtain thorough investigation of exhaust emission mechanisms.

Recent toxicological and epidemiologic studies have shown that diesel emissions have been a significant toxic air contaminant. Catalyzed DPF (CDPF) not only significantly reduces the PM mass emissions (>90%), but also further promotes carrier self-regeneration and oxidize more harmful gaseous pollutants by the catalyst coated on the carrier. However, some ultrafine particles and potentially harmful gaseous pollutants, such as VOCs species, originally emitted in the vapor-phase at high plume temperature, may penetrate through the CDPF filter. Furthermore, the components and content of catalyst coated on the CDPF could influence the physicochemical properties and toxicity intensity of those escaping ultrafine particles and gaseous pollutants. In this work, (1) we investigated the influence of precious metal content as a variable parameter on the physicochemical properties and catalytic activities of the small CDPF samples.