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The poisoning of three way catalysts (TWC) by the phosphorus contained in oil formulations containing zinc dialkyldithiophosphate (ZDDP) is examined. Catalysts were exposed to various types of ZDDP and detergents under conditions that were known to reduce performance through phosphorus poisoning without the blocking of sites by formation of glazing. The presence of phosphorus was detected with energy dispersive x-ray spectroscopy (EDX). In addition to analyzing the surface concentration of the phosphorus on the washcoat, the catalyst was cross cut so phosphorus that diffused into the washcoat could be mapped. The total phosphorus in the catalyst could then be calculated. The amount of total phosphorus detected correlated well with the reduced activity of the catalyst as measured by the temperature of 50% conversion.

The Cummins M-11 high soot diesel engine test is a key tool in evaluating lubricants for the new PC-7 (CH-4) performance category. M-11 rocker arms and crossheads from tests with a wide range of lubricant performance were studied by surface analytical techniques. Abrasive wear by primary soot particles is supported by the predominant appearance of parallel grooves on the worn parts with their widths matching closely the primary soot particle sizes. Soot abrasive action appears to be responsible for removing the protective antiwear film and, thus, abrades against metal parts as well. Subsequent to the removal of the antiwear film, carbide particles, graphite nodules, and other wear debris are abraded, either by soot particles or sliding metal-metal contact, from the crosshead and rocker arm metal surfaces. These particles further accelerate abrasive wear. In addition to abrasive wear, fatigue wear was evident on the engine parts.

The Icing Branch at NASA Glenn Research Center has funded an exploratory effort to identify requirements for developing a flight dispatcher-centered web-based icing training program that would be available for all airspace users. Through research and discussions with personnel at airlines, target areas were identified as influences on the requirements for the training system: 1 Flight dispatchers' icing related judgments and decision-making; 2 Certification, new hire and recurrent flight dispatcher training with respect to icing; 3 Icing related weather sources and the problems that flight dispatchers may have in their interpretation; 4 Pedagogical strategies (such as flight dispatcher-centered scenario-based approaches) for delivering flight dispatcher training content; and 5 Concerns/constraints with respect to web-based training for flight dispatchers.

The electrochemical and corrosion behavior of metals in aqueous environments has received substantial attention. However, relatively little work has been devoted to the electrochemistry and corrosion of metals in non-aqueous environments. Now, with greater pressures to increase fuel efficiencies and decrease exhaust emissions, alternatives and additives to gasoline (including methanol and ethanol) are receiving increased attention from government agencies and automobile manufacturers. Unfortunately, fundamental studies of the corrosion behavior of metals in these solutions are scarce. The objective of the present work is to investigate the electrochemical and corrosion behavior of iron in methanolic solutions containing Cl, H+, SO42-, and H2O. To accomplish this, a full factorial design test matrix was developed to systematically evaluate the effects of these impurities on the corrosion behavior of iron.

Effects of a cabin-level humidity upset on an activated carbon column used for adsorption of trace compounds from air are examined through a series of experiments and computer simulations. Breakthrough curves measured for dichloromethane in the presence of water indicate that a rapid increase in relative humidity can displace large quantities of dichloromethane from the adsorbed phase resulting in effluent streams containing more than 20 times the feed concentration. Additionally, the breakthrough time for organic compounds is reduced significantly at high relative humidity. Numerical simulation results show favorable qualitative agreement with measured breakthrough curves, yet do not consistently predict accurate water or dichloromethane loadings at all experimental conditions.

This paper examines an originally designed airbag deployment system for use in static experimental testing. It consists of a pressure vessel and valve arrangement with pneumatic and electric controls. A piston functions like a valve when operated and is activated pneumatically to release the air in the tank. Once released, the air fills the attached airbag. The leading edge velocity can be controlled by the initial pressure in the tank, which can range up to 960 kPa. Three different test configurations were studied, which resulted in leading edge deployment speeds of approximately 20 m/s, 40 m/s, and 60 m/s. In experiments using this system, seven types of airbags were tested that differed in their material, coating, and presence of a tether. Data for each series of tests is provided. High speed video and film were used to record the deployments, and a pressure transducer measured the airbag's internal pressure.

Traumatic aortic rupture (TAR) accounts for a significant mortality in automobile crashes. A numerical method by means of a mesh-based code coupling is employed to elucidate the injury mechanism of TAR. The aorta is modeled as a single-layered thick wall composed of two families of collagen fibers using an anisotropic strain energy function with consideration of viscoelasticity. A set of constitutive parameters is identified from experimental data of the human aorta, providing strict local convexity. An in vitro aorta model reconstructed from the Visible Human dataset is applied to the pulsatile blood flow to establish the references of mechanical quantities for physiological conditions. A series of simulations is performed using the parameterized impact pulses obtained from frontal sled tests.