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A simple set of equations has been developed to characterize automotive fuel behavior in fuel tanks, fuel vapor systems and fuel rails, particularly under hot weather conditions. The system of equations links the vapor pressure P, the temperature T, and the mass fraction evaporated Z. Parameters are determined empirically from laboratory vapor pressure and distillation tests. With appropriate values for heat capacity, heat of vaporization, and vapor composition, the equations can be used to estimate upper flammability limits, fuel weathering under hot fuel handling conditions, pressure rise in tanks, and evaporative vapor generation. The equations were developed as part of a larger fuel vapor system model.

A vehicle's evaporative emission control system is continuously working, even when the vehicle is not running, due to generation of vapors from the fuel tank during ambient temperature variations. Diurnal temperature cycles cause the fuel tank to breathe the fuel vapor in and out, and thus the activated carbon canister is constantly loading and purging the hydrocarbon vapors. This paper discusses a study undertaken at Ford to evaluate the relationship between carbon canister condition and fuel tank vapor generation during diurnal cycles. The results of an extensive set of experiments are presented, and the data from these experiments are compared to the output of a fuel vapor system model also developed at Ford. Key parameters relating to the migration of hydrocarbons during the experimental conditions studied, including initial canister condition, canister volume, and canister geometry, are discussed.