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In the last ten years, the number of natural gas vehicles worldwide has grown rapidly with the biggest contribution coming from the Asia-Pacific and Latin America regions. As natural gas is the cleanest fossil fuel, the exhaust emissions from natural gas spark ignition vehicles are lower than those of gasoline powered vehicles. Moreover, natural gas is less affected by price fluctuations and its resources are more evenly widespread over the globe than to oil. However, as natural gas vehicles are usually bi-fuel gasoline and natural gas, the excellent knock resistant characteristics of natural gas cannot be completely exploited. This paper shows the results of an experimental activity performed on a passenger car fuelled alternatively by gasoline and compressed natural gas (CNG). The vehicle has been tested on a chassis dynamometer over standard (NEDC) and real driving cycles (Artemis CADC), allowing to investigate a wide range of operating conditions.