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Hydrogen has been largely proposed as a possible alternative fuel for internal combustion engines. Its wide flammability range allows higher engine efficiency with leaner operation than conventional fuels, for both reduced toxic emissions and no CO2 gases. Independently, Homogenous Charge Compression Ignition (HCCI) also allows higher thermal efficiency and lower fuel consumption with reduced NOX emissions when compared to Spark-Ignition (SI) engine operation. For HCCI combustion, a mixture of air and fuel is supplied to the cylinder and autoignition occurs from compression; engine is operated throttle-less and load is controlled by the quality of the mixture, avoiding the large fluid-dynamic losses in the intake manifold of SI engines. HCCI can be induced and controlled by varying the mixture temperature, either by Exhaust Gas Recirculation (EGR) or intake air pre-heating.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

Recent pressures on vehicle manufacturers to reduce their average fleet levels of CO2 emissions have resulted in an increased drive to improve fuel economy and enable use of fuels developed from renewable sources that can achieve a net reduction in the CO2 output of each vehicle. The most popular choice for spark-ignition engines has been the blending of ethanol with gasoline, where the ethanol is derived either from agricultural or cellulosic sources such as sugar cane, corn or decomposed plant matter. However, other fuels, such as butanol, have also arisen as potential candidates due to their similarities to gasoline, e.g. higher energy density than ethanol. To extract the maximum benefits from these new fuels through optimized engine design and calibration, an understanding of the behaviour of these fuels in modern engines is necessary.

Current developments in fuels and emissions regulations are resulting in an increasingly severe operating environment for diesel fuel injection systems. The formation of deposits within the holes or on the outside of the injector nozzle can affect the overall system performance. The rate of deposit formation is affected by a number of parameters, including operating conditions and fuel composition. For the work reported here an accelerated test procedure was developed to evaluate the relative importance of some of these parameters in a high pressure common rail fuel injection system. The resulting methodology produced measurable deposits in a custom-made injector nozzle on a single-cylinder engine. The results indicate that fuels containing 30%v/v and 100% Fatty Acid Methyl Ester (FAME) that does not meet EN 14214 produced more deposit than an EN590 petroleum diesel fuel.

Diesel fuels usually comprise a wide range of compounds having different molecular structures which can affect both the fuel's physical properties and combustion characteristics. In future, as synthetic fuels from fossil and sustainable sources become increasingly available, it could be possible to control the fuel's molecular structure to achieve clean and efficient combustion. This paper presents experimental results of combustion and emissions studies undertaken on a single cylinder diesel engine supplied with 18 different fuels each comprising a single, acyclic, non-oxygenated hydrocarbon molecule. These molecules were chosen to highlight the effect of straight carbon chain length, degree of saturation and the addition of methyl groups as branches to a straight carbon chain.

One of the latest advancements in injector technology is laser drilling of the nozzle holes. In this context, the spray formation and atomisation characteristics of gasoline, ethanol and 1-butanol were investigated for a 7-hole spark eroded (SE) injector and its ‘direct replacement’ Laser-drilled (LD) injector using optical techniques. In the first step of the optical investigation, high-speed spray imaging was performed in a quiescent injection chamber with global illumination using diffused Laser light. The images were statistically analyzed to obtain spray penetration, spray tip velocity and spray ‘cone’ angles. Furthermore, droplet sizing was undertaken using Phase Doppler Anemometry (PDA). A single spray plume was isolated for this analysis and measurements were obtained across the plume at a fixed distance from the nozzle exit.

Extensive literature exists on spray development, mixing and combustion regarding engine modeling and diagnostics using single-component and model fuels. However, often the variation in data between different fuels, particularly relating to spray development and its effect on combustion, is neglected or overlooked. By injecting into a quiescent chamber, this work quantifies the differences in spray development from a multi-hole direct-injection spark-ignition engine injector for two single-component fuels (iso-octane and n-pentane), a non-fluorescing multi-component model fuel which may be used for in-cylinder Laser Induced Fluorescence experiments, and several grades of pump gasoline (with and without additives). High-speed recordings of the sprays were made for a range of fuel temperatures and gas pressures. It is shown that a fuel temperature above that of the lowest boiling point fraction of the tested fuel at the given gas pressure causes a convergence of the spray plumes.

Synthetic bio-fuels, which can be obtained through the gasification of biomass into synthesis gas and the subsequent catalytic reaction of the synthesis gas into liquid fuel molecules, could play a key-role in providing a sustainable source of automotive fuels during the coming decades. This paper presents an attempt to understand the effect of molecular structure of potential oxygenated synthetic bio-fuel molecules of different structure on the diesel combustion process in both stratified and homogeneous combustion modes. Specifically, the effects of molecular structure on the energy release rates, gaseous exhaust emissions and the sub-micron particulate matter distribution were examined. The experiments were carried out on a single-cylinder direct-injection diesel engine using a specially adapted common-rail fuel-system which allowed the injection of small single-molecule fuel samples at high pressure.

The effect on the intake flow field, air fuel mixing processes, thermodynamic performance and emissions output has been investigated for a range of valve operating profiles. A standard speed load point of 2000 rpm and 2.7 bar IMEP720° has been reached by throttling the intake whilst running standard cam profiles, by early closing of both inlet valves (EIVC) and by early closing of each inlet individually to generate bulk swirl motions within the cylinder. Data has been recorded at stoichiometric air fuel ratios for both direct injection and port fuelled operation. The valve profiles have been applied to two single cylinder homogeneous gasoline direct injection (GDI) spark ignition engines, developed to investigate the potential of controlling engine load by limiting the inducted air mass using fully variable valve timing (FVVT) to reduce pumping losses at part load.

For a spark-ignition engine, the parasitic loss suffered as a result of conventional throttling has long been recognised as a major reason for poor part-load fuel efficiency. While lean, stratified charge, operation addresses this issue, exhaust gas aftertreatment is more challenging compared with homogeneous operation and three-way catalyst after-treatment. This paper adopts a different approach: homogeneous charge direct injection (DI) operation with variable valve actuations which reduce throttling losses. In particular, low-lift and early inlet valve closing (EIVC) strategies are investigated. Results from a thermodynamic single cylinder engine are presented that quantify the effect of two low-lift camshafts and one standard high-lift camshaft operating EIVC strategies at four engine running conditions; both, two- and single-inlet valve operation were investigated. Tests were conducted for both port and DI fuelling, under stoichiometric conditions.

An experimental study was carried out to investigate the effects of fuel injection timing on the spatial and temporal development of injected fuel sprays within a firing direct-injection spark-ignition (DISI) engine. It was found that the structure of the injected fuel sprays varied significantly with the timing of the injection event. During the induction stroke and the early part of the compression stroke, the development of the injected fuel sprays was shown to be controlled by the state of the intake and intake-generated gas flows at the start of injection (SOI).The relative influence of these two flow regimes on the injected fuel sprays during this period was also observed to change with injection timing, directly affecting tip penetration, spray/wall impingement and air-fuel mixing. Later in the compression stroke, the results show the development of the injected fuel sprays to be dominated by the increased cylinder pressure at SOI.

A study to investigate the influence of fuel injection timing on exhaust emissions from a single-cylinder direct-injection spark-ignition (DISI) research engine was performed. Experimental results were obtained for carbon monoxide (CO), unburned hydrocarbon (HC), and oxides of nitrogen (NOx). Images showing the variation of liquid-phase fuel distribution with changing injection timing were obtained in a firing optically-accessed engine of similar design. A correlation between measured emissions and observed liquid-phase fuel distribution was performed. This correlation was supported by development of phenomenological models that permit explanation of the variation of CO, HC, and NOx emissions with changes in air-fuel mixture preparation.

This experimental work was concerned with the combination of internal EGR with an early inlet valve closure strategy for improved part-load fuel economy. The experiments were performed in a new spark-ignited thermodynamic single cylinder research engine, equipped with a mechanical fully variable valvetrain on both the inlet and exhaust. During unthrottled operation at constant engine speed and load, increasing the mass of trapped residual allowed increased valve duration and lift to be used. In turn, this enabled further small improvements in gas exchange efficiency, thermal efficiency and hence indicated fuel consumption. Such effects were quantified under both port and homogeneous central direct fuel injection conditions. Shrouding of the inlet ports as a potential method to increase in-cylinder gas velocities has also been considered.

This paper presents the results of an experimental study into the liquid sheet break-up mechanisms of high-pressure swirl atomizers of the type commonly used in direct-injection spark-ignition (DISI) engines. Sheet disintegration was investigated at two fuel pressures: 5 and 10 MPa, and three ambient back pressures: 50, 100 (atmospheric) and 200 kPa for a pre-production DISI injector. Microscopic images of the near-nozzle spray region were obtained with a high-speed rotating drum camera and copper vapour laser. For the range of conditions considered, the results show the initial break-up to occur in ‘perforated-sheet’ mode. A novel ‘void fraction’ analysis technique was applied to multiple images from the steady-state period of a single injection event in order to characterise and quantify details of the sheet break-up process. The sheet break-up lengths obtained by the authors were compared with the break-up lengths predicted by three commonly employed models from the literature.

This paper presents the results of an experimental study into the effects of fuel injection pressure on mixture formation within an optically accessed direct-injection spark-ignition (DISI) engine. Comparison is made between the spray characteristics and in-cylinder fuel distributions due to supply rail pressures of 50 bar and 100 bar subject to part-warm, part-load homogeneous charge operating conditions. A constant fuel mass, corresponding to stoichiometric tune, was maintained for both supply pressures. The injected sprays and their subsequent liquid-phase fuel distributions were visualized using the 2-D laser Mie-scattering technique. The experimental injector (nominally a hollow-cone pressure-swirl design) was seen to produce a dense filled spray structure for both injection pressures under investigation. In both cases, the leading edge velocities of the main spray suggest the direct impingement of liquid fuel on the cylinder walls.

A key objective of this research was to develop an interface device to enable visualization of in-cylinder events within a production SI engine operating at normal speeds and loads, without the need for engine modifications. The device was designed to utilize the existing spark plug hole and to be capable of providing in-cylinder illumination, image transmission and a source of ignition. This technical paper presents the results of the initial evaluation of the device. The evaluation of the durability of the device, in terms of its ability to operate as a spark plug and its permissible operating range is presented. In addition, images of events in the cylinder captured using the device are provided.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

Hydrogen has been largely proposed as a possible fuel for internal combustion engines. The main advantage of burning hydrogen is the absence of carbon-based tailpipe emissions. Hydrogen's wide flammability also offers the advantage of very lean combustion and higher engine efficiency than conventional carbon-based fuels. In order to avoid abnormal combustion modes like pre-ignition and backfiring, as well as air displacement from hydrogen's large injected volume per cycle, direct injection of hydrogen after intake valve closure is the preferred mixture preparation method for hydrogen engines. The current work focused on computational studies of hydrogen injection and mixture formation for direct-injection spark-ignition engines. Hydrogen conditions at the injector's nozzle exit are typically sonic.

An arrangement of port - injected, stratified-charge, 4 - valve SI engine is proposed, in which fuel is injected in a thin column from an injector which is angled so that the fuel is deflected by one of the inlet valves onto the combustion chamber surface, at a position close to the central spark plug. The injection takes place towards the end of the induction stroke, and the injector is mounted to the side of one of the intake ports. The second intake port is deactivated at part load to establish an axial swirling motion to stabilise the fuel evaporating from the warm combustion chamber surface. Testing has been performed on a single - cylinder research engine to assess the extent of the stratification by measuring pre - flame hydrocarbon concentrations at various positions around the combustion chamber.