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Journal Article

A Semi-Detailed Chemical Kinetic Mechanism of Acetone-Butanol-Ethanol (ABE) and Diesel Blends for Combustion Simulations

2016-04-05
2016-01-0583
With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. To seek for an optimized volumetric ratio for ABE-diesel blends, the previous work in our team has experimentally investigated and analyzed the combustion features of ABE-diesel blends with different volumetric ratio (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %) in a constant volume chamber. It was found that an increased amount of acetone would lead to a significant advancement of combustion phasing whereas butanol would compensate the advancing effect. Both spray dynamic and chemistry reaction dynamic are of great importance in explaining the unique combustion characteristic of ABE-diesel blend. In this study, a semi-detailed chemical mechanism is constructed and used to model ABE-diesel spray combustion in a constant volume chamber.
Technical Paper

Computational Analysis of Biodiesel Combustion in a Low-Temperature Combustion Engine using Well-Defined Fuel Properties

2007-04-16
2007-01-0617
Biodiesel fuel can be produced from a wide range of source materials that affect the properties of the fuel. The diesel engine has become a highly tuned power source that is sensitive to these properties. The objectives of this research were to measure and predict the key properties of biodiesel produced from a broad range of source materials to be used as inputs for combustion modeling; and second to compare the results of the model with and without the biodiesel fuel definition. Substantial differences in viscosity, surface tension, density and thermal conductivity were obtained relative to reference diesel fuels and among the different source materials. The combustion model revealed differences in the temperature and emissions of biodiesel when compared to reference diesel fuel.
Technical Paper

Combustion and Emissions of Biodiesel and Diesel Fuels in Direct Injection Compression Ignition Engines using Multiple Injection Strategies

2008-04-14
2008-01-1388
Biodiesel fuels and their blends with diesel are often used to reduce emissions from diesel engines. However, biodiesel has been shown to increase the NOx emissions. Operating a compression ignition engine in low-temperature combustion mode as well as using multiple injections can reduce NOx emissions. Experimental data for biodiesel are compared to those for diesel to show the effect of the biodiesel on the peak pressure, temperature, and emissions. Accurate prediction of biodiesel properties, combined with the KIVA 3V code, is used to investigate the combustion of biodiesel. The volume fraction of the cylinder that has temperatures greater than 2200 K is shown to directly affect the production of oxides of nitrogen. Biodiesel is shown to burn faster during the combustion events, though the ignition delay is often longer for biodiesel compared to diesel.
Technical Paper

Atomization Characteristics of Multi-component Bio-fuel Systems under Micro-explosion Conditions

2008-04-14
2008-01-0937
A numerical study of micro-explosion in multi-component droplets is presented. The homogeneous nucleation theory is used in describing the bubble generation process. A modified Rayleigh equation is then used to calculate the bubble growth rate. The breakup criterion is then determined by applying a linear stability analysis on the bubble-droplet system. After the explosion/breakup, the atomization characteristics, including Sauter mean radius and averaged velocity of the secondary droplets, are calculated from conservation equations. Micro-explosion can be enhanced by introducing biodiesel into the fuel blends of ethanol and tetradecane. Micro-explosion is more likely to occur at high ambient pressure. However, increasing the ambient temperature does not have a significant effect on micro-explosion. There exists an optimal composition in the liquid mixture for micro-explosion.
Technical Paper

Comparing the Operation of a High Speed Direction Injection Engine Using MVCO Injector and Conventional Fuel Injector

2009-04-20
2009-01-0718
The operation of a small bore high speed direct injection (HSDI) engine with a MVCO injector is simulated by the KIVA 3V code, developed by Los Alamos National Laboratory. The MVCO injector extends the range of injection timings over conventional injectors and it extra flexibility in designing injection schemes. Combustion from very early injection is observed with MVCO injections but not with conventional injection. This improves the fuel economy of the engine in terms of lower ISFC. Even better efficiency can be achieved by using biodiesel, which may be due to extra oxygen in the fuel improving the combustion process. Biodiesel sees a longer ignition delay for the initial injection. It also exhibits a faster burning rate and shorter combustion duration. Biodiesel also lowered both NOx and soot emissions. This is consistent with the general observation for soot emissions.
Technical Paper

Comparing the Operation of an HSDI Engine Using Multiple Injection Schemes with Soybean Biodiesel, Diesel and Their Blends

2009-04-20
2009-01-0719
The KIVA-3V code, developed by Los Alamos National Laboratory, with modifications that improve its capability with biodiesel simulations was used to model the operation of an HSDI engine using blends of soybean biodiesel and diesel. Biodiesel and their blends with diesel are frequently used to reduce emissions from diesel engines, although previous studies showed that biodiesel may increase NOx emission. The paradox may be resolved by running the engine in low temperature combustion mode with biodiesel/diesel blends, as low temperature combustion simultaneously reduced NOx and soot. The modified KIVA code predicts the major combustion characteristics: peak combustion pressure, heat release rate and ignition timing accurately when compared with experimental measurements. It also correctly predicts the trend of NOx emissions. It was observed that the cylinder temperature distribution has a strong effect on emission levels.
Technical Paper

Injector Nozzle Coking With Oxygenated Diesel

2001-05-07
2001-01-2016
The use of substances other than petroleum based fuels for power sources is not a new concept. Prior to the advent of petroleum fueled vehicles numerous other substances were used to create mobile sources of power. As the world's petroleum supply dwindles, alternative fuel sources are sought after to replace petroleum fuels. Many industries are particularly interested in the development of renewable fuel sources, or biologically derived fuel sources, which includes ethanol. The use of No. 2 diesel as well as many alternative fuels in compression ignition engines result in injector coking. Injector coking can severely limit engine performance by limiting the amount of fuel delivered to the combustion chamber and altering the spray pattern. Injector tip coking is also one of the most sensitive measures of diesel fuel quality [1]. A machine vision system was implemented to quantify injector coking accumulation when a compression ignition engine was fueled with oxydiesel.
Technical Paper

Feasibility of Modifying an Existing Semi-Trailer Air Suspension Into an Anti-Rollover System

2001-11-12
2001-01-2733
This paper examines the feasibility of modifying an existing semi-trailer air suspension system to function as an anti-rollover system in addition to its normal suspension operation. The semi-trailer model used is a dynamic, two-dimensional system. The anti-rollover system controller is formulated using projective control theory. All other factors being equal, simulations show that use of the modified suspension system decreases the weight shift when the semi-trailer undergoes lateral acceleration. By decreasing weight shift, the modified suspension system decreases the possibility of rollover.
Technical Paper

Comparison of Linear Roll Dynamics Properties for Various Vehicle Configurations

1992-02-01
920053
The ability to categorize, compare and segregate the roll dynamical behavior of various vehicles from one another is a subject of considerable research interest. A number of comparison paradigms have been developed (static stability index, roll couple methods, etc.), but all suffer from lack of robustness: results developed on the basis of a particular comparison metric are often not able to be generalized across vehicle lines and types, etc., or they simply do not segregate vehicles at all. In addition, most models do not describe vehicle dynamics in sufficient detail, and some contain no dynamics at all (e.g., static stability index = t/2h). In the present work, static stability index, a two-degree-of-freedom roll model and a three-degree-of-freedom roll and handling model were used to locate eigenvalues for a sample of 43 vehicles consisting of (1) passenger cars, (2) light trucks, (3) sport/utility vehicles and (4) minivans.
Technical Paper

Combustion Characteristics of Acetone, Butanol, and Ethanol (ABE) Blended with Diesel in a Compression-Ignition Engine

2016-04-05
2016-01-0884
Acetone-Butanol-Ethanol (ABE) is an intermediate product in the ABE fermentation process for producing bio-butanol. As an additive for diesel, it has been shown to improve spray evaporation, improve fuel atomization, enhance air-fuel mixing, and enhance combustion as a whole. The typical compositions of ABE are in a volumetric ratio of 3:6:1 or 6:3:1. From previous studies done in a constant volume chamber, it was observed that the presence of additional acetone in the blend caused advancement in the combustion phasing, but too much acetone content led to an increase in soot emission during combustion. The objective of this research was to investigate the combustion of these mixtures in a diesel engine. The experiments were conducted in an AVL 5402 single-cylinder diesel engine at different speeds and different loads to study component effects on the various engine conditions. The fuels tested in these experiments were D100, ABE(3:6:1)10, ABE(3:6:1)20, ABE(6:3:1)10, and ABE(6:3:1)20.
Technical Paper

An Optical Investigation of Multiple Diesel Injections in CNG/Diesel Dual-Fuel Combustion in a Light Duty Optical Diesel Engine

2017-03-28
2017-01-0755
Dual-fuel combustion combining a premixed charge of compressed natural gas (CNG) and a pilot injection of diesel fuel offer the potential to reduce diesel fuel consumption and drastically reduce soot emissions. In this study, dual-fuel combustion using methane ignited with a pilot injection of No. 2 diesel fuel, was studied in a single cylinder diesel engine with optical access. Experiments were performed at a CNG substitution rate of 70% CNG (based on energy) over a wide range of equivalence ratios of the premixed charge, as well as different diesel injection strategies (single and double injection). A color high-speed camera was used in order to identify and distinguish between lean-premixed methane combustion and diffusion combustion in dual-fuel combustion. The effect of multiple diesel injections is also investigated optically as a means to enhance flame propagation towards the center of the combustion chamber.
Technical Paper

NOx Reduction in Compression-Ignition Engine by Inverted Ignition Phi-Sensitivity

2017-03-28
2017-01-0749
A new approach of NOx reduction in the compression-ignition engine is introduced in this work. The previous research has shown that during the combustion stage, the high temperature ignition tends to occur early at the near-stoichiometric region where the combustion temperature is high and majority of NOx is formed; Therefore, it is desirable to burn the leaner region first and then the near-stoichiometric region, which inhibits the temperature rise of the near-stoichiometric region and consequently suppresses the formation of NOx. Such inverted ignition sequence requires mixture with inverted phi-sensitivity. Fuel selection is performed based on the criteria of strong ignition T-sensitivity, negligible negative temperature coefficient (NTC) behavior, and large heat of vaporization (HoV).
Technical Paper

Regulated and Unregulated Emissions from a Spark Ignition Engine Fueled with Acetone-Butanol-Ethanol (ABE)-Gasoline Blends

2017-10-08
2017-01-2328
Bio-butanol has been widely investigated as a promising alternative fuel. However, the main issues preventing the industrial-scale production of butanol is its relatively low production efficiency and high cost of production. Acetone-butanol-ethanol (ABE), the intermediate product in the ABE fermentation process for producing bio-butanol, has attracted a lot of interest as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. If ABE could be directly used for clean combustion, the separation costs would be eliminated which save an enormous amount of time and money in the production chain of bio-butanol.
Technical Paper

Comparison Study on Combustion and Emission Characteristics of ABE/IBE-Diesel Blends in a Common-Rreail Diesel Engine

2017-10-08
2017-01-2321
Bio-butanol has been considered as a promising alternative fuel for internal combustion engines due to its advantageous physicochemical properties. However, the further development of bio-butanol is inhibited by its high recovery cost and low production efficiency. Hence, the goal of this study is to evaluate two upstream products from different fermentation processes of bio-butanol, namely acetone-butanol-ethanol (ABE) and isopropanol-butanol-ethanol (IBE), as alternative fuels for diesel. The experimental comparison is conducted on a single-cylinder and common-rail diesel engine under various main injection timings (MIT) and equivalent engine load (EEL) conditions. The experimental results show that ABE and IBE significantly affect the combustion phasing. The start of combustion (SOC) is retarded when ABE and IBE are mixed with diesel. Furthermore, the ABE/IBE-diesel blends are more sensitive to the changes in MIT compared with that of pure diesel.
Technical Paper

Effect of Acetone-Gasoline Blend Ratio on Combustion and Emissions Characteristics in a Spark-Ignition Engine

2017-03-28
2017-01-0870
Due to the increasing consumption of fossil fuels, alternative fuels in internal combustion engines have attracted a lot of attention in recent years. Ethanol is the most common alternative fuel used in spark ignition (SI) engines due to its advantages of biodegradability, positively impacting emissions reduction as well as octane number improvement. Meanwhile, acetone is well-known as one of the industrial waste solvents for synthetic fibers and most plastic materials. In comparison to ethanol, acetone has a number of more desirable properties for being a viable alternative fuel such as its higher energy density, heating value and volatility.
Technical Paper

Experimental Investigation and Analysis of Combustion Process in a Diesel Engine Fueled with Acetone-Butanol-Ethanol/ Diesel Blends

2016-04-05
2016-01-0737
The performance and emission of an AVL 5402 single-cylinder engine fueled with acetone-butanol-ethanol (ABE) / diesel blends were experimentally investigated at various load conditions and injection timings. The fuels tested in the experiments were ABE10 (10% ABE, 90% diesel), ABE20 and diesel as baseline. Thermodynamics analyses of pressure traces acquired in experiments were performed to show the impact of ABE concentration to the overall combustion characteristics of the fuel mixtures. Cumulative heat release analysis showed that ABE mixtures generally retarded the overall combustion phasing, ignition delays of ABE-containing fuels were significantly extended, however, combustion rate during CA10∼CA50 were accelerated at different extent. Pressure rise rate of ABE-containing fuels further implicated that the premixed combustion were more dominant than that of diesel. Polytropic indices of both expansion and compression strokes were calculated from p-V diagram.
Technical Paper

Numerical Study and Parameter Optimization on a Diesel - Natural Gas Dual Fuel Engine

2016-04-05
2016-01-0769
This work presents a comprehensive computational study of diesel - natural gas (NG) dual fuel engine. A complete computational model is developed for the operation of a diesel - NG dual fuel engine modified from an AVL 5402 single cylinder diesel test engine. The model is based on the KIVA-3V program and includes customized sub-models. The model is validated against test cell measurements of both pure diesel and dual fuel operation. The effects of NG on ignition and combustion in dual fuel operation are analyzed in detail. Zero-dimensional computations with a diesel surrogate reaction mechanism are conducted to discover the effects of NG on ignition and combustion and to reveal the fundamental chemical mechanisms behind such effects. Backed by the detailed theoretical analysis, the engine operation parameters are optimized with genetic algorithm (GA) for the dual fuel operation of the modified AVL 5402 test engine.
Technical Paper

An Experimental Study of the Combustion, Performance and Emission Characteristics of a CI Engine under Diesel-1-Butanol/CNG Dual Fuel Operation Mode

2016-04-05
2016-01-0788
In order to comply with the stringent emission regulations, many researchers have been focusing on diesel-compressed natural gas (CNG) dual fuel operation in compression ignition (CI) engines. The diesel-CNG dual fuel operation mode has the potential to reduce both the soot and NOx emissions; however, the thermal efficiency is generally lower than that of the pure diesel operation, especially under the low and medium load conditions. The current experimental work investigates the potential of using diesel-1-butanol blends as the pilot fuel to improve the engine performance and emissions. Fuel blends of B0 (pure diesel), B10 (90% diesel and 10% 1-butanol by volume) and B20 (80% diesel and 20% 1-butanol) with 70% CNG substitution were compared based on an equivalent input energy at an engine speed of 1200 RPM. The results indicated that the diesel-1-butanol pilot fuel can lead to a more homogeneous mixture due to the longer ignition delay.
Technical Paper

Study of Biodiesel Combustion in a Constant Volume Chamber with Different Ambient Temperature and Oxygen Concentration

2011-08-30
2011-01-1931
Biodiesel is a widely used biofuel in diesel engines, which is of particular interest as a renewable fuel because it possesses the similar properties as the diesel fuel. The pure soybean biodiesel was tested in an optical constant volume combustion chamber using natural flame luminosity and forward illumination light extinction (FILE) methods to explore the combustion process and soot distribution at various ambient temperatures (800 K and 1000 K) and oxygen concentrations (21%, 16%, 10.5%). Results indicated that, with a lower ambient temperature, the autoignition delay became longer for all three oxygen concentrations and more ambient air was entrained by spray jet and more fuel was burnt by premixed combustion. With less ambient oxygen concentration, the heat release rate showed not only a longer ignition delay but also longer combustion duration.
Technical Paper

Experimental Study on Performance and Emission of Acetone-Ethanol and Gasoline Blends in a PFI Spark Ignition Engine

2016-04-05
2016-01-0833
To face the challenges of fossil fuel shortage and air pollution problems, there is growing interest in the potential usage of alternative fuels such as bio-ethanol and bio-butanol in internal combustion engines. The literature shows that the acetone in the Acetone-Butanol-Ethanol (ABE) blends plays an important part in improving the combustion performance and emissions, owing to its higher volatility. In order to study the effects of acetone addition into commercial gasoline, this study focuses on the differences in combustion, performance and emission characteristics of a port-injection spark-ignition engine fueled with pure gasoline (G100), ethanol-containing gasoline (E30) and acetone-ethanol-gasoline blends (AE30 at A:E volumetric ratio of 3:1). The tests were conducted at 1200RPM with the default calibration (for gasoline), at 3 bar and 5 bar BMEP under various equivalence ratios.
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