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Technical Paper

Computational Analysis of Biodiesel Combustion in a Low-Temperature Combustion Engine using Well-Defined Fuel Properties

2007-04-16
2007-01-0617
Biodiesel fuel can be produced from a wide range of source materials that affect the properties of the fuel. The diesel engine has become a highly tuned power source that is sensitive to these properties. The objectives of this research were to measure and predict the key properties of biodiesel produced from a broad range of source materials to be used as inputs for combustion modeling; and second to compare the results of the model with and without the biodiesel fuel definition. Substantial differences in viscosity, surface tension, density and thermal conductivity were obtained relative to reference diesel fuels and among the different source materials. The combustion model revealed differences in the temperature and emissions of biodiesel when compared to reference diesel fuel.
Technical Paper

Combustion and Emissions of Biodiesel and Diesel Fuels in Direct Injection Compression Ignition Engines using Multiple Injection Strategies

2008-04-14
2008-01-1388
Biodiesel fuels and their blends with diesel are often used to reduce emissions from diesel engines. However, biodiesel has been shown to increase the NOx emissions. Operating a compression ignition engine in low-temperature combustion mode as well as using multiple injections can reduce NOx emissions. Experimental data for biodiesel are compared to those for diesel to show the effect of the biodiesel on the peak pressure, temperature, and emissions. Accurate prediction of biodiesel properties, combined with the KIVA 3V code, is used to investigate the combustion of biodiesel. The volume fraction of the cylinder that has temperatures greater than 2200 K is shown to directly affect the production of oxides of nitrogen. Biodiesel is shown to burn faster during the combustion events, though the ignition delay is often longer for biodiesel compared to diesel.
Technical Paper

Atomization Characteristics of Multi-component Bio-fuel Systems under Micro-explosion Conditions

2008-04-14
2008-01-0937
A numerical study of micro-explosion in multi-component droplets is presented. The homogeneous nucleation theory is used in describing the bubble generation process. A modified Rayleigh equation is then used to calculate the bubble growth rate. The breakup criterion is then determined by applying a linear stability analysis on the bubble-droplet system. After the explosion/breakup, the atomization characteristics, including Sauter mean radius and averaged velocity of the secondary droplets, are calculated from conservation equations. Micro-explosion can be enhanced by introducing biodiesel into the fuel blends of ethanol and tetradecane. Micro-explosion is more likely to occur at high ambient pressure. However, increasing the ambient temperature does not have a significant effect on micro-explosion. There exists an optimal composition in the liquid mixture for micro-explosion.
Technical Paper

Comparing the Operation of a High Speed Direction Injection Engine Using MVCO Injector and Conventional Fuel Injector

2009-04-20
2009-01-0718
The operation of a small bore high speed direct injection (HSDI) engine with a MVCO injector is simulated by the KIVA 3V code, developed by Los Alamos National Laboratory. The MVCO injector extends the range of injection timings over conventional injectors and it extra flexibility in designing injection schemes. Combustion from very early injection is observed with MVCO injections but not with conventional injection. This improves the fuel economy of the engine in terms of lower ISFC. Even better efficiency can be achieved by using biodiesel, which may be due to extra oxygen in the fuel improving the combustion process. Biodiesel sees a longer ignition delay for the initial injection. It also exhibits a faster burning rate and shorter combustion duration. Biodiesel also lowered both NOx and soot emissions. This is consistent with the general observation for soot emissions.
Technical Paper

Comparing the Operation of an HSDI Engine Using Multiple Injection Schemes with Soybean Biodiesel, Diesel and Their Blends

2009-04-20
2009-01-0719
The KIVA-3V code, developed by Los Alamos National Laboratory, with modifications that improve its capability with biodiesel simulations was used to model the operation of an HSDI engine using blends of soybean biodiesel and diesel. Biodiesel and their blends with diesel are frequently used to reduce emissions from diesel engines, although previous studies showed that biodiesel may increase NOx emission. The paradox may be resolved by running the engine in low temperature combustion mode with biodiesel/diesel blends, as low temperature combustion simultaneously reduced NOx and soot. The modified KIVA code predicts the major combustion characteristics: peak combustion pressure, heat release rate and ignition timing accurately when compared with experimental measurements. It also correctly predicts the trend of NOx emissions. It was observed that the cylinder temperature distribution has a strong effect on emission levels.
Technical Paper

Injector Nozzle Coking With Oxygenated Diesel

2001-05-07
2001-01-2016
The use of substances other than petroleum based fuels for power sources is not a new concept. Prior to the advent of petroleum fueled vehicles numerous other substances were used to create mobile sources of power. As the world's petroleum supply dwindles, alternative fuel sources are sought after to replace petroleum fuels. Many industries are particularly interested in the development of renewable fuel sources, or biologically derived fuel sources, which includes ethanol. The use of No. 2 diesel as well as many alternative fuels in compression ignition engines result in injector coking. Injector coking can severely limit engine performance by limiting the amount of fuel delivered to the combustion chamber and altering the spray pattern. Injector tip coking is also one of the most sensitive measures of diesel fuel quality [1]. A machine vision system was implemented to quantify injector coking accumulation when a compression ignition engine was fueled with oxydiesel.
Technical Paper

On-Orbit Performance of the Major Constituent Analyzer

2002-07-15
2002-01-2404
The Major Constituent Analyzer (MCA) was activated on-orbit on 2/13/01 and provided essentially continuous readings of partial pressures for oxygen, nitrogen, carbon dioxide, methane, hydrogen and water in the ISS atmosphere. The MCA plays a crucial role in the operation of the Laboratory ECLSS and EVA operations from the airlock. This paper discusses the performance of the MCA as compared to specified accuracy requirements. The MCA has an on-board self-calibration capability and the frequency of this calibration could be relaxed with the level of instrument stability observed on-orbit. This paper also discusses anomalies the MCA experienced during the first year of on-orbit operation. Extensive Built In Test (BIT) and fault isolation capabilities proved to be invaluable in isolating the causes of anomalies. The process of fault isolation is discussed along with development of workaround solutions and implementation of permanent on-orbit corrections.
Technical Paper

Regulated and Unregulated Emissions from a Spark Ignition Engine Fueled with Acetone-Butanol-Ethanol (ABE)-Gasoline Blends

2017-10-08
2017-01-2328
Bio-butanol has been widely investigated as a promising alternative fuel. However, the main issues preventing the industrial-scale production of butanol is its relatively low production efficiency and high cost of production. Acetone-butanol-ethanol (ABE), the intermediate product in the ABE fermentation process for producing bio-butanol, has attracted a lot of interest as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. If ABE could be directly used for clean combustion, the separation costs would be eliminated which save an enormous amount of time and money in the production chain of bio-butanol.
Technical Paper

Comparison Study on Combustion and Emission Characteristics of ABE/IBE-Diesel Blends in a Common-Rreail Diesel Engine

2017-10-08
2017-01-2321
Bio-butanol has been considered as a promising alternative fuel for internal combustion engines due to its advantageous physicochemical properties. However, the further development of bio-butanol is inhibited by its high recovery cost and low production efficiency. Hence, the goal of this study is to evaluate two upstream products from different fermentation processes of bio-butanol, namely acetone-butanol-ethanol (ABE) and isopropanol-butanol-ethanol (IBE), as alternative fuels for diesel. The experimental comparison is conducted on a single-cylinder and common-rail diesel engine under various main injection timings (MIT) and equivalent engine load (EEL) conditions. The experimental results show that ABE and IBE significantly affect the combustion phasing. The start of combustion (SOC) is retarded when ABE and IBE are mixed with diesel. Furthermore, the ABE/IBE-diesel blends are more sensitive to the changes in MIT compared with that of pure diesel.
Technical Paper

Study of Biodiesel Combustion in a Constant Volume Chamber with Different Ambient Temperature and Oxygen Concentration

2011-08-30
2011-01-1931
Biodiesel is a widely used biofuel in diesel engines, which is of particular interest as a renewable fuel because it possesses the similar properties as the diesel fuel. The pure soybean biodiesel was tested in an optical constant volume combustion chamber using natural flame luminosity and forward illumination light extinction (FILE) methods to explore the combustion process and soot distribution at various ambient temperatures (800 K and 1000 K) and oxygen concentrations (21%, 16%, 10.5%). Results indicated that, with a lower ambient temperature, the autoignition delay became longer for all three oxygen concentrations and more ambient air was entrained by spray jet and more fuel was burnt by premixed combustion. With less ambient oxygen concentration, the heat release rate showed not only a longer ignition delay but also longer combustion duration.
Technical Paper

Dual-Pump Coherent Anti-Stokes Raman Scattering Measurements in a Direct-Injection Natural Gas Engine

1998-02-23
980144
Single-laser-shot measurements of the fuel/air ratio in the cylinder of a motored direct-injection natural gas (DING) engine were obtained using a dual-pump coherent anti-Stokes Raman scattering (CARS) technique capable of simultaneously probing N2 and CH4. The DING engine was modified for optical access and CARS was used to probe the region near the glow plug. Measurements were acquired at eight different probe volume locations with one crank angle degree resolution for injections starting at 30° and 20° BTDC. The CARS data clearly show the arrival of the fuel jet at the probe volume and, from traversing the probe volume, the location of the centerlines of two fuel jets in the vicinity of the glow plug. The CARS measurements also show large fluctuations in fuel concentration on a shot-to-shot basis indicating the presence of large-scale mixing structures within the fuel jets.
Technical Paper

Further Characterization and Multifiltration Treatment of Shuttle Humidity Condensate

1995-07-01
951685
On the International Space Station (ISS), humidity condensate will be collected from the atmosphere and treated by multifiltration to produce potable water for use by the crews. Ground-based development tests have demonstrated that multifiltration beds filled with a series of ion-exchange resins and activated carbons can remove many inorganic and organic contaminants effectively from wastewaters. As a precursor to the use of this technology on the ISS, a demonstration of multifiltration treatment under microgravity conditions was undertaken. On the Space Shuttle, humidity condensate from cabin air is recovered in the atmosphere revitalization system, then stored and periodically vented to space vacuum. A Shuttle Condensate Adsorption Device (SCAD) containing sorbent materials similar to those planned for use on the ISS was developed and flown on STS-68 as a continuation of DSO 317, which was flown initially on STS-45 and STS-47.
Technical Paper

Oxygen From Lunar Soils

1996-07-01
961595
We have conducted experiments on 16 lunar soils and 3 lunar volcanic glass samples to study the extraction of oxygen, an important resource for future lunar bases. The samples were chosen to span the range of composition and mineralogy represented in the Apollo collection. Each sample was reduced in flowing hydrogen for 3 hours at 1050°C. The dominant effect was reduction of Fe2+ (as FeO) in minerals and glass to iron metal, with concomitant release of oxygen. Oxygen extraction was strongly correlated with initial Fe2+ abundance but varied among mineral and glass phases. The experimental reduction of lunar soil and glass provides a method for assessing the oxygen production potential for sites on the lunar surface from lunar orbit. Our results show that oxygen yield from lunar soils can be predicted from knowledge of only one parameter, total iron content. This parameter can be measured from orbit by gamma ray spectrometry or multispectral imaging.
Technical Paper

Integrated Atmosphere Revitalization System Description and Test Results

1983-07-11
831110
Regenerative-type subsystems are being tested at JSC to provide atmosphere revitalization functions of oxygen supply and carbon dioxide (CO2) removal for a future Space Station. Oxygen is supplied by an electrolysis subsystem, developed by General Electric, Wilmington, Mass., which uses the product water from either the CO2 reduction subsystem or a water reclamation process. CO2 is removed and concentrated by an electrochemical process, developed by Life Systems, Inc., Cleveland, Ohio. The concentrated CO2 is reduced in a Sabatier process with the hydrogen from the electrolysis process to water and methane. This subsystem is developed by Hamilton Standard, Windsor Locks, Conn. These subsystems are being integrated into an atmosphere revitalization group. This paper describes the integrated test configuration and the initial checkout test. The feasibility and design compatibility of these subsystems integrated into an air revitalization system is discussed.
Technical Paper

An Advanced Carbon Reactor Subsystem for Carbon Dioxide Reduction

1986-07-14
860995
Reduction of metabolic carbon dioxide is one of the essential steps in physiochemical air revitalization for long-duration manned space missions. Under contract with NASA Johnson Space Center, Hamilton Standard is developing an Advanced Carbon Reactor Subsystem (ACRS) to produce water and dense solid carbon from carbon dioxide and hydrogen. The ACRS essentially consists of a Sabatier Methanation Reactor (SMR) to reduce carbon dioxide with hydrogen to methane and water, a gas-liquid separator to remove product water from the methane, and a Carbon Formation Reactor (CFR) to pyrolyze methane to carbon and hydrogen. The hydrogen is recycled to the SMR, while the produce carbon is periodically removed from the CFR. The SMR is well-developed, while the CFR is under development. In this paper, the fundamentals of the SMR and CFR processes are presented and results of Breadboard CFR testing are reported.
Technical Paper

Macroscopic and Microscopic Characteristics of Flash Boiling Spray with Binary Fuel Mixtures

2019-04-02
2019-01-0274
Flash boiling has drawn much attention recently for its ability to enhance spray atomization and vaporization, while providing better fuel/air mixing for gasoline direct injection engines. However, the behaviors of flash boiling spray with multi-component fuels have not been fully discovered. In this study, isooctane, ethanol and the mixtures of the two with three blend ratios were chosen as the fuels. Measurements were performed with constant fuel temperature while ambient pressures were varied to adjust the superheated degree. Macroscopic and microscopic characteristics of flash boiling spray were investigated using Diffused Back-Illumination (DBI) imaging and Phase Doppler Anemometry (PDA). Comparisons between flash boiling sprays with single component and binary fuel mixtures were performed to study the effect of fuel properties on spray structure as well as atomization and vaporization processes.
Technical Paper

Spray Characteristics of Gasoline-Ethanol Fuel Blends under Flash-Boiling Conditions

2019-04-02
2019-01-0297
The spray structure and vaporization processes of flash-boiling sprays in a constant volume chamber under a wide range of superheated conditions were experimentally investigated by a high speed imaging technique. The Engine Combustion Network’s Spray G injector was used. Four fuels including gasoline, ethanol, and gasoline-ethanol blends E30 and E50 were investigated. Spray penetration length and spray width were correlated to the degree of the superheated degree, which is the ratio of the ambient pressure to saturated vapor pressure (pa/ps). It is found that parameter pa/ps is critical in describing the spray transformation under flash-boiling conditions. Three distinct stages namely the slight flash-boiling, the transition flash-boiling, and the flare flash-boiling are identified to describe the transformation of spray structures.
Technical Paper

Methane Jet Penetration in a Direct-Injection Natural Gas Engine

1998-02-01
980143
A direct-injection natural gas (DING) engine was modified for optical access to allow the use of laser diagnostic techniques to measure species concentrations and temperatures within the cylinder. The injection and mixing processes were examined using planar laser-induced fluorescence (PLIF) of acetone-seeded natural gas to obtain qualitative maps of the fuel/air ratio. Initial acetone PLIF images were acquired in a quiescent combustion chamber with the piston locked in a position corresponding to 90° BTDC. A series of single shot images acquired in 0.1 ms intervals was used to measure the progression of one of the fuel jets across the cylinder. Cylinder pressures as high as 2 MPa were used to match the in-cylinder density during injection in a firing engine. Subsequent images were acquired in a motoring engine at 600 rpm with injections starting at 30, 20, and 15° BTDC in 0.5 crank angle degree increments.
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