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The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

A physics based, lumped thermal capacity model of a 1litre, 3 cylinder, turbocharged, directly injected spark ignition engine has been developed to investigate the effects of cylinder deactivation on the thermal behaviour and fuel economy of small capacity, 3 cylinder engines. When one is deactivated, the output of the two firing cylinders is increased by 50%. The largest temperature differences resulting from this are between exhaust ports and between the upper parts of liners of the deactivated cylinder and the adjacent firing cylinder. These differences increase with load. The deactivated cylinder liner cools to near-coolant temperature. Temperatures in the lower engine structure show little response to deactivation. Temperature response times following deactivation or reactivation events are similar. Motoring work for the deactivated cylinder is a minor loss; the net benefit of deactivation diminishes with increasing load.

A Ford 2.4-liter 115PS light-duty diesel engine was modified to allow solenoid control of the oil feed to the piston cooling jets, enabling these to be switched on or off on demand. The influence of the jets on piston temperatures, engine thermal state, gaseous emissions and fuel economy has been investigated. With the jets switched off, piston temperatures were measured to be between 23 and 88°C higher. Across a range of speed-load points, switching off the jets increased engine-out emissions of NOx typically by 3%, and reduced emissions of CO by 5-10%. Changes in HC were of the same order and were reductions at most conditions. Fuel consumption increased at low-speed, high-load conditions and decreased at high-speed, low-load conditions. Applying the results to the NEDC drive cycle suggests active on/off control of the jets could reduce engine-out emissions of CO by 6%, at the expense of a 1% increase in NOx, compared to the case when the jets are on continuously.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

In a context of global warming and our needs to reduce CO2 emissions, building envelopes will play an important role. A new imperative has been put forth to architects and engineers to develop innovative materials, components and systems, in order to make building envelopes adaptive and responsive to variable and extreme climate conditions. Envelopes serve multiple functions, from shielding the interior environment to collecting, storing and generating energy. Perhaps a more recent concern of terrestrial habitats is permeability and leakages within the building envelope. Such air tight and concealed envelopes with zero particle exchange are a necessity and already exist in regard to space capsules and habitats. This paper attempts to acknowledge existing and visionary envelope concepts and their functioning in conjunction with maintaining a favourable interior environment. It introduces several criteria and requirements of advanced façades along with interior pressurization control.

DISI engine emissions and fuel economy are strongly dependent upon fuel injection and spark timings, particularly when the engine is operating in stratified charge mode. Experimental studies of the effects of injection and spark timings and the interaction between these are described. The sensitivity of HC and NOx emissions to timings during stratified charge operation, the comparison of performance under stratified and homogeneous charge modes of operation and the rationale for mode switch point settings are investigated. The high sensitivity of emissions to injection and spark timing settings gives rise to potential robustness issues. These are described.

This work was concerned with study of the in-cylinder flow field and flame development in a spark ignition research engine equipped with Bowditch piston optical access. High-speed natural light (chemiluminescence) imaging and simultaneous in-cylinder pressure data measurement and analysis were used to understand the fundamentals of flame propagation for a variety of ethanol fuels blended with either gasoline or iso-octane. PIV was undertaken on the same engine in a motoring operation at a horizontal imaging plane close to TDC (10 mm below the fire face) throughout the compression stroke (30°,40°,90° and 180°bTDC) for a low load engine operating condition at 1500rpm/0.5 bar inlet plenum pressure. Up to 1500 cycles were considered to determine the ensemble average flow-field and turbulent kinetic energy. Finally, comparisons were made between the flame and flow experiments to understand the apparent interactions.

Environmental authorities such as EPA, VCA have enforced stringent emissions legislation governing air pollutants released into the atmosphere. Of particular interest is the challenge introduced by the limit on particulate number (PN) counting (#/km) and real driving emissions (RDE) testing; with new emissions legislation being shortly introduced for the gasoline direct injection (GDI) engines, gasoline particulate filters (GPF) are considered the most immediate solution. While engine calibration and testing over the Worldwide harmonized Light vehicles Test Cycle (WLTC) allow for the limits to be met, real driving emission and cold start constitute a real challenge. The present work focuses on an experimental durability study on road under real world driving conditions. Two sets of experiments were carried out. The first study analyzed a gasoline particulate filter (GPF) (2.4 liter, diameter 5.2” round) installed in the underfloor (UF) position and driven up to 200k km.

Soot formation and distribution inside the cylinder of a light-duty direct injection diesel engine, have been predicted using Kiva-3v CFD software. Pathlines of soot particles traced from specific in-cylinder locations and crank angle instants have been explored using the results for cylinder charge motion predicted by the Kiva-3v code. Pathlines are determined assuming soot particles are massless and follow charge motion. Coagulation and agglomeration have not been taken into account. High rates of soot formation dominate during and just after the injection. Oxidation becomes dominant after the injection has terminated and throughout the power stroke. Computed soot pathlines show that soot particles formed just below the fuel spray axis during the early injection period are more likely to travel to the cylinder wall boundary layer. Soot particles above the fuel spray have lesser tendency to be conveyed to the cylinder wall.

The effect of compression ratio on sensitivity to changes in start of injection and air-fuel ratio has been investigated on a single-cylinder DI diesel engine at fixed low and medium speeds and loads. Compression ratio was set to 17.9:1 or 13.7:1 by using pistons with different bowl sizes. Injection timing and air-to-fuel ratio were swept around a nominal map point at which gross IMEP and NOx values were matched for the two compression ratios. It was found that CO, HC and ISFC were higher at low compression ratio, but the soot/NOx trade-off improved and this could be exploited to reduce the fuel economy penalty. Sensitivity to inputs is generally similar, but high compression ratio tended to have steeper response gradients. Reducing compression ratio to 13.7 gave rise to a marked degradation of performance at light load, producing high CO emissions and a fall in combustion efficiency. This could be eased by reducing rail pressure, but the advantage in smoke emission was lost.

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together.

Spark ignition engines for automotive applications must have good cold start performance characteristics at sub-zero ambient temperatures. Satisfactory performance is most difficult to achieve at the lower end of the temperature range, typically around -30°C. The start characteristics of a particular engine depend on basic design features, starter motor characteristics, and the calibration and strategy used to regulate fuel supply during start up. The paper reports a computational model which enables the investigation of these with the minimum of experimental data. The model has been developed to run on desk-top PC machines, specifically as a CAE development tool. The formulation of the model and the experimental tests were used to generate the input data required for particular applications are described.

Optimising an engine specification to improve cold start performance has been investigated. Taguchi methods were used to define a test programme to assess the effect of seven build factors. Experiments were conducted to measure mixture ratio at the spark plug location after a short period of engine cranking at test conditions covering ± 15°C and three fuel-mass-supplied values. The analysis of the results identified build modifications which improved start quality and reduced HC and CO emissions substantially compared to a reference, base-line build. Injector design and location, and inlet valve timing were found to have most influence on robustness to uncontrolled variations in mixture preparation during starts.

The cycle-by-cycle variation of heat transferred per cycle (q) to the combustion chamber surfaces of spark ignition engines has been investigated for quasi-steady and transient conditions produced by throttle movements. The heat transfer calculation is by integration of the instantaneous value over the cycle, using the Woschni correlation for the heat transfer coefficient. By examination of the results obtained, a relatively simple correlation has been identified: This holds both for quasi-steady and transient conditions and is on a per cylinder basis. The analysis has been extended to define a heat flux distribution over the surface of the chamber. This is given by: where F(x/L) is a polynomial function, q″ is the heat transfer per cycle per unit area to head and piston crown surfaces and gives the distribution along the liner

Cycle-by-cycle pressure data have been recorded for a spark ignition engine operating over a wide range of steady state and perturbed running condition. The data base has been analysed to derive mass fraction burnt, pressure development and work mean effective pressure characteristics for individual cycles. Cross-correlation coefficients have been calculated to identify predominant relationships. The effect of combustion phasing on cross-correlation coefficients is particularly significant and three regimes of behaviour have been identified. These are associated with early, optimal and late cases. The cross-correlations between parameters derived from cycle-by-cycle data do not uniformly reflect trends seen between cycle-averaged values of these. Auto-correlation results have been examined for interactions between successive cycles with less success, although, again combustion phasing can have a significant influence on the strength of auto-correlation coefficients.

Engine Electronic Control (EEC) systems on spark ignition engines enable a high degree of performance optimisation to be achieved through strategy and calibration details in software, but development times and costs can be high. The range of functions performed by EEC systems, and the level of performance demanded, are increasing and new methods of development are required. In the paper, the use of neural networks in the development and implementation of open-loop control of air/fuel ratio during engine transient operating conditions is described. The investigation has addressed the definition of suitable networks, the procedure and data required to train these, and assessment of real-time performance of the implemented system. The potential benefits of the approach include reduced calibration effort and simplification of the control strategy.

Surface-mounted heat flux sensors have been used in the intake port of a fuel injected, spark ignition engine to investigate heat transfer between the surface, the gas flows through the port, and fuel deposited in surface films. The engine is of a four valve per cylinder design, with a bifurcated intake port. For dry-port conditions heat transfer per cycle varies between 0 and 300 J/m2 depending on location, towards the surface at low temperatures and away from the surface at fully-warm conditions. Particular attention has been given to the changes in heat transfer rate associated with fuel deposition. Typically this is of the order of 5 kW/m2 in regions of heavy fuel deposition and varies by a factor of 2 over the period of an engine cycle. During warm-up, as coolant temperature increases from 0 to 90°C, changes in heat transfer associated with fuel deposition typically increase from 300 J/m2 to 1000 J/m2.

Experimental studies have been carried out on a spark ignition engine with port fuel injection to examine the influence of injector type and to contrast this with the effects of fuel composition. Intake port fuel transport characteristics and engine-out emissions for fully-warm and warm-up engine operating conditions have been examined as indicators of performance. The investigation has encompassed four types of injector and five gasoline blends. Fuel transport has been characterised using the τ and X parameters. The influence of injector type on these is of similar significance as that of changes in gasoline composition between summer and winter grades. The latter will limit the in-service accuracy of open-loop mixture control during transients. Injector type has a small effect on engine-out emissions under fully-warm operating conditions but has a significant influence on emissions during the early stages of warm-up.

Surface heat transfer measurements have been taken in the intake port of a single cylinder four valve SI engine running on isooctane fuel. The objective has been to establish how fuel characteristics affect trends in surface heat transfer rates for a range of engine operating conditions. The heat transfer measurements were made using heat flux gauges bonded to the intake port surface in the region where highest rates of fuel deposition occur. The influence on heat transfer rates of the deposited fuel and its subsequent behaviour has been examined by comparing fuel-wetted and dry-surface heat transfer measurements. Heat transfer changes are consistent with trends predicted by convective mass transfer over much of the range of surface temperatures from 20°C to 100°C. Towards the upper temperature limit heat transfer reaches a maximum limited by the rate and distribution of fuel deposition.

Experimental studies of fuel utilisation during the early stages of engine warm-up after cold-starts are reported. The investigation has been carried out on a 1.81, 4 cylinder spark-ignition engine with port electronic fuel injection. The relationship between fuel supplied and fuel accounted for by the analysis of exhaust gas composition shows that a significant mass of fuel supplied is temporarily stored or permanently lost. An interpretation of data is made which allows time-dependent variations of these to be separately resolved and estimates of fuel quantities made. The data covers a range of cold-start conditions down to -5°C at which, on a per cylinder basis, fuel stored peaks typically at around 0.75g and a total of 1g is returned over 100 seconds of engine running. Fuel lost past the piston typically accounts for 2g over 200 to 300 seconds of running.