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The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Since the mechanisms leading to cyclic combustion variabilities in direct injection gasoline engines are still poorly understood, advanced computational studies are necessary to be able to predict, analyze and optimize the complete engine process from aerodynamics to mixing, ignition, combustion and heat transfer. In this work the Scale-Adaptive Simulation (SAS) turbulence model is used in combination with a parameterized lagrangian spray model for the purpose of predicting transient in-cylinder cold flow, injection and mixture formation in a gasoline engine. An existing CFD model based on FLUENT v15.0 [1] has been extended with a spray description using the FLUENT Discrete Phase Model (DPM). This article will first discuss the validation of the in-cylinder cold flow model using experimental data measured within an optically accessible engine by High Speed Particle Image Velocimetry (HS-PIV).

Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.

Two optical techniques were developed and combined with a CFD simulation to obtain spatio-temporally resolved information on air/fuel mixing in the cylinder of a methane-fueled, fired, optically accessible engine. Laser-induced fluorescence (LIF) of anisole (methoxybenzene), vaporized in trace amounts into the gaseous fuel upstream of the injector, was captured by a two-camera system, providing one instantaneous image of the air/fuel ratio per cycle. Broadband infrared (IR) absorption by the methane fuel itself was measured in a small probe volume via a spark-plug integrated sensor, yielding time-resolved quasi-point information at kHz-rates. The simulation was based on the Reynolds-averaged Navier-Stokes (RANS) approach with the two-equation k-epsilon turbulence model in a finite volume discretization scheme and included the port-fuel injection event. Commercial CFD software was used to perform engine simulations close to the experimental conditions.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

Over the next decades to come, fossil fuel powered Internal Combustion Engines (ICE) will still constitute the major powertrains for land transport. Therefore, their impact on the global and local pollution and on the use of natural resources should be minimized. To this end, an extensive fundamental and practical study was performed to evaluate the potential benefits of simultaneously co-optimizing the system fuel-and-engine using diesel as an example. It will be clearly shown that the still unused co-optimizing of the system fuel-and-engine (including advanced exhaust after-treatment) as a single entity is a must for enabling cleaner future road transport by cleaner fuels since there are large, still unexploited potentials for improvements in road fuels which will provide major reductions in pollutant emissions both in vehicles already in the field and even more so in future dedicated vehicles.

Laser-based measurements of charge temperature and exhaust gas recirculation (EGR) ratio in an homogeneous charge compression ignition (HCCI) engine are demonstrated. For this purpose, the rotational coherent anti-Stokes Raman spectroscopy technique (CARS) was used. This technique allows temporally and locally resolved measurements in combustion environments through only two small line-of-sight optical accesses and the use of standard gasoline as a fuel. The investigated engine is a production-line four-cylinder direct-injection gasoline engine with the valve strategy modified to realize HCCI-operation. CARS-measurements were performed in motored and fired operation and the results are compared to polytropic calculations. Studies of engine speed, load, valve timing, and injection pressure were conducted showing the strong influence of charge temperature on the combustion timing.

In one-dimensional engine simulation programs the simulation of engine performance is mostly done by parameter fitting in order to match simulations with experimental data. The extensive fitting procedure is especially needed for emissions formation - CO, HC, NO, soot - simulations. An alternative to this approach is, to calculate the emissions based on detailed kinetic models. This however demands that the in-cylinder combustion-flow interaction can be modeled accurately, and that the CPU time needed for the model is still acceptable. PDF based stochastic reactor models offer one possible solution. They usually introduce only one (time dependent) parameter - the mixing time - to model the influence of flow on the chemistry. They offer the prediction of the heat release, together with all emission formation, if the optimum mixing time is given.

An investigation was conducted to elucidate, how the latest turbocharged, direct injection Volkswagen diesel engine generation with cylinder pressure based closed loop control, to be launched in the US in 2008, reacts to fuel variability. A de-correlated fuels matrix was designed to bracket the range of US market fuel properties, which allowed a clear correlation of individual fuel properties with engine response. The test program consisting of steady state operating points showed that cylinder pressure based closed loop control successfully levels out the influence of fuel ignition quality, showing the effectiveness of this new technology for markets with a wide range of fuel qualities. However, it also showed that within the cetane range tested (39 to 55), despite the constant combustion mid-point, cetane number still has an influence on particulate and gaseous emissions. Volatility and energy density also influence the engine's behavior, but less strongly.

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

Internal combustion engines with lean homogeneous charge and auto-ignition combustion of gasoline fuels have the capability to significantly reduce fuel consumption and realize ultra-low engine-out NOx emissions. Group research of Volkswagen AG has therefore defined the Gasoline Compression Ignition combustion (GCI®) concept. A detailed investigation of this novel combustion process has been carried out on test bench engines and test vehicles by group research of Volkswagen AG and IAV GmbH Gifhorn. Experimental results confirm the theoretically expected potential for improved efficiency and emissions behavior. Volkswagen AG and IAV GmbH will utilize a highly flexible externally supercharged variable valve train (VVT) engine for future investigations to extend the understanding of gas exchange and EGR strategy as well as the boost demands of gasoline auto-ignition combustion processes.

Flow control by fluidic devices - without moving parts - offers advantages of reliability and low cost. As an example of their automobile application based on authors'' long-time experience the paper describes a fluidic valve for switching exhaust gas flow in a NOx absorber into a by-pass during regeneration phase. The unique feature here is the fluidic valve being of monostable and of axisymmetric design, integrated into the absorber body. After development in aerodynamic laboratory, the final design was tested on engine test stand and finally in a car. This proved that the performance under high temperature and pulsation existing in exhaust systems is reliable and promising. Fluidic valves require, however, close matching with aerodynamic load. To optimize the exhaust system layout for the whole load-speed range and reaching minimum counter- pressure, both the components of exhaust system and control strategy have to be properly adopted.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

The interaction of three bio-lubricant base oil candidates with seventeen combinations of surface treatment was studied, comparing wear scar volumes and coefficient of friction results. Substrates were initially ground, then a combination of superfinished, Dymon-iC™ DLC, an impact technique of ultra-fine shot blasting method doped with Tin and Molybdenum Disulfide, a calcium based chemical dip containing calcium sulfate and nano fullerene, were used. DLC is well reported to reduce friction. Some reports suggest wear in coated contacts is independent of the type of lubricant used, whilst others report that bio-lubricants offer reduced friction and wear in combination with DLC. Shot blasting can also reduce wear and friction, due to the surface dimples acting as lubricant reservoirs, making hydrodynamic lubrication more likely.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

Meeting strict current and future emissions legislation necessitates development of computational tools capable of predicting the behaviour of combustion and emissions with an accuracy sufficient to make correct design decisions while keeping computational cost of the simulations amenable for large-scale design space exploration. While detailed kinetics modelling is increasingly seen as a necessity for accurate simulations, the computational cost can be often prohibitive, prompting interest in simplified approaches allowing fast simulation of reduced mechanisms at coarse grid resolutions appropriate for internal combustion engine simulations in design context. In this study we present a simplified Well-stirred Reactor (WSR) implementation coupled with 3D CFD Ricardo VECTIS solver.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

VOLKSWAGEN has conducted a number of investigations on a Multi Fuel Vehicle (MFV), designed for variable fuel operation, to determine the influence of fuel composition and clean fuels on exhaust emissions, mainly on ozone forming potential. Results of the tests indicate a small advantage of Phase II Reformulated Gasoline and a greater one for for methanol fuel M85, compared to today's gasoline. For M85 there is an about 25 % lower ozone forming potential. The most critical components in the exhaust of methanol fueled vehicles (M85) are unburned methanol and formaldehyde, forming more than 60 % of the total ozone forming potential. Therefore improvement of cold start and warmup driving during the first two to three minutes is of great importance, because in this time about 90 % of the mentioned components are formed.

Possible materials' solutions to mass reduction in the transport industry are to be found within particulate-reinforced aluminium alloy matrix composites. The objective of this paper is to demonstrate how thixoforming may solve material and manufacturing problems for metallic composites with silicon carbide or silicon particles. Silicon carbide reinforced alloy was thixoformed successfully, at several reinforcement levels, showing a well-maintained particle distribution. Hypereutectic aluminium - silicon material was produced with fine uniform microstructure giving a high Young's modulus and low coefficient of thermal expansion. The results provide alternative approaches for solving slightly differing design problems and applications.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.