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Thermoplastic Vulcanizate (TPV) is a special class of Thermoplastic Elastomers (TPEs) made of a rubber/plastic polymer mixture in which the rubber phase is highly vulcanized. It is prepared by melt mixing a thermoplastic with an elastomer and by in-situ crosslinking of the rubber phase. Currently, TPV is replacing EPDM rubber dramatically because of the impressive advantages for automotive sealing applications. Some of the advantages of TPV compared to that of EPDM rubber are good gloss, recyclability, improved colorability, shorter cycle time and design flexibility. The development of TPV foaming technology is to fulfill the requirement of achieving lower cost, lighter weight and better fuel economy. Foaming of TPV has not been investigated extensively.

TPO is being used to make automotive parts for its number of advantages: i) low temperature flexibility and ductility, ii) excellent impact/stiffness/flow balance, iii) excellent weatherability, and iv) free-flowing pellet form for easy processing, storage, and handling. However, by foaming TPO, due to its higher rigidity-to-weigh ratio, it would offer additional advantages over the solid counterparts in terms of reduced weight, reduced material cost, and decreased fuel usage without compromising their performance. Since a major component in TPO is polypropylene (PP), understanding PP foaming behaviours is an important step towards understanding TPO foaming. For foam materials, cell density and cell size are two significant parameters that affect their material properties. In this research, we observed the cell nucleation and initial growth behaviours of PP foams blown with CO2 under various experimental conditions in a batch foaming simulation system.

Foaming of a thermoplastic polyolefin (TPO) is gaining interests because of its superior mechanical properties of foamed automotive parts, such as lightweight and high performance to weight ratio, etc. In this context, understanding of the thermophysical properties of PP/gas and TPO/gas mixtures is critically important. This paper will present the newly developed experimental technique to accurately measure the swelling of PP and TPO due to gas dissolution at elevated temperatures and pressures. Our technique measures the geometry of the pendent drop accurately from the captured images to obtain the volume swelling data. It determines the boundary location of the polymer/gas sample accurately by magnifying the sample drop locally along its edge before capturing the image. The automated high-precision XY stage is chosen as the platform to control the motion of the CCD camera.

Foaming of thermoplastic polyolefins (TPO) and thermoplastic elastomers (TPE) is gaining interest because of the lightweight and high performance to weight ratio of foamed automotive parts. Since foaming will occur mainly in the PP matrix in these PP-based automotive materials, understanding of the thermophysical properties of PP/gas mixtures is critically important. This paper will present a proposed methodology for measuring the swelling of polymer/gas mixtures. The preliminary experimental measurement of PP/N2 swelling at elevated temperatures and pressures will be discussed.

This paper demonstrates the effects of nano-clay on the microcellular foam processing of nylon. First, Nylon 6 nanocomposites with 1 wt% clay were prepared by a twin screw extruder. The nanocomposite structures were characterized by XRD and TEM. Nylon and its nanocomposites were foamed in extrusion using CO2. The cell morphologies of nylon and its nanocomposite foams were investigated. It appeared that the nano-clay not only enhanced cell nucleation, but also suppressed cell deterioration in the microcellular foaming of nylon.